Steric Control of Aggregation in Neutral Silver(I) Thiolates, [AgSR]n. Crystal and Molecular Structures of [AgSCH(SiMe3)2]8, a Discrete Molecular Biscycle of Weakly Interacting [AgSCH(SiMe3)2]4 Units, and of [AgSC(SiphMe2)3]3 and [AgSC(SiMe3)3]4, Discrete Molecular Monocycles Containing Linearly Coordinated Silver(I) and Doubly Bridging Mercapto Sulfur Donors from Novel Sterically Hindered Thiolate Ligands. A Comparison with the Nonmolecular Structure of [Ag4{SCH2(SiMe3)}3]n(OMe)n1

Kaluo Tang, Mohammad Aslam, Eric Block, Terrence Nicholson, Jon Zubieta

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