Syntheses and structures of two new organic-inorganic hybrid manganese vanadates, [Mn(2,2′-bipyridine)2V2O6] and [Mn(1,10-phenanthroline) (H2O)V2O6]

R. Nandini Devi, Jon Zubieta

Research output: Contribution to journalArticle

25 Scopus citations

Abstract

Two new organic-inorganic hybrid manganese vanadates, [Mn(2,2′-bipyridine)2V2O6] (1) and [Mn(1,10-phenanthroline)(H2O)V2O6] (2) were synthesized hydrothermally from mixtures of manganese acetate, V2O5 and the corresponding ligand and acidified with acetic acid. Compound 1 is a molecular cluster consisting of [V4O12]4- rings decorated with [Mn(2,2′-bpy)2]2+ subunits. The structure of 2 is two dimensional, with a network constructed from one-dimensional chains of corner-sharing [VO4]3- tetrahedra, which are linked through [Mn(phen)(H2O)]2+ groups.

Original languageEnglish (US)
Pages (from-to)165-168
Number of pages4
JournalInorganica Chimica Acta
Volume338
DOIs
StatePublished - Oct 14 2002

Keywords

  • Bimetallic oxides
  • Syntheses and structures of two new organic-inorganic hybrid manganese vanadates
  • [Mn(1,10-phenanthroline) (HO)VO]
  • [Mn(2,2′-bipyridine)VO]

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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