TY - JOUR
T1 - Syntheis and structural characterization of cyclo-pentakis [bis(μ-trimethylsilylthiomethane)nickel(II)], [Ni(SCH2SiMe3)2]5, a pentametallic tiara structure
AU - Koo, Bon Kweon
AU - Block, Eric
AU - Kang, Hyunkyu
AU - Liu, Shuncheng
AU - Zubieta, Jon
PY - 1988
Y1 - 1988
N2 - Reaction of (NEt4)2NiCl4 with HSCH2SiMe3 in acetonitrile yields lustrous dark brown crystals of [Ni(SR)2]5 (1). The structure of 1 consists of a nearly regular pentagon of Ni atoms, bridged by pairs of thiolate ligands and represents an unusual example of a pentametallic "tiara" structure. Crystal data: space group P21/c; a = 16.483(3), b = 22.219(4), c = 23.439(4) Å, β = 108.07(1)°, V = 8160.5(13) Å3; current R = 0.0611, based on 6246 reflections.
AB - Reaction of (NEt4)2NiCl4 with HSCH2SiMe3 in acetonitrile yields lustrous dark brown crystals of [Ni(SR)2]5 (1). The structure of 1 consists of a nearly regular pentagon of Ni atoms, bridged by pairs of thiolate ligands and represents an unusual example of a pentametallic "tiara" structure. Crystal data: space group P21/c; a = 16.483(3), b = 22.219(4), c = 23.439(4) Å, β = 108.07(1)°, V = 8160.5(13) Å3; current R = 0.0611, based on 6246 reflections.
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U2 - 10.1016/S0277-5387(00)80392-7
DO - 10.1016/S0277-5387(00)80392-7
M3 - Article
AN - SCOPUS:0000238585
SN - 0277-5387
VL - 7
SP - 1397
EP - 1399
JO - Polyhedron
JF - Polyhedron
IS - 15
ER -