Structural comparison of CuI and CuII complexes displaying analogous N2S2 co-ordination; X-ray analyses of tetraco-ordinate [cu(Pma)]BPh4 and pentaco-ordinate [Cu(pma)SO4 [pma = 2-pyridylmethylbis-(2-ethylthioethyl)amine]

Kenneth D. Karlin; Phillip L. Dahlstrom; Jeffrey R. Hyde; Jon Zubieta

doi:10.1039/C39800000906

Structural comparison of Cu^I and Cu^II complexes displaying analogous N₂S₂ co-ordination; X-ray analyses of tetraco-ordinate [cu(Pma)]BPh₄ and pentaco-ordinate [Cu(pma)SO₄ [pma = 2-pyridylmethylbis-(2-ethylthioethyl)amine]

Kenneth D. Karlin, Phillip L. Dahlstrom, Jeffrey R. Hyde, Jon Zubieta

Research output: Contribution to journal › Article › peer-review

77 Scopus citations

Abstract

The synthesis and X-ray structural characterization of the Cu^I and Cu^II complexes [Cu(pma)]BPh₄ and [Cu(pma)SO₄] [pma — 2-pyndylmethylbis-(2-ethylthioethyl)amme] are reported, both display N₂S₂ co-ordmation with the Cu^I complex exhibiting trigonal pyramidal geometry while the Cu^II derivative shows a distorted trigonal bipyramidal geometry which includes a coordmated sulphate group.

Original language	English (US)
Pages (from-to)	906-908
Number of pages	3
Journal	Journal of the Chemical Society - Series Chemical Communications
Issue number	19
DOIs	https://doi.org/10.1039/C39800000906
State	Published - 1980
Externally published	Yes

ASJC Scopus subject areas

Molecular Medicine

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Karlin, K. D., Dahlstrom, P. L., Hyde, J. R., & Zubieta, J. (1980). Structural comparison of Cu^I and Cu^II complexes displaying analogous N₂S₂ co-ordination; X-ray analyses of tetraco-ordinate [cu(Pma)]BPh₄ and pentaco-ordinate [Cu(pma)SO₄ [pma = 2-pyridylmethylbis-(2-ethylthioethyl)amine]. Journal of the Chemical Society - Series Chemical Communications, (19), 906-908. https://doi.org/10.1039/C39800000906

Structural comparison of Cu^I and Cu^II complexes displaying analogous N₂S₂ co-ordination; X-ray analyses of tetraco-ordinate [cu(Pma)]BPh₄ and pentaco-ordinate [Cu(pma)SO₄ [pma = 2-pyridylmethylbis-(2-ethylthioethyl)amine]. / Karlin, Kenneth D.; Dahlstrom, Phillip L.; Hyde, Jeffrey R. et al.
In: Journal of the Chemical Society - Series Chemical Communications, No. 19, 1980, p. 906-908.

Research output: Contribution to journal › Article › peer-review

Karlin, KD, Dahlstrom, PL, Hyde, JR & Zubieta, J 1980, 'Structural comparison of Cu^I and Cu^II complexes displaying analogous N₂S₂ co-ordination; X-ray analyses of tetraco-ordinate [cu(Pma)]BPh₄ and pentaco-ordinate [Cu(pma)SO₄ [pma = 2-pyridylmethylbis-(2-ethylthioethyl)amine]', Journal of the Chemical Society - Series Chemical Communications, no. 19, pp. 906-908. https://doi.org/10.1039/C39800000906

Karlin KD, Dahlstrom PL, Hyde JR, Zubieta J. Structural comparison of Cu^I and Cu^II complexes displaying analogous N₂S₂ co-ordination; X-ray analyses of tetraco-ordinate [cu(Pma)]BPh₄ and pentaco-ordinate [Cu(pma)SO₄ [pma = 2-pyridylmethylbis-(2-ethylthioethyl)amine]. Journal of the Chemical Society - Series Chemical Communications. 1980;(19):906-908. doi: 10.1039/C39800000906

Karlin, Kenneth D. ; Dahlstrom, Phillip L. ; Hyde, Jeffrey R. et al. / Structural comparison of Cu^I and Cu^II complexes displaying analogous N₂S₂ co-ordination; X-ray analyses of tetraco-ordinate [cu(Pma)]BPh₄ and pentaco-ordinate [Cu(pma)SO₄ [pma = 2-pyridylmethylbis-(2-ethylthioethyl)amine]. In: Journal of the Chemical Society - Series Chemical Communications. 1980 ; No. 19. pp. 906-908.

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