Abstract
Hydrogen peroxide reacts with a Cuii complex of a m-xylyl binucleating ligand with concomitant hydroxylation to give a phenoxo-bridged complex (previously found as the product of the reaction of dioxygen with the Cui analogue) whereas a newly synthesized mononuclear analogue is unreactive, thereby implicating μ-peroxo-Cuii intermediates in the hydroxylation reaction.
Original language | English (US) |
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Pages (from-to) | 939-940 |
Number of pages | 2 |
Journal | Journal of the Chemical Society - Series Chemical Communications |
Issue number | 14 |
DOIs | |
State | Published - Jan 1 1984 |
Externally published | Yes |
ASJC Scopus subject areas
- Molecular Medicine