TY - JOUR
T1 - Syntheses and structures of the first heavy alkaline earth metal germanides M(THF)n(Ge(SiMe3)3)2 (M = Ca, n = 3; M = Sr, n = 3; and M = Ba, n = 4)
AU - Teng, Weijie
AU - Ruhlandt-Senge, Karin
PY - 2004/3/1
Y1 - 2004/3/1
N2 - Calcium, strontium, and barium compounds involving heavy group 14 ligands have been recognized as useful initiators in the polymerization of acrylonitrile. Since little is known on the exact nature of the target compounds, including information on synthetic access and spectroscopic and structural details, we have prepared and characterized the first calcium, strontium, and barium germanides of the general formula M(THF)n(Ge(SiMe3)3)2 (M = Ca, n = 3, 1; Sr, n = 3, 2; and Ba, n = 4, 3). The title compounds are available by a convenient one-pot metathesis reaction.
AB - Calcium, strontium, and barium compounds involving heavy group 14 ligands have been recognized as useful initiators in the polymerization of acrylonitrile. Since little is known on the exact nature of the target compounds, including information on synthetic access and spectroscopic and structural details, we have prepared and characterized the first calcium, strontium, and barium germanides of the general formula M(THF)n(Ge(SiMe3)3)2 (M = Ca, n = 3, 1; Sr, n = 3, 2; and Ba, n = 4, 3). The title compounds are available by a convenient one-pot metathesis reaction.
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U2 - 10.1021/om034157m
DO - 10.1021/om034157m
M3 - Article
AN - SCOPUS:1542647325
SN - 0276-7333
VL - 23
SP - 952
EP - 956
JO - Organometallics
JF - Organometallics
IS - 5
ER -