Abstract
The hydrothermal reaction of silver nitrate with 4,4′-dipyridylamine (Hdpa) yields a new Ag(I) two-dimensional network material, [Ag(dpa)]. The structure is constructed from trigonal Ag(I) sites bound to two nitrogen donors from adjacent dpa- ligands and the central deprotonated nitrogen of the dpa- ligand. Crystal data: orthorhombic Cmcm, a = 11.0160(8) Å, b = 11.2683(8) Å, c = 7.2619(5) Å, Z = 16, V = 901.4(1) Å3, Dcalc = 2.049 g cm-3, R1 = 0.0308.
Original language | English (US) |
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Pages (from-to) | 211-214 |
Number of pages | 4 |
Journal | Inorganica Chimica Acta |
Volume | 340 |
DOIs | |
State | Published - Nov 25 2002 |
Keywords
- Hydrothermal synthesis
- Silver networks
- Two-dimensional network
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
- Materials Chemistry