Syntheses and structures of two organic-inorganic hybrid vanadates, [Cu(1,10-phenanthroline)(H2O)V2O6] and [Co(1,10-phenanthroline)(H2O)V2O6]

R. Nandini Devi; Jon Zubieta

doi:10.1016/S0020-1693(02)01213-6

Syntheses and structures of two organic-inorganic hybrid vanadates, [Cu(1,10-phenanthroline)(H₂O)V₂O₆] and [Co(1,10-phenanthroline)(H₂O)V₂O₆]

R. Nandini Devi, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

Two new organic-inorganic hybrid vanadates, [Cu(1,10-phenanthroline)(H₂O)V₂O₆] (1) and [Co(1,10-phenanthroline)(H₂O)V₂O₆] (2) were synthesized hydrothermally. The cell parameters of the compounds are: 1, a=7.8353(5), b=9.2300(6), c=10.7162(7) Å, α=88.830(1), β=70.891(1), γ=76.444(1)°, V=710.55(8) Å³, Z=2 and 2, a=7.8357(4), b=21.0896(12), c=9.4155(5) Å, β=112.904(1), V=1433.26(13) Å³, Z=4. Compound 1 is one-dimensional consisting of [V₄O₁₂]^4- rings connected through [Cu(phen)(H₂O)]²⁺ subunits. The structure of 2 is two-dimensional, with a network constructed from one-dimensional chains of corner-sharing [VO₄]^3- tetrahedra, which are linked through [Co(phen)(H₂O)]²⁺ groups.

Original language	English (US)
Pages (from-to)	313-316
Number of pages	4
Journal	Inorganica Chimica Acta
Volume	343
DOIs	https://doi.org/10.1016/S0020-1693(02)01213-6
State	Published - Jan 30 2003

Keywords

Copper vanadates
Inorganic oxides
Organic-inorganic hybrid materials

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/S0020-1693(02)01213-6

Cite this

@article{e844f8ee71304b5ead99b185b9cd7135,

title = "Syntheses and structures of two organic-inorganic hybrid vanadates, [Cu(1,10-phenanthroline)(H2O)V2O6] and [Co(1,10-phenanthroline)(H2O)V2O6]",

abstract = "Two new organic-inorganic hybrid vanadates, [Cu(1,10-phenanthroline)(H2O)V2O6] (1) and [Co(1,10-phenanthroline)(H2O)V2O6] (2) were synthesized hydrothermally. The cell parameters of the compounds are: 1, a=7.8353(5), b=9.2300(6), c=10.7162(7) {\AA}, α=88.830(1), β=70.891(1), γ=76.444(1)°, V=710.55(8) {\AA}3, Z=2 and 2, a=7.8357(4), b=21.0896(12), c=9.4155(5) {\AA}, β=112.904(1), V=1433.26(13) {\AA}3, Z=4. Compound 1 is one-dimensional consisting of [V4O12]4- rings connected through [Cu(phen)(H2O)]2+ subunits. The structure of 2 is two-dimensional, with a network constructed from one-dimensional chains of corner-sharing [VO4]3- tetrahedra, which are linked through [Co(phen)(H2O)]2+ groups.",

keywords = "Copper vanadates, Inorganic oxides, Organic-inorganic hybrid materials",

author = "Devi, {R. Nandini} and Jon Zubieta",

note = "Funding Information: This work was supported by NSF grant CHE9987471.",

year = "2003",

month = jan,

day = "30",

doi = "10.1016/S0020-1693(02)01213-6",

language = "English (US)",

volume = "343",

pages = "313--316",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier",

}

TY - JOUR

T1 - Syntheses and structures of two organic-inorganic hybrid vanadates, [Cu(1,10-phenanthroline)(H2O)V2O6] and [Co(1,10-phenanthroline)(H2O)V2O6]

AU - Devi, R. Nandini

AU - Zubieta, Jon

N1 - Funding Information: This work was supported by NSF grant CHE9987471.

PY - 2003/1/30

Y1 - 2003/1/30

N2 - Two new organic-inorganic hybrid vanadates, [Cu(1,10-phenanthroline)(H2O)V2O6] (1) and [Co(1,10-phenanthroline)(H2O)V2O6] (2) were synthesized hydrothermally. The cell parameters of the compounds are: 1, a=7.8353(5), b=9.2300(6), c=10.7162(7) Å, α=88.830(1), β=70.891(1), γ=76.444(1)°, V=710.55(8) Å3, Z=2 and 2, a=7.8357(4), b=21.0896(12), c=9.4155(5) Å, β=112.904(1), V=1433.26(13) Å3, Z=4. Compound 1 is one-dimensional consisting of [V4O12]4- rings connected through [Cu(phen)(H2O)]2+ subunits. The structure of 2 is two-dimensional, with a network constructed from one-dimensional chains of corner-sharing [VO4]3- tetrahedra, which are linked through [Co(phen)(H2O)]2+ groups.

AB - Two new organic-inorganic hybrid vanadates, [Cu(1,10-phenanthroline)(H2O)V2O6] (1) and [Co(1,10-phenanthroline)(H2O)V2O6] (2) were synthesized hydrothermally. The cell parameters of the compounds are: 1, a=7.8353(5), b=9.2300(6), c=10.7162(7) Å, α=88.830(1), β=70.891(1), γ=76.444(1)°, V=710.55(8) Å3, Z=2 and 2, a=7.8357(4), b=21.0896(12), c=9.4155(5) Å, β=112.904(1), V=1433.26(13) Å3, Z=4. Compound 1 is one-dimensional consisting of [V4O12]4- rings connected through [Cu(phen)(H2O)]2+ subunits. The structure of 2 is two-dimensional, with a network constructed from one-dimensional chains of corner-sharing [VO4]3- tetrahedra, which are linked through [Co(phen)(H2O)]2+ groups.

KW - Copper vanadates

KW - Inorganic oxides

KW - Organic-inorganic hybrid materials

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