Synthesis and characterization of a '3+2' {Re(V)O}3+ core complex carrying the ONS/PO donor atom set

Frank J. Femia, Xiaoyuan Chen, John W. Babich, Jon Zubieta

Research output: Contribution to journalArticle

13 Scopus citations

Abstract

The reaction of [TBA][ReOBr4(OPPh3)] with [HOC6H4C(H)=NC6H4SH)] and [HOC6H4-2-P(C6H5)2] in methanol yielded [ReO{η3-(OC6H4C(H)= NC6H4S)}{η2-OC6H4 P(C6H5)2}] (1). The coordination environment around rhenium is distorted octahedral with the ONS donors of the Schiff base and the phosphorus of the phosphinophenolate ligand occupying the equatorial plane, while the axial sites are occupied by the oxo group and the oxygen atom of the PO ligand, as shown by single-crystal X-ray analysis of 1.

Original languageEnglish (US)
Pages (from-to)145-148
Number of pages4
JournalInorganica Chimica Acta
Volume316
Issue number1-2
DOIs
StatePublished - May 7 2001

Keywords

  • Crystal structures
  • Oxo complexes
  • Rhenium complexes
  • Schiff base complexes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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