Structural comparison of CuI and CuII complexes displaying analogous N2S2 co-ordination; X-ray analyses of tetraco-ordinate [cu(Pma)]BPh4 and pentaco-ordinate [Cu(pma)SO4 [pma = 2-pyridylmethylbis-(2-ethylthioethyl)amine]

Kenneth D. Karlin, Phillip L. Dahlstrom, Jeffrey R. Hyde, Jon Zubieta

Research output: Contribution to journalArticle

72 Scopus citations

Abstract

The synthesis and X-ray structural characterization of the CuI and CuII complexes [Cu(pma)]BPh4 and [Cu(pma)SO4] [pma — 2-pyndylmethylbis-(2-ethylthioethyl)amme] are reported, both display N2S2 co-ordmation with the CuI complex exhibiting trigonal pyramidal geometry while the CuII derivative shows a distorted trigonal bipyramidal geometry which includes a coordmated sulphate group.

Original languageEnglish (US)
Pages (from-to)906-908
Number of pages3
JournalJournal of the Chemical Society - Series Chemical Communications
Issue number19
DOIs
StatePublished - Jan 1 1980
Externally publishedYes

ASJC Scopus subject areas

  • Molecular Medicine

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