Solvatothermal synthesis and crystal structure of (Ph4P)[(VO2)4(CH3CO 2)4cl]

José Salta; Jon Zubieta

doi:10.1016/s0020-1693(96)05325-x

Solvatothermal synthesis and crystal structure of (Ph₄P)[(VO₂)₄(CH₃CO ₂)₄cl]

José Salta, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

The solvatothermal reaction of (Ph₄P)[VO₂Cl₂] with acetic acid in methylene chloride at 110°C for 48 h yields bright red crystals of (Ph₄P)[(VO₂)₄(CH₃CO ₂)₄Cl] (1) in 20% yield. The structure of the anion of 1 consists of a tetrakis(μ-acetato-μ-oxo-oxovanadium) crown with a chloride guest anion occupying the hollow formed by the edge-sharing of the four {VO₅} square pyramids. Crystal data: C₃₂H₃₂O₁₆PClV₄, tetragonal I4₁/a, a = 15.969(2), c = 29.020(5) Å, V = 7400(1) Å³, Z = 8.

Original language	English (US)
Pages (from-to)	435-438
Number of pages	4
Journal	Inorganica Chimica Acta
Volume	252
Issue number	1-2
DOIs	https://doi.org/10.1016/s0020-1693(96)05325-x
State	Published - Nov 1 1996

Keywords

Crystal structures
Oxovanadate complexes
Solvatothermal synthesis

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/s0020-1693(96)05325-x

Cite this

@article{ef885d1939864626b56e0db7eb099d65,

title = "Solvatothermal synthesis and crystal structure of (Ph4P)[(VO2)4(CH3CO 2)4cl]",

abstract = "The solvatothermal reaction of (Ph4P)[VO2Cl2] with acetic acid in methylene chloride at 110°C for 48 h yields bright red crystals of (Ph4P)[(VO2)4(CH3CO 2)4Cl] (1) in 20% yield. The structure of the anion of 1 consists of a tetrakis(μ-acetato-μ-oxo-oxovanadium) crown with a chloride guest anion occupying the hollow formed by the edge-sharing of the four {VO5} square pyramids. Crystal data: C32H32O16PClV4, tetragonal I41/a, a = 15.969(2), c = 29.020(5) {\AA}, V = 7400(1) {\AA}3, Z = 8.",

keywords = "Crystal structures, Oxovanadate complexes, Solvatothermal synthesis",

author = "Jos{\'e} Salta and Jon Zubieta",

note = "Funding Information: This work was supported by NSF grant CHE 9318824.",

year = "1996",

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doi = "10.1016/s0020-1693(96)05325-x",

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volume = "252",

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TY - JOUR

T1 - Solvatothermal synthesis and crystal structure of (Ph4P)[(VO2)4(CH3CO 2)4cl]

AU - Salta, José

AU - Zubieta, Jon

N1 - Funding Information: This work was supported by NSF grant CHE 9318824.

PY - 1996/11/1

Y1 - 1996/11/1

N2 - The solvatothermal reaction of (Ph4P)[VO2Cl2] with acetic acid in methylene chloride at 110°C for 48 h yields bright red crystals of (Ph4P)[(VO2)4(CH3CO 2)4Cl] (1) in 20% yield. The structure of the anion of 1 consists of a tetrakis(μ-acetato-μ-oxo-oxovanadium) crown with a chloride guest anion occupying the hollow formed by the edge-sharing of the four {VO5} square pyramids. Crystal data: C32H32O16PClV4, tetragonal I41/a, a = 15.969(2), c = 29.020(5) Å, V = 7400(1) Å3, Z = 8.

AB - The solvatothermal reaction of (Ph4P)[VO2Cl2] with acetic acid in methylene chloride at 110°C for 48 h yields bright red crystals of (Ph4P)[(VO2)4(CH3CO 2)4Cl] (1) in 20% yield. The structure of the anion of 1 consists of a tetrakis(μ-acetato-μ-oxo-oxovanadium) crown with a chloride guest anion occupying the hollow formed by the edge-sharing of the four {VO5} square pyramids. Crystal data: C32H32O16PClV4, tetragonal I41/a, a = 15.969(2), c = 29.020(5) Å, V = 7400(1) Å3, Z = 8.

KW - Crystal structures

KW - Oxovanadate complexes

KW - Solvatothermal synthesis

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