Solid state coordination chemistry: Two-dimensional oxides constructed from polyoxomolybdate clusters and copper-organoamine subunits

Douglas Hagrman; Claudio Sangregorio; Charles J. O'Connor; Jon Zubieta

doi:10.1039/a806234j

Solid state coordination chemistry: Two-dimensional oxides constructed from polyoxomolybdate clusters and copper-organoamine subunits

Douglas Hagrman, Claudio Sangregorio, Charles J. O'Connor, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

159 Scopus citations

Abstract

Copper-organodiamine substructures are effective bridging groups for polyoxomolybdate anions in the construction of two-dimensional mixed metal networks, of which [{Cu(bpe)}₄(α-Mo₈O₂₆)]·2H ₂O and [{Cu(pyrd)}₄(γ-H₄Mo₈-O₂₆)] are representative [bpe = 1,2-bis(4-pyridyl)ethylene; pyrd = pyridazine].

Original language	English (US)
Pages (from-to)	3707-3709
Number of pages	3
Journal	Journal of the Chemical Society - Dalton Transactions
Issue number	22
DOIs	https://doi.org/10.1039/a806234j
State	Published - Nov 21 1998

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Chemistry(all)

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title = "Solid state coordination chemistry: Two-dimensional oxides constructed from polyoxomolybdate clusters and copper-organoamine subunits",

abstract = "Copper-organodiamine substructures are effective bridging groups for polyoxomolybdate anions in the construction of two-dimensional mixed metal networks, of which [{Cu(bpe)}4(α-Mo8O26)]·2H 2O and [{Cu(pyrd)}4(γ-H4Mo8-O26)] are representative [bpe = 1,2-bis(4-pyridyl)ethylene; pyrd = pyridazine].",

author = "Douglas Hagrman and Claudio Sangregorio and O'Connor, {Charles J.} and Jon Zubieta",

year = "1998",

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doi = "10.1039/a806234j",

language = "English (US)",

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journal = "Dalton Transactions",

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publisher = "Royal Society of Chemistry",

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T1 - Solid state coordination chemistry

T2 - Two-dimensional oxides constructed from polyoxomolybdate clusters and copper-organoamine subunits

AU - Hagrman, Douglas

AU - Sangregorio, Claudio

AU - O'Connor, Charles J.

AU - Zubieta, Jon

PY - 1998/11/21

Y1 - 1998/11/21

N2 - Copper-organodiamine substructures are effective bridging groups for polyoxomolybdate anions in the construction of two-dimensional mixed metal networks, of which [{Cu(bpe)}4(α-Mo8O26)]·2H 2O and [{Cu(pyrd)}4(γ-H4Mo8-O26)] are representative [bpe = 1,2-bis(4-pyridyl)ethylene; pyrd = pyridazine].

AB - Copper-organodiamine substructures are effective bridging groups for polyoxomolybdate anions in the construction of two-dimensional mixed metal networks, of which [{Cu(bpe)}4(α-Mo8O26)]·2H 2O and [{Cu(pyrd)}4(γ-H4Mo8-O26)] are representative [bpe = 1,2-bis(4-pyridyl)ethylene; pyrd = pyridazine].

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Solid state coordination chemistry: Two-dimensional oxides constructed from polyoxomolybdate clusters and copper-organoamine subunits

Abstract

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