TY - JOUR
T1 - Syntheses and structures of two organic-inorganic hybrid vanadates, [Cu(1,10-phenanthroline)(H2O)V2O6] and [Co(1,10-phenanthroline)(H2O)V2O6]
AU - Devi, R. Nandini
AU - Zubieta, Jon
N1 - Funding Information:
This work was supported by NSF grant CHE9987471.
PY - 2003/1/30
Y1 - 2003/1/30
N2 - Two new organic-inorganic hybrid vanadates, [Cu(1,10-phenanthroline)(H2O)V2O6] (1) and [Co(1,10-phenanthroline)(H2O)V2O6] (2) were synthesized hydrothermally. The cell parameters of the compounds are: 1, a=7.8353(5), b=9.2300(6), c=10.7162(7) Å, α=88.830(1), β=70.891(1), γ=76.444(1)°, V=710.55(8) Å3, Z=2 and 2, a=7.8357(4), b=21.0896(12), c=9.4155(5) Å, β=112.904(1), V=1433.26(13) Å3, Z=4. Compound 1 is one-dimensional consisting of [V4O12]4- rings connected through [Cu(phen)(H2O)]2+ subunits. The structure of 2 is two-dimensional, with a network constructed from one-dimensional chains of corner-sharing [VO4]3- tetrahedra, which are linked through [Co(phen)(H2O)]2+ groups.
AB - Two new organic-inorganic hybrid vanadates, [Cu(1,10-phenanthroline)(H2O)V2O6] (1) and [Co(1,10-phenanthroline)(H2O)V2O6] (2) were synthesized hydrothermally. The cell parameters of the compounds are: 1, a=7.8353(5), b=9.2300(6), c=10.7162(7) Å, α=88.830(1), β=70.891(1), γ=76.444(1)°, V=710.55(8) Å3, Z=2 and 2, a=7.8357(4), b=21.0896(12), c=9.4155(5) Å, β=112.904(1), V=1433.26(13) Å3, Z=4. Compound 1 is one-dimensional consisting of [V4O12]4- rings connected through [Cu(phen)(H2O)]2+ subunits. The structure of 2 is two-dimensional, with a network constructed from one-dimensional chains of corner-sharing [VO4]3- tetrahedra, which are linked through [Co(phen)(H2O)]2+ groups.
KW - Copper vanadates
KW - Inorganic oxides
KW - Organic-inorganic hybrid materials
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U2 - 10.1016/S0020-1693(02)01213-6
DO - 10.1016/S0020-1693(02)01213-6
M3 - Article
AN - SCOPUS:0037472420
SN - 0020-1693
VL - 343
SP - 313
EP - 316
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
ER -