Studies of molybdenum thiolato-complexes. The crystal and molecular structures of two triply bridged Mo(V) dimers, [Bu4nN][Mo2O2Cl5(SPh)2] and [Mo2O3(SPh)2(S2CNMe2)2]

Jonathan R. Dilworth; Bryan D. Neaves; Phillip Dahlstrom; Jeffery Hyde; Jon A. Zubieta

doi:10.1007/BF00618709

Studies of molybdenum thiolato-complexes. The crystal and molecular structures of two triply bridged Mo(V) dimers, [Bu₄ⁿN][Mo₂O₂Cl₅(SPh)₂] and [Mo₂O₃(SPh)₂(S₂CNMe₂)₂]

Jonathan R. Dilworth, Bryan D. Neaves, Phillip Dahlstrom, Jeffery Hyde, Jon A. Zubieta

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

The complex [Bu₄ⁿN][Mo₂O₂Cl₅(SPh)₂] has been prepared by reaction of [Bu₄ⁿN][MoO(SPh)₄] with stoichiometric amounts of HCl and characterised by single crystal X-ray structure analysis. The dimer is bridged by two oxo-groups and one chloride and each Mo has pseudo-octahedral co-ordination. The related compound [Mo₂O₃(SPh)₂(S₂CNMe₂)₂] was synthesised by reaction of [MoO₂(S₂CNMe₂)₂] with thiophenol in methanol and has also been characterised crystallographically. In this case the triple-bridge consists of two thiophenolate sulphurs and one oxo-group, each molybdenum having pseudo-octahedral geometry. These structures are compared with other triply-bridged species.

Original language	English (US)
Pages (from-to)	257-260
Number of pages	4
Journal	Transition Metal Chemistry
Volume	7
Issue number	5
DOIs	https://doi.org/10.1007/BF00618709
State	Published - Oct 1982
Externally published	Yes

ASJC Scopus subject areas

Inorganic Chemistry
Metals and Alloys
Materials Chemistry

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Studies of molybdenum thiolato-complexes. The crystal and molecular structures of two triply bridged Mo(V) dimers, [Bu₄ⁿN][Mo₂O₂Cl₅(SPh)₂] and [Mo₂O₃(SPh)₂(S₂CNMe₂)₂]. / Dilworth, Jonathan R.; Neaves, Bryan D.; Dahlstrom, Phillip et al.
In: Transition Metal Chemistry, Vol. 7, No. 5, 10.1982, p. 257-260.

Research output: Contribution to journal › Article › peer-review

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title = "Studies of molybdenum thiolato-complexes. The crystal and molecular structures of two triply bridged Mo(V) dimers, [Bu4nN][Mo2O2Cl5(SPh)2] and [Mo2O3(SPh)2(S2CNMe2)2]",

abstract = "The complex [Bu4nN][Mo2O2Cl5(SPh)2] has been prepared by reaction of [Bu4nN][MoO(SPh)4] with stoichiometric amounts of HCl and characterised by single crystal X-ray structure analysis. The dimer is bridged by two oxo-groups and one chloride and each Mo has pseudo-octahedral co-ordination. The related compound [Mo2O3(SPh)2(S2CNMe2)2] was synthesised by reaction of [MoO2(S2CNMe2)2] with thiophenol in methanol and has also been characterised crystallographically. In this case the triple-bridge consists of two thiophenolate sulphurs and one oxo-group, each molybdenum having pseudo-octahedral geometry. These structures are compared with other triply-bridged species.",

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T1 - Studies of molybdenum thiolato-complexes. The crystal and molecular structures of two triply bridged Mo(V) dimers, [Bu4nN][Mo2O2Cl5(SPh)2] and [Mo2O3(SPh)2(S2CNMe2)2]

AU - Dilworth, Jonathan R.

AU - Neaves, Bryan D.

AU - Dahlstrom, Phillip

AU - Hyde, Jeffery

AU - Zubieta, Jon A.

PY - 1982/10

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N2 - The complex [Bu4nN][Mo2O2Cl5(SPh)2] has been prepared by reaction of [Bu4nN][MoO(SPh)4] with stoichiometric amounts of HCl and characterised by single crystal X-ray structure analysis. The dimer is bridged by two oxo-groups and one chloride and each Mo has pseudo-octahedral co-ordination. The related compound [Mo2O3(SPh)2(S2CNMe2)2] was synthesised by reaction of [MoO2(S2CNMe2)2] with thiophenol in methanol and has also been characterised crystallographically. In this case the triple-bridge consists of two thiophenolate sulphurs and one oxo-group, each molybdenum having pseudo-octahedral geometry. These structures are compared with other triply-bridged species.

AB - The complex [Bu4nN][Mo2O2Cl5(SPh)2] has been prepared by reaction of [Bu4nN][MoO(SPh)4] with stoichiometric amounts of HCl and characterised by single crystal X-ray structure analysis. The dimer is bridged by two oxo-groups and one chloride and each Mo has pseudo-octahedral co-ordination. The related compound [Mo2O3(SPh)2(S2CNMe2)2] was synthesised by reaction of [MoO2(S2CNMe2)2] with thiophenol in methanol and has also been characterised crystallographically. In this case the triple-bridge consists of two thiophenolate sulphurs and one oxo-group, each molybdenum having pseudo-octahedral geometry. These structures are compared with other triply-bridged species.

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Studies of molybdenum thiolato-complexes. The crystal and molecular structures of two triply bridged Mo(V) dimers, [Bu₄ⁿN][Mo₂O₂Cl₅(SPh)₂] and [Mo₂O₃(SPh)₂(S₂CNMe₂)₂]

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