Spin canting in an unprecedented three-dimensional pyrophosphate- and 2,2′-bipyrimidine-bridged cobalt(II) framework

Nadia Marino, Teresa F. Mastropietro, Donatella Armentano, Giovanni De Munno, Robert P. Doyle, Francesc Lloret, Miguel Julve

Research output: Contribution to journalArticle

34 Scopus citations

Abstract

The three-dimensional cobalt(ii) compound of formula {[Co 2(P2O7)(bpym)2]̇12H 2O}n, where the pyrophosphate and 2,2′-bipyrimidine act as bridging ligands, is a new example of a spin-canted antiferromagnet with Tc = 19 K.

Original languageEnglish (US)
Pages (from-to)5152-5154
Number of pages3
JournalDalton Transactions
Issue number38
DOIs
StatePublished - Sep 29 2008

ASJC Scopus subject areas

  • Inorganic Chemistry

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