TY - JOUR
T1 - Syntheses and structures of two new organic-inorganic hybrid manganese vanadates, [Mn(2,2′-bipyridine)2V2O6] and [Mn(1,10-phenanthroline) (H2O)V2O6]
AU - Nandini Devi, R.
AU - Zubieta, Jon
N1 - Funding Information:
This work was supported by a grant from the National Science Foundation (CHE 9987471).
PY - 2002/10/14
Y1 - 2002/10/14
N2 - Two new organic-inorganic hybrid manganese vanadates, [Mn(2,2′-bipyridine)2V2O6] (1) and [Mn(1,10-phenanthroline)(H2O)V2O6] (2) were synthesized hydrothermally from mixtures of manganese acetate, V2O5 and the corresponding ligand and acidified with acetic acid. Compound 1 is a molecular cluster consisting of [V4O12]4- rings decorated with [Mn(2,2′-bpy)2]2+ subunits. The structure of 2 is two dimensional, with a network constructed from one-dimensional chains of corner-sharing [VO4]3- tetrahedra, which are linked through [Mn(phen)(H2O)]2+ groups.
AB - Two new organic-inorganic hybrid manganese vanadates, [Mn(2,2′-bipyridine)2V2O6] (1) and [Mn(1,10-phenanthroline)(H2O)V2O6] (2) were synthesized hydrothermally from mixtures of manganese acetate, V2O5 and the corresponding ligand and acidified with acetic acid. Compound 1 is a molecular cluster consisting of [V4O12]4- rings decorated with [Mn(2,2′-bpy)2]2+ subunits. The structure of 2 is two dimensional, with a network constructed from one-dimensional chains of corner-sharing [VO4]3- tetrahedra, which are linked through [Mn(phen)(H2O)]2+ groups.
KW - Bimetallic oxides
KW - Syntheses and structures of two new organic-inorganic hybrid manganese vanadates
KW - [Mn(1,10-phenanthroline) (HO)VO]
KW - [Mn(2,2′-bipyridine)VO]
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U2 - 10.1016/S0020-1693(02)00911-8
DO - 10.1016/S0020-1693(02)00911-8
M3 - Article
AN - SCOPUS:0037078761
SN - 0020-1693
VL - 338
SP - 165
EP - 168
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
ER -