Spin canting in an unprecedented three-dimensional pyrophosphate- and 2,2′-bipyrimidine-bridged cobalt(II) framework

Nadia Marino; Teresa F. Mastropietro; Donatella Armentano; Giovanni De Munno; Robert P. Doyle; Francesc Lloret; Miguel Julve

doi:10.1039/b813097n

Spin canting in an unprecedented three-dimensional pyrophosphate- and 2,2′-bipyrimidine-bridged cobalt(II) framework

Nadia Marino, Teresa F. Mastropietro, Donatella Armentano, Giovanni De Munno, Robert P. Doyle, Francesc Lloret, Miguel Julve

Research output: Contribution to journal › Article › peer-review

37 Scopus citations

Abstract

The three-dimensional cobalt(ii) compound of formula {[Co ₂(P₂O₇)(bpym)₂]̇12H ₂O}_n, where the pyrophosphate and 2,2′-bipyrimidine act as bridging ligands, is a new example of a spin-canted antiferromagnet with T_c = 19 K.

Original language	English (US)
Pages (from-to)	5152-5154
Number of pages	3
Journal	Dalton Transactions
Issue number	38
DOIs	https://doi.org/10.1039/b813097n
State	Published - 2008

ASJC Scopus subject areas

Inorganic Chemistry

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title = "Spin canting in an unprecedented three-dimensional pyrophosphate- and 2,2′-bipyrimidine-bridged cobalt(II) framework",

abstract = "The three-dimensional cobalt(ii) compound of formula {[Co 2(P2O7)(bpym)2{\.]}12H 2O}n, where the pyrophosphate and 2,2′-bipyrimidine act as bridging ligands, is a new example of a spin-canted antiferromagnet with Tc = 19 K.",

author = "Nadia Marino and Mastropietro, {Teresa F.} and Donatella Armentano and {De Munno}, Giovanni and Doyle, {Robert P.} and Francesc Lloret and Miguel Julve",

year = "2008",

doi = "10.1039/b813097n",

language = "English (US)",

pages = "5152--5154",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

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T1 - Spin canting in an unprecedented three-dimensional pyrophosphate- and 2,2′-bipyrimidine-bridged cobalt(II) framework

AU - Marino, Nadia

AU - Mastropietro, Teresa F.

AU - Armentano, Donatella

AU - De Munno, Giovanni

AU - Doyle, Robert P.

AU - Lloret, Francesc

AU - Julve, Miguel

PY - 2008

Y1 - 2008

N2 - The three-dimensional cobalt(ii) compound of formula {[Co 2(P2O7)(bpym)2]̇12H 2O}n, where the pyrophosphate and 2,2′-bipyrimidine act as bridging ligands, is a new example of a spin-canted antiferromagnet with Tc = 19 K.

AB - The three-dimensional cobalt(ii) compound of formula {[Co 2(P2O7)(bpym)2]̇12H 2O}n, where the pyrophosphate and 2,2′-bipyrimidine act as bridging ligands, is a new example of a spin-canted antiferromagnet with Tc = 19 K.

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U2 - 10.1039/b813097n

DO - 10.1039/b813097n

M3 - Article

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AN - SCOPUS:52349086923

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JO - Dalton Transactions

JF - Dalton Transactions

IS - 38

ER -

Spin canting in an unprecedented three-dimensional pyrophosphate- and 2,2′-bipyrimidine-bridged cobalt(II) framework

Abstract

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