Abstract
The hydrothermal reaction of silver nitrate with trans-1-(2-pyridyl)-2-(4-pyridyl)ethylene (2,4-bpye) yields a new Ag(I) organodiimine coordination complex polymer [Ag(NO3)(2,4′-bpye)]. The structure of the complex is constructed from one-dimensional {Ag(2,4′-bpye)}nn+ sinusoidal chains in which the Ag(I) site has a distorted trigonal or 'T' shaped geometry through bonding to two pyridyl nitrogen atoms from the ligand and an oxygen from the nitrate anion. Crystal data: orthorhombic Pna21, a = 10.9754(6), b = 16.0285(9), c = 13.3326(8) Å, Z = 4, V = 2345.5 Å3, Dcalc = 1.994 g cm3, R1 = 0.0633.
Original language | English (US) |
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Pages (from-to) | 235-239 |
Number of pages | 5 |
Journal | Inorganica Chimica Acta |
Volume | 319 |
Issue number | 1-2 |
DOIs | |
State | Published - Jul 16 2001 |
Keywords
- Coordination polymer complexes
- Crystal structures
- Diimine complexes
- Silver complexes
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
- Materials Chemistry