Structure directing role of a tridentate ligand in a two-dimensional Ag(I) network

Randy S. Rarig, Jon Zubieta

Research output: Contribution to journalArticle

7 Scopus citations

Abstract

The hydrothermal reaction of silver nitrate with 4,4′-dipyridylamine (Hdpa) yields a new Ag(I) two-dimensional network material, [Ag(dpa)]. The structure is constructed from trigonal Ag(I) sites bound to two nitrogen donors from adjacent dpa- ligands and the central deprotonated nitrogen of the dpa- ligand. Crystal data: orthorhombic Cmcm, a = 11.0160(8) Å, b = 11.2683(8) Å, c = 7.2619(5) Å, Z = 16, V = 901.4(1) Å3, Dcalc = 2.049 g cm-3, R1 = 0.0308.

Original languageEnglish (US)
Pages (from-to)211-214
Number of pages4
JournalInorganica Chimica Acta
Volume340
DOIs
StatePublished - Nov 25 2002

Keywords

  • Hydrothermal synthesis
  • Silver networks
  • Two-dimensional network

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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