Synthesis and characterisation of cobalt and nickel compounds with phosphinothiol ligands. Crystal and molecular structures of [Co{ {2- (Ph2P)-6- (Me3Si)C6H3S)} }3], [Ni{ {2- (Ph2P)-6- (Me3Si)C6H3S)} }2] and [Co{ {2- (Ph2PO)-6- (Me3Si)C6H3S}.

P. Pérez-Lourido; J. Romero; J. A. García-Vázquez; A. Sousa; J. Zubieta; K. Maresca

doi:10.1016/S0277-5387(98)00252-6

Synthesis and characterisation of cobalt and nickel compounds with phosphinothiol ligands. Crystal and molecular structures of [Co{ {2- (Ph₂P)-6- (Me₃Si)C₆H₃S)} }₃], [Ni{ {2- (Ph₂P)-6- (Me₃Si)C₆H₃S)} }₂] and [Co{ {2- (Ph₂PO)-6- (Me₃Si)C₆H₃S}.

P. Pérez-Lourido, J. Romero, J. A. García-Vázquez, A. Sousa, J. Zubieta, K. Maresca

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

Theelectrochemical oxidation of anodic metal (cobalt or nickel) in an acetonitrile solution of phosphinothiol ligands, 2- (Ph₂P)C₆H₄SH, 2- (Ph₂P)-6- (SiMe₃)C₆H₃SH, 2- (Ph₂PO)-6- (SiMe₃)C₆H₃SH, affords [Co{2- (Ph₂P)C₆H₄S)}₃] 1, [Ni{2- (Ph₂P)C₆H₄S}₂] 2, [Co{2- (Ph₂P)-6- (SiMe₃)C₆H₃S}₃] 3, [Ni{2- (Ph₂P)-6- (SiMe₃) C₆H₃S}₂] 4, [Co{2- (Ph₂PO)-6- (SiMe₃)C₆H₃S}₂] 5, [Co{2- (Ph₂PO)-6- (SiMe₃)C₆H₃S}₃] 6 and [Ni{2- (Ph₂PO)-6- (SiMe₃)C₆H₃S}₂] 7. All compounds have been characterised by microanalysis, IR, UV-visible, FAB and NMR spectroscopic studies and compounds 3, 4 and 5 by single-crystal X-ray diffraction.

Original language	English (US)
Pages (from-to)	4457-4464
Number of pages	8
Journal	Polyhedron
Volume	17
Issue number	25-26
DOIs	https://doi.org/10.1016/S0277-5387(98)00252-6
State	Published - Nov 27 1998

Keywords

Cobalt and nickel complexes
Crystalsstructures
Electrochemical synthesis
Phosphinothiol complexes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0277-5387(98)00252-6

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Dive into the research topics of 'Synthesis and characterisation of cobalt and nickel compounds with phosphinothiol ligands. Crystal and molecular structures of [Co{ {2- (Ph₂P)-6- (Me₃Si)C₆H₃S)} }₃], [Ni{ {2- (Ph₂P)-6- (Me₃Si)C₆H₃S)} }₂] and [Co{ {2- (Ph₂PO)-6- (Me₃Si)C₆H₃S}.'. Together they form a unique fingerprint.

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Pérez-Lourido, P., Romero, J., García-Vázquez, J. A., Sousa, A., Zubieta, J., & Maresca, K. (1998). Synthesis and characterisation of cobalt and nickel compounds with phosphinothiol ligands. Crystal and molecular structures of [Co{ {2- (Ph₂P)-6- (Me₃Si)C₆H₃S)} }₃], [Ni{ {2- (Ph₂P)-6- (Me₃Si)C₆H₃S)} }₂] and [Co{ {2- (Ph₂PO)-6- (Me₃Si)C₆H₃S}. Polyhedron, 17(25-26), 4457-4464. https://doi.org/10.1016/S0277-5387(98)00252-6

Synthesis and characterisation of cobalt and nickel compounds with phosphinothiol ligands. Crystal and molecular structures of [Co{ {2- (Ph₂P)-6- (Me₃Si)C₆H₃S)} }₃], [Ni{ {2- (Ph₂P)-6- (Me₃Si)C₆H₃S)} }₂] and [Co{ {2- (Ph₂PO)-6- (Me₃Si)C₆H₃S}. / Pérez-Lourido, P.; Romero, J.; García-Vázquez, J. A. et al.
In: Polyhedron, Vol. 17, No. 25-26, 27.11.1998, p. 4457-4464.

Research output: Contribution to journal › Article › peer-review

Pérez-Lourido, P, Romero, J, García-Vázquez, JA, Sousa, A, Zubieta, J & Maresca, K 1998, 'Synthesis and characterisation of cobalt and nickel compounds with phosphinothiol ligands. Crystal and molecular structures of [Co{ {2- (Ph₂P)-6- (Me₃Si)C₆H₃S)} }₃], [Ni{ {2- (Ph₂P)-6- (Me₃Si)C₆H₃S)} }₂] and [Co{ {2- (Ph₂PO)-6- (Me₃Si)C₆H₃S}.', Polyhedron, vol. 17, no. 25-26, pp. 4457-4464. https://doi.org/10.1016/S0277-5387(98)00252-6

Pérez-Lourido P, Romero J, García-Vázquez JA, Sousa A, Zubieta J, Maresca K. Synthesis and characterisation of cobalt and nickel compounds with phosphinothiol ligands. Crystal and molecular structures of [Co{ {2- (Ph₂P)-6- (Me₃Si)C₆H₃S)} }₃], [Ni{ {2- (Ph₂P)-6- (Me₃Si)C₆H₃S)} }₂] and [Co{ {2- (Ph₂PO)-6- (Me₃Si)C₆H₃S}. Polyhedron. 1998 Nov 27;17(25-26):4457-4464. doi: 10.1016/S0277-5387(98)00252-6

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title = "Synthesis and characterisation of cobalt and nickel compounds with phosphinothiol ligands. Crystal and molecular structures of [Co{ {2- (Ph2P)-6- (Me3Si)C6H3S)} }3], [Ni{ {2- (Ph2P)-6- (Me3Si)C6H3S)} }2] and [Co{ {2- (Ph2PO)-6- (Me3Si)C6H3S}.",

abstract = "Theelectrochemical oxidation of anodic metal (cobalt or nickel) in an acetonitrile solution of phosphinothiol ligands, 2- (Ph2P)C6H4SH, 2- (Ph2P)-6- (SiMe3)C6H3SH, 2- (Ph2PO)-6- (SiMe3)C6H3SH, affords [Co{2- (Ph2P)C6H4S)}3] 1, [Ni{2- (Ph2P)C6H4S}2] 2, [Co{2- (Ph2P)-6- (SiMe3)C6H3S}3] 3, [Ni{2- (Ph2P)-6- (SiMe3) C6H3S}2] 4, [Co{2- (Ph2PO)-6- (SiMe3)C6H3S}2] 5, [Co{2- (Ph2PO)-6- (SiMe3)C6H3S}3] 6 and [Ni{2- (Ph2PO)-6- (SiMe3)C6H3S}2] 7. All compounds have been characterised by microanalysis, IR, UV-visible, FAB and NMR spectroscopic studies and compounds 3, 4 and 5 by single-crystal X-ray diffraction.",

keywords = "Cobalt and nickel complexes, Crystalsstructures, Electrochemical synthesis, Phosphinothiol complexes",

author = "P. P{\'e}rez-Lourido and J. Romero and Garc{\'i}a-V{\'a}zquez, {J. A.} and A. Sousa and J. Zubieta and K. Maresca",

note = "Funding Information: —We thank the Xunta de Galicia (Xuga-20316B96) for financial support. ",

year = "1998",

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doi = "10.1016/S0277-5387(98)00252-6",

language = "English (US)",

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T1 - Synthesis and characterisation of cobalt and nickel compounds with phosphinothiol ligands. Crystal and molecular structures of [Co{ {2- (Ph2P)-6- (Me3Si)C6H3S)} }3], [Ni{ {2- (Ph2P)-6- (Me3Si)C6H3S)} }2] and [Co{ {2- (Ph2PO)-6- (Me3Si)C6H3S}.

AU - Pérez-Lourido, P.

AU - Romero, J.

AU - García-Vázquez, J. A.

AU - Sousa, A.

AU - Zubieta, J.

AU - Maresca, K.

N1 - Funding Information: —We thank the Xunta de Galicia (Xuga-20316B96) for financial support.

PY - 1998/11/27

Y1 - 1998/11/27

N2 - Theelectrochemical oxidation of anodic metal (cobalt or nickel) in an acetonitrile solution of phosphinothiol ligands, 2- (Ph2P)C6H4SH, 2- (Ph2P)-6- (SiMe3)C6H3SH, 2- (Ph2PO)-6- (SiMe3)C6H3SH, affords [Co{2- (Ph2P)C6H4S)}3] 1, [Ni{2- (Ph2P)C6H4S}2] 2, [Co{2- (Ph2P)-6- (SiMe3)C6H3S}3] 3, [Ni{2- (Ph2P)-6- (SiMe3) C6H3S}2] 4, [Co{2- (Ph2PO)-6- (SiMe3)C6H3S}2] 5, [Co{2- (Ph2PO)-6- (SiMe3)C6H3S}3] 6 and [Ni{2- (Ph2PO)-6- (SiMe3)C6H3S}2] 7. All compounds have been characterised by microanalysis, IR, UV-visible, FAB and NMR spectroscopic studies and compounds 3, 4 and 5 by single-crystal X-ray diffraction.

AB - Theelectrochemical oxidation of anodic metal (cobalt or nickel) in an acetonitrile solution of phosphinothiol ligands, 2- (Ph2P)C6H4SH, 2- (Ph2P)-6- (SiMe3)C6H3SH, 2- (Ph2PO)-6- (SiMe3)C6H3SH, affords [Co{2- (Ph2P)C6H4S)}3] 1, [Ni{2- (Ph2P)C6H4S}2] 2, [Co{2- (Ph2P)-6- (SiMe3)C6H3S}3] 3, [Ni{2- (Ph2P)-6- (SiMe3) C6H3S}2] 4, [Co{2- (Ph2PO)-6- (SiMe3)C6H3S}2] 5, [Co{2- (Ph2PO)-6- (SiMe3)C6H3S}3] 6 and [Ni{2- (Ph2PO)-6- (SiMe3)C6H3S}2] 7. All compounds have been characterised by microanalysis, IR, UV-visible, FAB and NMR spectroscopic studies and compounds 3, 4 and 5 by single-crystal X-ray diffraction.

KW - Cobalt and nickel complexes

KW - Crystalsstructures

KW - Electrochemical synthesis

KW - Phosphinothiol complexes

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