TY - JOUR
T1 - Structure directing role of a tridentate ligand in a two-dimensional Ag(I) network
AU - Rarig, Randy S.
AU - Zubieta, Jon
N1 - Funding Information:
This work was supported by a grant from the National Science Foundation, CHE 9987471.
PY - 2002/11/25
Y1 - 2002/11/25
N2 - The hydrothermal reaction of silver nitrate with 4,4′-dipyridylamine (Hdpa) yields a new Ag(I) two-dimensional network material, [Ag(dpa)]. The structure is constructed from trigonal Ag(I) sites bound to two nitrogen donors from adjacent dpa- ligands and the central deprotonated nitrogen of the dpa- ligand. Crystal data: orthorhombic Cmcm, a = 11.0160(8) Å, b = 11.2683(8) Å, c = 7.2619(5) Å, Z = 16, V = 901.4(1) Å3, Dcalc = 2.049 g cm-3, R1 = 0.0308.
AB - The hydrothermal reaction of silver nitrate with 4,4′-dipyridylamine (Hdpa) yields a new Ag(I) two-dimensional network material, [Ag(dpa)]. The structure is constructed from trigonal Ag(I) sites bound to two nitrogen donors from adjacent dpa- ligands and the central deprotonated nitrogen of the dpa- ligand. Crystal data: orthorhombic Cmcm, a = 11.0160(8) Å, b = 11.2683(8) Å, c = 7.2619(5) Å, Z = 16, V = 901.4(1) Å3, Dcalc = 2.049 g cm-3, R1 = 0.0308.
KW - Hydrothermal synthesis
KW - Silver networks
KW - Two-dimensional network
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U2 - 10.1016/S0020-1693(02)01055-1
DO - 10.1016/S0020-1693(02)01055-1
M3 - Article
AN - SCOPUS:0037175543
VL - 340
SP - 211
EP - 214
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
SN - 0020-1693
ER -