Stereo- and Regioselective Formation of Silyl-Dienyl Boronates

Lauren Kaminsky, Robert J. Wilson, Daniel A. Clark

Research output: Contribution to journalArticle

6 Scopus citations

Abstract

The intramolecular trans-silylruthenation of internal alkynes and subsequent insertion of vinyl boronates is described. This approach provides complete regiocontrol through a stereoselective trans-5-exo-dig cyclization which affords a tetrasubstituted olefin as a vinylsilane and a highly functionalized Z,E diene motif.

Original languageEnglish (US)
Pages (from-to)3126-3129
Number of pages4
JournalOrganic Letters
Volume17
Issue number12
DOIs
StatePublished - Jun 19 2015

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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