Structural consequences of fluoride incorporation into oxovanadium- xylyldiphosphonates with charge compensating copper(II)-imine components

Tiffany M. Smith; Luke Strauskulage; Kathryn A. Perrin; Diona Symester; Steven R. Freund; Jose Vargas; Leonard Spinu; Jon Zubieta

doi:10.1016/j.ica.2013.11.017

Structural consequences of fluoride incorporation into oxovanadium- xylyldiphosphonates with charge compensating copper(II)-imine components

Tiffany M. Smith, Luke Strauskulage, Kathryn A. Perrin, Diona Symester, Steven R. Freund, Jose Vargas, Leonard Spinu, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

The hydrothermal reactions of V₂O₅, Cu(CH ₃CO₂)₂·H₂O, an appropriate imine, a xylyl-diphosphonic acid and HF in low HF/V ratio yielded the bimetallic xylyldiphosphonate phases, [Cu(o-phen)VO₂(1,2-HO₃PC ₈H₈PO₃)] (1) and [Cu₂(dpa) ₂V₂O₅(1,3-O₃PC₈H ₈PO₃)] (2). When the HF/V ratio was increased to ca. 23:1, a series of materials of the V_xF_yO_z/copper- imine/xylyldiphosphonate family were prepared. These include the one-dimensional [Cu₂(o-phen)₂V₂F₂O ₄(H₂O)(1,3-O₃PC₈H₈PO ₃)] (3), the two-dimensional [Cu₂(o-phen) ₂V₂F₂O₄(1,4-O₃PC ₈H₈PO₃)] (4), [Cu₂(dpa) ₂V₂F₂O₄(1,2-O₃PC ₈H₈PO₃)] (5) and [Cu₂(dpa) ₂V₂F₂O₄(1,3-O₃PC ₈H₈PO₃)] (6·H₂O), and the three-dimensional [Cu₂(bpy)₂V₂F ₂O₄(1,4-O₃PC₈H₈PO ₃)] (7) and [{Cu₂(tpyprz)(H₂O) ₂}V₂F₂O₄(1,3-O₃PC ₈H₈PO₃)] (8·2H₂O). The influences of structural determinants such as the xylyldiphosphonate geometry, the identity of the imine coligand and fluoride substitution for oxide are discussed.

Original language	English (US)
Pages (from-to)	134-147
Number of pages	14
Journal	Inorganica Chimica Acta
Volume	411
DOIs	https://doi.org/10.1016/j.ica.2013.11.017
State	Published - Feb 24 2014

Keywords

Bimetallic xylyldiphosphonates
Magnetism of copper vanadates
Oxyfluorovanadates
X-ray structures of metal oxyfluorides

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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@article{bdc56f952b514f46b5c11695e58a7354,

title = "Structural consequences of fluoride incorporation into oxovanadium- xylyldiphosphonates with charge compensating copper(II)-imine components",

abstract = "The hydrothermal reactions of V2O5, Cu(CH 3CO2)2·H2O, an appropriate imine, a xylyl-diphosphonic acid and HF in low HF/V ratio yielded the bimetallic xylyldiphosphonate phases, [Cu(o-phen)VO2(1,2-HO3PC 8H8PO3)] (1) and [Cu2(dpa) 2V2O5(1,3-O3PC8H 8PO3)] (2). When the HF/V ratio was increased to ca. 23:1, a series of materials of the VxFyOz/copper- imine/xylyldiphosphonate family were prepared. These include the one-dimensional [Cu2(o-phen)2V2F2O 4(H2O)(1,3-O3PC8H8PO 3)] (3), the two-dimensional [Cu2(o-phen) 2V2F2O4(1,4-O3PC 8H8PO3)] (4), [Cu2(dpa) 2V2F2O4(1,2-O3PC 8H8PO3)] (5) and [Cu2(dpa) 2V2F2O4(1,3-O3PC 8H8PO3)] (6·H2O), and the three-dimensional [Cu2(bpy)2V2F 2O4(1,4-O3PC8H8PO 3)] (7) and [{Cu2(tpyprz)(H2O) 2}V2F2O4(1,3-O3PC 8H8PO3)] (8·2H2O). The influences of structural determinants such as the xylyldiphosphonate geometry, the identity of the imine coligand and fluoride substitution for oxide are discussed.",

keywords = "Bimetallic xylyldiphosphonates, Magnetism of copper vanadates, Oxyfluorovanadates, X-ray structures of metal oxyfluorides",

author = "Smith, {Tiffany M.} and Luke Strauskulage and Perrin, {Kathryn A.} and Diona Symester and Freund, {Steven R.} and Jose Vargas and Leonard Spinu and Jon Zubieta",

note = "Funding Information: This work was funded by a grant from the National Science Foundation (CHE-0907787). ",

year = "2014",

month = feb,

day = "24",

doi = "10.1016/j.ica.2013.11.017",

language = "English (US)",

volume = "411",

pages = "134--147",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier",

}

TY - JOUR

T1 - Structural consequences of fluoride incorporation into oxovanadium- xylyldiphosphonates with charge compensating copper(II)-imine components

AU - Smith, Tiffany M.

AU - Strauskulage, Luke

AU - Perrin, Kathryn A.

AU - Symester, Diona

AU - Freund, Steven R.

AU - Vargas, Jose

AU - Spinu, Leonard

AU - Zubieta, Jon

N1 - Funding Information: This work was funded by a grant from the National Science Foundation (CHE-0907787).

PY - 2014/2/24

Y1 - 2014/2/24

N2 - The hydrothermal reactions of V2O5, Cu(CH 3CO2)2·H2O, an appropriate imine, a xylyl-diphosphonic acid and HF in low HF/V ratio yielded the bimetallic xylyldiphosphonate phases, [Cu(o-phen)VO2(1,2-HO3PC 8H8PO3)] (1) and [Cu2(dpa) 2V2O5(1,3-O3PC8H 8PO3)] (2). When the HF/V ratio was increased to ca. 23:1, a series of materials of the VxFyOz/copper- imine/xylyldiphosphonate family were prepared. These include the one-dimensional [Cu2(o-phen)2V2F2O 4(H2O)(1,3-O3PC8H8PO 3)] (3), the two-dimensional [Cu2(o-phen) 2V2F2O4(1,4-O3PC 8H8PO3)] (4), [Cu2(dpa) 2V2F2O4(1,2-O3PC 8H8PO3)] (5) and [Cu2(dpa) 2V2F2O4(1,3-O3PC 8H8PO3)] (6·H2O), and the three-dimensional [Cu2(bpy)2V2F 2O4(1,4-O3PC8H8PO 3)] (7) and [{Cu2(tpyprz)(H2O) 2}V2F2O4(1,3-O3PC 8H8PO3)] (8·2H2O). The influences of structural determinants such as the xylyldiphosphonate geometry, the identity of the imine coligand and fluoride substitution for oxide are discussed.

AB - The hydrothermal reactions of V2O5, Cu(CH 3CO2)2·H2O, an appropriate imine, a xylyl-diphosphonic acid and HF in low HF/V ratio yielded the bimetallic xylyldiphosphonate phases, [Cu(o-phen)VO2(1,2-HO3PC 8H8PO3)] (1) and [Cu2(dpa) 2V2O5(1,3-O3PC8H 8PO3)] (2). When the HF/V ratio was increased to ca. 23:1, a series of materials of the VxFyOz/copper- imine/xylyldiphosphonate family were prepared. These include the one-dimensional [Cu2(o-phen)2V2F2O 4(H2O)(1,3-O3PC8H8PO 3)] (3), the two-dimensional [Cu2(o-phen) 2V2F2O4(1,4-O3PC 8H8PO3)] (4), [Cu2(dpa) 2V2F2O4(1,2-O3PC 8H8PO3)] (5) and [Cu2(dpa) 2V2F2O4(1,3-O3PC 8H8PO3)] (6·H2O), and the three-dimensional [Cu2(bpy)2V2F 2O4(1,4-O3PC8H8PO 3)] (7) and [{Cu2(tpyprz)(H2O) 2}V2F2O4(1,3-O3PC 8H8PO3)] (8·2H2O). The influences of structural determinants such as the xylyldiphosphonate geometry, the identity of the imine coligand and fluoride substitution for oxide are discussed.

KW - Bimetallic xylyldiphosphonates

KW - Magnetism of copper vanadates

KW - Oxyfluorovanadates

KW - X-ray structures of metal oxyfluorides

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U2 - 10.1016/j.ica.2013.11.017

DO - 10.1016/j.ica.2013.11.017

M3 - Article

AN - SCOPUS:84891884338

SN - 0020-1693

VL - 411

SP - 134

EP - 147

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

ER -

Structural consequences of fluoride incorporation into oxovanadium- xylyldiphosphonates with charge compensating copper(II)-imine components

Abstract

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