Structure directing role of a tridentate ligand in a two-dimensional Ag(I) network

Randy S. Rarig; Jon Zubieta

doi:10.1016/S0020-1693(02)01055-1

Structure directing role of a tridentate ligand in a two-dimensional Ag(I) network

Randy S. Rarig, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article

7 Scopus citations

Abstract

The hydrothermal reaction of silver nitrate with 4,4′-dipyridylamine (Hdpa) yields a new Ag(I) two-dimensional network material, [Ag(dpa)]. The structure is constructed from trigonal Ag(I) sites bound to two nitrogen donors from adjacent dpa^- ligands and the central deprotonated nitrogen of the dpa^- ligand. Crystal data: orthorhombic Cmcm, a = 11.0160(8) Å, b = 11.2683(8) Å, c = 7.2619(5) Å, Z = 16, V = 901.4(1) Å³, D_calc = 2.049 g cm^-3, R₁ = 0.0308.

Original language	English (US)
Pages (from-to)	211-214
Number of pages	4
Journal	Inorganica Chimica Acta
Volume	340
DOIs	https://doi.org/10.1016/S0020-1693(02)01055-1
State	Published - Nov 25 2002

Keywords

Hydrothermal synthesis
Silver networks
Two-dimensional network

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0020-1693(02)01055-1

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Rarig, R. S., & Zubieta, J. (2002). Structure directing role of a tridentate ligand in a two-dimensional Ag(I) network. Inorganica Chimica Acta, 340, 211-214. https://doi.org/10.1016/S0020-1693(02)01055-1

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abstract = "The hydrothermal reaction of silver nitrate with 4,4′-dipyridylamine (Hdpa) yields a new Ag(I) two-dimensional network material, [Ag(dpa)]. The structure is constructed from trigonal Ag(I) sites bound to two nitrogen donors from adjacent dpa- ligands and the central deprotonated nitrogen of the dpa- ligand. Crystal data: orthorhombic Cmcm, a = 11.0160(8) {\AA}, b = 11.2683(8) {\AA}, c = 7.2619(5) {\AA}, Z = 16, V = 901.4(1) {\AA}3, Dcalc = 2.049 g cm-3, R1 = 0.0308.",

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N2 - The hydrothermal reaction of silver nitrate with 4,4′-dipyridylamine (Hdpa) yields a new Ag(I) two-dimensional network material, [Ag(dpa)]. The structure is constructed from trigonal Ag(I) sites bound to two nitrogen donors from adjacent dpa- ligands and the central deprotonated nitrogen of the dpa- ligand. Crystal data: orthorhombic Cmcm, a = 11.0160(8) Å, b = 11.2683(8) Å, c = 7.2619(5) Å, Z = 16, V = 901.4(1) Å3, Dcalc = 2.049 g cm-3, R1 = 0.0308.

AB - The hydrothermal reaction of silver nitrate with 4,4′-dipyridylamine (Hdpa) yields a new Ag(I) two-dimensional network material, [Ag(dpa)]. The structure is constructed from trigonal Ag(I) sites bound to two nitrogen donors from adjacent dpa- ligands and the central deprotonated nitrogen of the dpa- ligand. Crystal data: orthorhombic Cmcm, a = 11.0160(8) Å, b = 11.2683(8) Å, c = 7.2619(5) Å, Z = 16, V = 901.4(1) Å3, Dcalc = 2.049 g cm-3, R1 = 0.0308.

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