TY - JOUR
T1 - Structural influences of ligand geometry and charge-compensating oxoanion on a Ag(I)-organodiimine coordination complex polymer
AU - Rarig, Randy S.
AU - Zubieta, Jon
N1 - Funding Information:
This work was supported by a grant from the National Science Foundation, CHE 9987471.
Copyright:
Copyright 2020 Elsevier B.V., All rights reserved.
PY - 2001/7/16
Y1 - 2001/7/16
N2 - The hydrothermal reaction of silver nitrate with trans-1-(2-pyridyl)-2-(4-pyridyl)ethylene (2,4-bpye) yields a new Ag(I) organodiimine coordination complex polymer [Ag(NO3)(2,4′-bpye)]. The structure of the complex is constructed from one-dimensional {Ag(2,4′-bpye)}nn+ sinusoidal chains in which the Ag(I) site has a distorted trigonal or 'T' shaped geometry through bonding to two pyridyl nitrogen atoms from the ligand and an oxygen from the nitrate anion. Crystal data: orthorhombic Pna21, a = 10.9754(6), b = 16.0285(9), c = 13.3326(8) Å, Z = 4, V = 2345.5 Å3, Dcalc = 1.994 g cm3, R1 = 0.0633.
AB - The hydrothermal reaction of silver nitrate with trans-1-(2-pyridyl)-2-(4-pyridyl)ethylene (2,4-bpye) yields a new Ag(I) organodiimine coordination complex polymer [Ag(NO3)(2,4′-bpye)]. The structure of the complex is constructed from one-dimensional {Ag(2,4′-bpye)}nn+ sinusoidal chains in which the Ag(I) site has a distorted trigonal or 'T' shaped geometry through bonding to two pyridyl nitrogen atoms from the ligand and an oxygen from the nitrate anion. Crystal data: orthorhombic Pna21, a = 10.9754(6), b = 16.0285(9), c = 13.3326(8) Å, Z = 4, V = 2345.5 Å3, Dcalc = 1.994 g cm3, R1 = 0.0633.
KW - Coordination polymer complexes
KW - Crystal structures
KW - Diimine complexes
KW - Silver complexes
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U2 - 10.1016/S0020-1693(01)00458-3
DO - 10.1016/S0020-1693(01)00458-3
M3 - Article
AN - SCOPUS:0035898866
SN - 0020-1693
VL - 319
SP - 235
EP - 239
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
IS - 1-2
ER -