Structural influences of ligand geometry and charge-compensating oxoanion on a Ag(I)-organodiimine coordination complex polymer

Randy S. Rarig; Jon Zubieta

doi:10.1016/S0020-1693(01)00458-3

Structural influences of ligand geometry and charge-compensating oxoanion on a Ag(I)-organodiimine coordination complex polymer

Randy S. Rarig, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article

15 Scopus citations

Abstract

The hydrothermal reaction of silver nitrate with trans-1-(2-pyridyl)-2-(4-pyridyl)ethylene (2,4-bpye) yields a new Ag(I) organodiimine coordination complex polymer [Ag(NO₃)(2,4′-bpye)]. The structure of the complex is constructed from one-dimensional {Ag(2,4′-bpye)}_nⁿ⁺ sinusoidal chains in which the Ag(I) site has a distorted trigonal or 'T' shaped geometry through bonding to two pyridyl nitrogen atoms from the ligand and an oxygen from the nitrate anion. Crystal data: orthorhombic Pna2_1, a = 10.9754(6), b = 16.0285(9), c = 13.3326(8) Å, Z = 4, V = 2345.5 Å³, D_calc = 1.994 g cm³, R₁ = 0.0633.

Original language	English (US)
Pages (from-to)	235-239
Number of pages	5
Journal	Inorganica Chimica Acta
Volume	319
Issue number	1-2
DOIs	https://doi.org/10.1016/S0020-1693(01)00458-3
State	Published - Jul 16 2001

Keywords

Coordination polymer complexes
Crystal structures
Diimine complexes
Silver complexes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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Rarig, R. S., & Zubieta, J. (2001). Structural influences of ligand geometry and charge-compensating oxoanion on a Ag(I)-organodiimine coordination complex polymer. Inorganica Chimica Acta, 319(1-2), 235-239. https://doi.org/10.1016/S0020-1693(01)00458-3

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title = "Structural influences of ligand geometry and charge-compensating oxoanion on a Ag(I)-organodiimine coordination complex polymer",

abstract = "The hydrothermal reaction of silver nitrate with trans-1-(2-pyridyl)-2-(4-pyridyl)ethylene (2,4-bpye) yields a new Ag(I) organodiimine coordination complex polymer [Ag(NO3)(2,4′-bpye)]. The structure of the complex is constructed from one-dimensional {Ag(2,4′-bpye)}nn+ sinusoidal chains in which the Ag(I) site has a distorted trigonal or 'T' shaped geometry through bonding to two pyridyl nitrogen atoms from the ligand and an oxygen from the nitrate anion. Crystal data: orthorhombic Pna21, a = 10.9754(6), b = 16.0285(9), c = 13.3326(8) {\AA}, Z = 4, V = 2345.5 {\AA}3, Dcalc = 1.994 g cm3, R1 = 0.0633.",

keywords = "Coordination polymer complexes, Crystal structures, Diimine complexes, Silver complexes",

author = "Rarig, {Randy S.} and Jon Zubieta",

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AU - Rarig, Randy S.

AU - Zubieta, Jon

PY - 2001/7/16

Y1 - 2001/7/16

N2 - The hydrothermal reaction of silver nitrate with trans-1-(2-pyridyl)-2-(4-pyridyl)ethylene (2,4-bpye) yields a new Ag(I) organodiimine coordination complex polymer [Ag(NO3)(2,4′-bpye)]. The structure of the complex is constructed from one-dimensional {Ag(2,4′-bpye)}nn+ sinusoidal chains in which the Ag(I) site has a distorted trigonal or 'T' shaped geometry through bonding to two pyridyl nitrogen atoms from the ligand and an oxygen from the nitrate anion. Crystal data: orthorhombic Pna21, a = 10.9754(6), b = 16.0285(9), c = 13.3326(8) Å, Z = 4, V = 2345.5 Å3, Dcalc = 1.994 g cm3, R1 = 0.0633.

AB - The hydrothermal reaction of silver nitrate with trans-1-(2-pyridyl)-2-(4-pyridyl)ethylene (2,4-bpye) yields a new Ag(I) organodiimine coordination complex polymer [Ag(NO3)(2,4′-bpye)]. The structure of the complex is constructed from one-dimensional {Ag(2,4′-bpye)}nn+ sinusoidal chains in which the Ag(I) site has a distorted trigonal or 'T' shaped geometry through bonding to two pyridyl nitrogen atoms from the ligand and an oxygen from the nitrate anion. Crystal data: orthorhombic Pna21, a = 10.9754(6), b = 16.0285(9), c = 13.3326(8) Å, Z = 4, V = 2345.5 Å3, Dcalc = 1.994 g cm3, R1 = 0.0633.

KW - Coordination polymer complexes

KW - Crystal structures

KW - Diimine complexes

KW - Silver complexes

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