Solid state coordination chemistry: The hydrothermal synthesis and structure of a bimetallic oxide incorporating 2,2′:6′,2″-terpyridine (terpy), [{VO(terpy)}MoO4]

Robert C. Finn; Jon Zubieta

doi:10.1016/S0020-1693(02)00703-X

Solid state coordination chemistry: The hydrothermal synthesis and structure of a bimetallic oxide incorporating 2,2′:6′,2″-terpyridine (terpy), [{VO(terpy)}MoO₄]

Robert C. Finn, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

The hydrothermal reaction of MoO₃, Na₃VO₄, 2,2′:6′,2″-terpyridine (terpy) and H₂O in the mole ratio 1.53:1.00:1.30:1460 at pH 3 yields red crystals of [{VO(terpy)}MoO₄] (1) in 55% yield. The structure of 1 is a one-dimensional chain of {VO(terpy)}²⁺ units bridged in the characteristic O,O′-mode by {MoO₄}^2- tetrahedra. Crystal data: C₁₅H₁₁N₃O₅MoV, orthorhombic, P2₁2₁2₁, a=26.145(1) Å, b=6.7607(4) Å, c=9.2496(5) Å, V=1634.9(2) Å³, Z=2, D_calc=1.869 gcm^-3; structure solution and refinement converged at R₁=0.0335 and wR₂=0.0735.

Original language	English (US)
Pages (from-to)	186-190
Number of pages	5
Journal	Inorganica Chimica Acta
Volume	332
Issue number	1
DOIs	https://doi.org/10.1016/S0020-1693(02)00703-X
State	Published - Apr 17 2002

Keywords

Bimetallic oxide
Hydrothermal synthesis
Organic-inorganic hybrid materials
Solid state coordination chemistry
Vanadomolybdate structures

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/S0020-1693(02)00703-X

Cite this

@article{49986f3e1db94b65b8000445c914fdab,

title = "Solid state coordination chemistry: The hydrothermal synthesis and structure of a bimetallic oxide incorporating 2,2′:6′,2″-terpyridine (terpy), [{VO(terpy)}MoO4]",

abstract = "The hydrothermal reaction of MoO3, Na3VO4, 2,2′:6′,2″-terpyridine (terpy) and H2O in the mole ratio 1.53:1.00:1.30:1460 at pH 3 yields red crystals of [{VO(terpy)}MoO4] (1) in 55% yield. The structure of 1 is a one-dimensional chain of {VO(terpy)}2+ units bridged in the characteristic O,O′-mode by {MoO4}2- tetrahedra. Crystal data: C15H11N3O5MoV, orthorhombic, P212121, a=26.145(1) {\AA}, b=6.7607(4) {\AA}, c=9.2496(5) {\AA}, V=1634.9(2) {\AA}3, Z=2, Dcalc=1.869 gcm-3; structure solution and refinement converged at R1=0.0335 and wR2=0.0735.",

keywords = "Bimetallic oxide, Hydrothermal synthesis, Organic-inorganic hybrid materials, Solid state coordination chemistry, Vanadomolybdate structures",

author = "Finn, {Robert C.} and Jon Zubieta",

note = "Funding Information: This work was supported by a grant from the National Science Foundation (CHE 9987471). ",

year = "2002",

month = apr,

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doi = "10.1016/S0020-1693(02)00703-X",

language = "English (US)",

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TY - JOUR

T1 - Solid state coordination chemistry

T2 - The hydrothermal synthesis and structure of a bimetallic oxide incorporating 2,2′:6′,2″-terpyridine (terpy), [{VO(terpy)}MoO4]

AU - Finn, Robert C.

AU - Zubieta, Jon

N1 - Funding Information: This work was supported by a grant from the National Science Foundation (CHE 9987471).

PY - 2002/4/17

Y1 - 2002/4/17

N2 - The hydrothermal reaction of MoO3, Na3VO4, 2,2′:6′,2″-terpyridine (terpy) and H2O in the mole ratio 1.53:1.00:1.30:1460 at pH 3 yields red crystals of [{VO(terpy)}MoO4] (1) in 55% yield. The structure of 1 is a one-dimensional chain of {VO(terpy)}2+ units bridged in the characteristic O,O′-mode by {MoO4}2- tetrahedra. Crystal data: C15H11N3O5MoV, orthorhombic, P212121, a=26.145(1) Å, b=6.7607(4) Å, c=9.2496(5) Å, V=1634.9(2) Å3, Z=2, Dcalc=1.869 gcm-3; structure solution and refinement converged at R1=0.0335 and wR2=0.0735.

AB - The hydrothermal reaction of MoO3, Na3VO4, 2,2′:6′,2″-terpyridine (terpy) and H2O in the mole ratio 1.53:1.00:1.30:1460 at pH 3 yields red crystals of [{VO(terpy)}MoO4] (1) in 55% yield. The structure of 1 is a one-dimensional chain of {VO(terpy)}2+ units bridged in the characteristic O,O′-mode by {MoO4}2- tetrahedra. Crystal data: C15H11N3O5MoV, orthorhombic, P212121, a=26.145(1) Å, b=6.7607(4) Å, c=9.2496(5) Å, V=1634.9(2) Å3, Z=2, Dcalc=1.869 gcm-3; structure solution and refinement converged at R1=0.0335 and wR2=0.0735.

KW - Bimetallic oxide

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KW - Organic-inorganic hybrid materials

KW - Solid state coordination chemistry

KW - Vanadomolybdate structures

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