TY - JOUR
T1 - Spectroscopic and structural studies of complexes of the fac-[Re(N∩N)(CO)3L]n+ type (N∩N = 2-(2-pyridyl)benzothiazole; L = Cl, Br, CF3SO3-, CH3CN)
AU - Chen, Xiaoyuan
AU - Femia, Frank J.
AU - Babich, John W.
AU - Zubieta, Jon
N1 - Funding Information:
This work was supported by a grant from the Department of Energy (DOE), Office of Health and Environmental Research D2-FG02-99ER62791.
PY - 2001/3/19
Y1 - 2001/3/19
N2 - The reaction of [Re(CO)5X] (where X = Cl or Br) with the bidentate imine donor ligand 2-(2-pyridyl)benzothiazole (N∩N) afforded complexes of the type fac-[Re(N∩N)(CO)3X] (1, X = Cl; 2, X = Br). Dehalogenation of complex 1 or 2 was realized by reaction with silver trifluoromethanesulfonate (silver triflate) to give 3; subsequent reaction of 3 with acetonitrile gave [Re(N∩N)(CO)3(CH3CN)][CF3 SO3-].
AB - The reaction of [Re(CO)5X] (where X = Cl or Br) with the bidentate imine donor ligand 2-(2-pyridyl)benzothiazole (N∩N) afforded complexes of the type fac-[Re(N∩N)(CO)3X] (1, X = Cl; 2, X = Br). Dehalogenation of complex 1 or 2 was realized by reaction with silver trifluoromethanesulfonate (silver triflate) to give 3; subsequent reaction of 3 with acetonitrile gave [Re(N∩N)(CO)3(CH3CN)][CF3 SO3-].
KW - 2-(2-Pyridyl)benzothiazole
KW - Crystal structures
KW - Organometallic complexes
KW - Radiopharmaceuticals
KW - Tricarbonylrhenium(I) core
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U2 - 10.1016/S0020-1693(01)00301-2
DO - 10.1016/S0020-1693(01)00301-2
M3 - Article
AN - SCOPUS:0035911795
SN - 0020-1693
VL - 314
SP - 91
EP - 96
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
IS - 1-2
ER -