Syntheses and reactivity of stannyloligosilanes. 2. A branched stannyloligosilanes

Burkhard Costisella, Ulrich Englich, Ingo Prass, Markus Schürmann, Karin Ruhlandt-Senge, Frank Uhlig

Research output: Contribution to journalArticle

14 Scopus citations

Abstract

Branched tri(stannyl)tetrasilanes MeSi[SiMe2SnR2R′]3 (2, R = R′ = Ph; 3, R = R′ = Me; 5, R = t-Bu, R′ = H) were synthesized by the reaction of alkali metal tri- or diorganostannides with methyltris(fluorodimethylsilyl)silane (1) or methyltris(chlorodimethylsilyl)silane (4) or by reacting triphenylchlorostannane with 1 in the presence of magnesium. Methyltris[(hydridodi-tert-butylstannyl)dimethylsilyl]silane (5) was halogenated at the tin atom by treatment with CHCl3 or CHBr3.

Original languageEnglish (US)
Pages (from-to)2546-2550
Number of pages5
JournalOrganometallics
Volume19
Issue number13
DOIs
StatePublished - Jun 26 2000

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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