Structural influences of ligand geometry and charge-compensating oxoanion on a Ag(I)-organodiimine coordination complex polymer

Randy S. Rarig, Jon Zubieta

Research output: Contribution to journalArticle

15 Scopus citations

Abstract

The hydrothermal reaction of silver nitrate with trans-1-(2-pyridyl)-2-(4-pyridyl)ethylene (2,4-bpye) yields a new Ag(I) organodiimine coordination complex polymer [Ag(NO3)(2,4′-bpye)]. The structure of the complex is constructed from one-dimensional {Ag(2,4′-bpye)}nn+ sinusoidal chains in which the Ag(I) site has a distorted trigonal or 'T' shaped geometry through bonding to two pyridyl nitrogen atoms from the ligand and an oxygen from the nitrate anion. Crystal data: orthorhombic Pna21, a = 10.9754(6), b = 16.0285(9), c = 13.3326(8) Å, Z = 4, V = 2345.5 Å3, Dcalc = 1.994 g cm3, R1 = 0.0633.

Original languageEnglish (US)
Pages (from-to)235-239
Number of pages5
JournalInorganica Chimica Acta
Volume319
Issue number1-2
DOIs
StatePublished - Jul 16 2001

Keywords

  • Coordination polymer complexes
  • Crystal structures
  • Diimine complexes
  • Silver complexes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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