Structure and magnetic properties of a pyrophosphate-bridged Cu(II) complex

P. E. Kruger, R. P. Doyle, M. Julve, F. Lloret, M. Nieuwenhuyzen

Research output: Contribution to journalArticle

53 Scopus citations

Abstract

The reaction of a Cu(II) salt, 2,2′-bipyridine (bipy), and Na4P2O7·4H2O in aqueous solution affords the novel dinuclear complex {[(bipy)Cu(H2O)]2(μ-P2O7)] ·7H2O} (1), where pyrophosphate adopts a bis-bidentate bridging mode; the weak antiferromagnetic coupling through the pyrophosphate bridge in 1 (J = -20 cm-1; H = -JŜ1·Ŝ2) is much increased in its fully anhydrous phase (J = -110 cm-1).

Original languageEnglish (US)
Pages (from-to)1726-1727
Number of pages2
JournalInorganic Chemistry
Volume40
Issue number8
DOIs
StatePublished - Apr 9 2001
Externally publishedYes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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