Structure-directing influences of dipodal organoimine ligands: Hydrothermal synthesis and structure of a three-dimensional cobalt vanadate, [Co3(bpypr)4(H2O)4V6O 18] · 2H2O (bpypr = 1,3-di-4-pyridylpropane)

Robert L. La Duca; Rebecca Ratkoski; Randy S. Rarig; Jon Zubieta

doi:10.1016/S1387-7003(01)00284-2

Structure-directing influences of dipodal organoimine ligands: Hydrothermal synthesis and structure of a three-dimensional cobalt vanadate, [Co₃(bpypr)₄(H₂O)₄V₆O ₁₈] · 2H₂O (bpypr = 1,3-di-4-pyridylpropane)

Robert L. La Duca, Rebecca Ratkoski, Randy S. Rarig, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

The hydrothermal reaction of COCl₂ · ₆H₂O, NaVO₃, 1,3-di-4-pyridylpropane (bpypr) and water in the mole ratio 1.0:1.1:2.0:1500 at 120°C for 48 h yields [Co₃(bpypr)₄(H₂O)₄V₆O ₁₈] · 2H₂O (1 · 2H₂O) as red crystals in 45% yield. The structure of 1 is constructed from three distinct substructures: two-dimensional {Co(bpypr)₂}_n²ⁿ⁺ networks, one-dimensional {Co(H₂O)₂(bpypr)}_n²ⁿ⁺ chains and vanadate spirals. Each vanadate chain links two adjacent networks, while vanadate and cobalt chains interlink to form a three-dimensional framework. Crystal data for C₂₆H₃₄N₆O₁₂Co_1.5V ₃: monoclinic P2₁/n, a = 13.0977(7) Å, b = 16.5226(a) Å, c = 15.3842(8) Å, β = 102.246(1)°, V = 3253.5(3) Å³, Z = 4, D calc. = 1.706 g cm^-3. Synopsis: The hydrothermal reaction of COCl₂ · 6H₂O, NaVO₃, 1,3-di-4-pyridylpropane (bpypr) and water yields the three-dimensional organic-inorganic hybrid material [Co₃(bpypr)₄(H₂O)₄V₆O ₁₈] · 2H₂O, shown below.

Original language	English (US)
Pages (from-to)	621-625
Number of pages	5
Journal	Inorganic Chemistry Communications
Volume	4
Issue number	11
DOIs	https://doi.org/10.1016/S1387-7003(01)00284-2
State	Published - 2001

Keywords

Bimetallic oxide
Cobalt vanadate
Hybrid material
Hydrothermal synthesis

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S1387-7003(01)00284-2

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La Duca, R. L., Ratkoski, R., Rarig, R. S., & Zubieta, J. (2001). Structure-directing influences of dipodal organoimine ligands: Hydrothermal synthesis and structure of a three-dimensional cobalt vanadate, [Co₃(bpypr)₄(H₂O)₄V₆O ₁₈] · 2H₂O (bpypr = 1,3-di-4-pyridylpropane). Inorganic Chemistry Communications, 4(11), 621-625. https://doi.org/10.1016/S1387-7003(01)00284-2

Structure-directing influences of dipodal organoimine ligands: Hydrothermal synthesis and structure of a three-dimensional cobalt vanadate, [Co₃(bpypr)₄(H₂O)₄V₆O ₁₈] · 2H₂O (bpypr = 1,3-di-4-pyridylpropane). / La Duca, Robert L.; Ratkoski, Rebecca; Rarig, Randy S. et al.
In: Inorganic Chemistry Communications, Vol. 4, No. 11, 2001, p. 621-625.

Research output: Contribution to journal › Article › peer-review

La Duca, RL, Ratkoski, R, Rarig, RS & Zubieta, J 2001, 'Structure-directing influences of dipodal organoimine ligands: Hydrothermal synthesis and structure of a three-dimensional cobalt vanadate, [Co₃(bpypr)₄(H₂O)₄V₆O ₁₈] · 2H₂O (bpypr = 1,3-di-4-pyridylpropane)', Inorganic Chemistry Communications, vol. 4, no. 11, pp. 621-625. https://doi.org/10.1016/S1387-7003(01)00284-2

@article{6f831c2be2b0462f906064b55725d742,

title = "Structure-directing influences of dipodal organoimine ligands: Hydrothermal synthesis and structure of a three-dimensional cobalt vanadate, [Co3(bpypr)4(H2O)4V6O 18] · 2H2O (bpypr = 1,3-di-4-pyridylpropane)",

abstract = "The hydrothermal reaction of COCl2 · 6H2O, NaVO3, 1,3-di-4-pyridylpropane (bpypr) and water in the mole ratio 1.0:1.1:2.0:1500 at 120°C for 48 h yields [Co3(bpypr)4(H2O)4V6O 18] · 2H2O (1 · 2H2O) as red crystals in 45% yield. The structure of 1 is constructed from three distinct substructures: two-dimensional {Co(bpypr)2}n2n+ networks, one-dimensional {Co(H2O)2(bpypr)}n2n+ chains and vanadate spirals. Each vanadate chain links two adjacent networks, while vanadate and cobalt chains interlink to form a three-dimensional framework. Crystal data for C26H34N6O12Co1.5V 3: monoclinic P21/n, a = 13.0977(7) {\AA}, b = 16.5226(a) {\AA}, c = 15.3842(8) {\AA}, β = 102.246(1)°, V = 3253.5(3) {\AA}3, Z = 4, D calc. = 1.706 g cm-3. Synopsis: The hydrothermal reaction of COCl2 · 6H2O, NaVO3, 1,3-di-4-pyridylpropane (bpypr) and water yields the three-dimensional organic-inorganic hybrid material [Co3(bpypr)4(H2O)4V6O 18] · 2H2O, shown below.",

keywords = "Bimetallic oxide, Cobalt vanadate, Hybrid material, Hydrothermal synthesis",

author = "{La Duca}, {Robert L.} and Rebecca Ratkoski and Rarig, {Randy S.} and Jon Zubieta",

note = "Funding Information: This work was supported by NSF grant CHE 9987471. ",

year = "2001",

doi = "10.1016/S1387-7003(01)00284-2",

language = "English (US)",

volume = "4",

pages = "621--625",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier",

number = "11",

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TY - JOUR

T1 - Structure-directing influences of dipodal organoimine ligands

T2 - Hydrothermal synthesis and structure of a three-dimensional cobalt vanadate, [Co3(bpypr)4(H2O)4V6O 18] · 2H2O (bpypr = 1,3-di-4-pyridylpropane)

AU - La Duca, Robert L.

AU - Ratkoski, Rebecca

AU - Rarig, Randy S.

AU - Zubieta, Jon

N1 - Funding Information: This work was supported by NSF grant CHE 9987471.

PY - 2001

Y1 - 2001

N2 - The hydrothermal reaction of COCl2 · 6H2O, NaVO3, 1,3-di-4-pyridylpropane (bpypr) and water in the mole ratio 1.0:1.1:2.0:1500 at 120°C for 48 h yields [Co3(bpypr)4(H2O)4V6O 18] · 2H2O (1 · 2H2O) as red crystals in 45% yield. The structure of 1 is constructed from three distinct substructures: two-dimensional {Co(bpypr)2}n2n+ networks, one-dimensional {Co(H2O)2(bpypr)}n2n+ chains and vanadate spirals. Each vanadate chain links two adjacent networks, while vanadate and cobalt chains interlink to form a three-dimensional framework. Crystal data for C26H34N6O12Co1.5V 3: monoclinic P21/n, a = 13.0977(7) Å, b = 16.5226(a) Å, c = 15.3842(8) Å, β = 102.246(1)°, V = 3253.5(3) Å3, Z = 4, D calc. = 1.706 g cm-3. Synopsis: The hydrothermal reaction of COCl2 · 6H2O, NaVO3, 1,3-di-4-pyridylpropane (bpypr) and water yields the three-dimensional organic-inorganic hybrid material [Co3(bpypr)4(H2O)4V6O 18] · 2H2O, shown below.

AB - The hydrothermal reaction of COCl2 · 6H2O, NaVO3, 1,3-di-4-pyridylpropane (bpypr) and water in the mole ratio 1.0:1.1:2.0:1500 at 120°C for 48 h yields [Co3(bpypr)4(H2O)4V6O 18] · 2H2O (1 · 2H2O) as red crystals in 45% yield. The structure of 1 is constructed from three distinct substructures: two-dimensional {Co(bpypr)2}n2n+ networks, one-dimensional {Co(H2O)2(bpypr)}n2n+ chains and vanadate spirals. Each vanadate chain links two adjacent networks, while vanadate and cobalt chains interlink to form a three-dimensional framework. Crystal data for C26H34N6O12Co1.5V 3: monoclinic P21/n, a = 13.0977(7) Å, b = 16.5226(a) Å, c = 15.3842(8) Å, β = 102.246(1)°, V = 3253.5(3) Å3, Z = 4, D calc. = 1.706 g cm-3. Synopsis: The hydrothermal reaction of COCl2 · 6H2O, NaVO3, 1,3-di-4-pyridylpropane (bpypr) and water yields the three-dimensional organic-inorganic hybrid material [Co3(bpypr)4(H2O)4V6O 18] · 2H2O, shown below.

KW - Bimetallic oxide

KW - Cobalt vanadate

KW - Hybrid material

KW - Hydrothermal synthesis

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DO - 10.1016/S1387-7003(01)00284-2

M3 - Article

AN - SCOPUS:0034771242

SN - 1387-7003

VL - 4

SP - 621

EP - 625

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 11

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