Synthesis and characterization of a '3+2' {Re(V)O}3+ core complex carrying the ONS/PO donor atom set

Frank J. Femia; Xiaoyuan Chen; John W. Babich; Jon Zubieta

doi:10.1016/S0020-1693(01)00394-2

Synthesis and characterization of a '3+2' {Re(V)O}³⁺ core complex carrying the ONS/PO donor atom set

Frank J. Femia, Xiaoyuan Chen, John W. Babich, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

The reaction of [TBA][ReOBr₄(OPPh₃)] with [HOC₆H₄C(H)=NC₆H₄SH)] and [HOC₆H₄-2-P(C₆H₅)₂] in methanol yielded [ReO{η³-(OC₆H₄C(H)= NC₆H₄S)}{η²-OC₆H₄ P(C₆H₅)₂}] (1). The coordination environment around rhenium is distorted octahedral with the ONS donors of the Schiff base and the phosphorus of the phosphinophenolate ligand occupying the equatorial plane, while the axial sites are occupied by the oxo group and the oxygen atom of the PO ligand, as shown by single-crystal X-ray analysis of 1.

Original language	English (US)
Pages (from-to)	145-148
Number of pages	4
Journal	Inorganica Chimica Acta
Volume	316
Issue number	1-2
DOIs	https://doi.org/10.1016/S0020-1693(01)00394-2
State	Published - May 7 2001

Keywords

Crystal structures
Oxo complexes
Rhenium complexes
Schiff base complexes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/S0020-1693(01)00394-2

Cite this

@article{08e26f9edac34182bf387e3d8988ea41,

title = "Synthesis and characterization of a '3+2' {Re(V)O}3+ core complex carrying the ONS/PO donor atom set",

abstract = "The reaction of [TBA][ReOBr4(OPPh3)] with [HOC6H4C(H)=NC6H4SH)] and [HOC6H4-2-P(C6H5)2] in methanol yielded [ReO{η3-(OC6H4C(H)= NC6H4S)}{η2-OC6H4 P(C6H5)2}] (1). The coordination environment around rhenium is distorted octahedral with the ONS donors of the Schiff base and the phosphorus of the phosphinophenolate ligand occupying the equatorial plane, while the axial sites are occupied by the oxo group and the oxygen atom of the PO ligand, as shown by single-crystal X-ray analysis of 1.",

keywords = "Crystal structures, Oxo complexes, Rhenium complexes, Schiff base complexes",

author = "Femia, {Frank J.} and Xiaoyuan Chen and Babich, {John W.} and Jon Zubieta",

note = "Funding Information: This work was supported by a grant from the Department of Energy (DOE), Office of Health and Environmental Research D2-FG02-99ER62791. ",

year = "2001",

month = may,

day = "7",

doi = "10.1016/S0020-1693(01)00394-2",

language = "English (US)",

volume = "316",

pages = "145--148",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier",

number = "1-2",

}

TY - JOUR

T1 - Synthesis and characterization of a '3+2' {Re(V)O}3+ core complex carrying the ONS/PO donor atom set

AU - Femia, Frank J.

AU - Chen, Xiaoyuan

AU - Babich, John W.

AU - Zubieta, Jon

N1 - Funding Information: This work was supported by a grant from the Department of Energy (DOE), Office of Health and Environmental Research D2-FG02-99ER62791.

PY - 2001/5/7

Y1 - 2001/5/7

N2 - The reaction of [TBA][ReOBr4(OPPh3)] with [HOC6H4C(H)=NC6H4SH)] and [HOC6H4-2-P(C6H5)2] in methanol yielded [ReO{η3-(OC6H4C(H)= NC6H4S)}{η2-OC6H4 P(C6H5)2}] (1). The coordination environment around rhenium is distorted octahedral with the ONS donors of the Schiff base and the phosphorus of the phosphinophenolate ligand occupying the equatorial plane, while the axial sites are occupied by the oxo group and the oxygen atom of the PO ligand, as shown by single-crystal X-ray analysis of 1.

AB - The reaction of [TBA][ReOBr4(OPPh3)] with [HOC6H4C(H)=NC6H4SH)] and [HOC6H4-2-P(C6H5)2] in methanol yielded [ReO{η3-(OC6H4C(H)= NC6H4S)}{η2-OC6H4 P(C6H5)2}] (1). The coordination environment around rhenium is distorted octahedral with the ONS donors of the Schiff base and the phosphorus of the phosphinophenolate ligand occupying the equatorial plane, while the axial sites are occupied by the oxo group and the oxygen atom of the PO ligand, as shown by single-crystal X-ray analysis of 1.

KW - Crystal structures

KW - Oxo complexes

KW - Rhenium complexes

KW - Schiff base complexes

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U2 - 10.1016/S0020-1693(01)00394-2

DO - 10.1016/S0020-1693(01)00394-2

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SP - 145

EP - 148

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

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