Solid state coordination chemistry: Temperature dependence of the crystal chemistry of the oxovanadium-phenylphosphonate-copper(II)-2,2′-bipyridine system. Crystal structures of the one-dimensional [{Cu(bpy)}VO 2(O3PC6H5)(HO3PC 6H5)]

Gundog Yucesan; Wayne Ouellette; Vladimir Golub; Charles J. O'Connor; Jon Zubieta

doi:10.1016/j.solidstatesciences.2005.01.009

Solid state coordination chemistry: Temperature dependence of the crystal chemistry of the oxovanadium-phenylphosphonate-copper(II)-2,2′-bipyridine system. Crystal structures of the one-dimensional [{Cu(bpy)}VO ₂(O₃PC₆H₅)(HO₃PC ₆H₅)]

Gundog Yucesan, Wayne Ouellette, Vladimir Golub, Charles J. O'Connor, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

The temperature dependence of the hydrothermal chemistry of the oxovanadium-phenylphosphonate/copper(II)-bipyridine system has been investigated. Reactions of identical compositions of CuSO ₄ṡ5H₂O, bipyridine, C₆H₅PO ₃H₂ and Na₃VO₄ in H₂O yielded [{Cu(bpy)}VO₂(O₃PC₆H ₅)(HOC₆H₅)] (1), [{Cu₃(bpy) ₃(H₂O)}V₄O₉(O₃PC ₆H₅)₄]ṡ3.9H₂O (2ṡ3.9H ₂O) and [{Cu(bpy)}VO(O₃PC₆H₅) ₂] (4) at 120 °C, 150 °C and 180-230 °C, respectively. Furthermore, variations in stoichiometry at 150 °C provided yet a fourth one-dimensional phase [{Cu(bpy)}₂V₃O₆(O ₃PC₆H₅)₃(HO₃PC ₆H₅)] (3). Substitution of a methyl substituent for the phenyl group yielded another one-dimensional material [{Cu(bpy)}V ₂O₄(O₃PCH₃)₂ṡH ₂O (5ṡH₂O). The structural chemistry is discussed in terms of the polyhedral variability of vanadium oxides, the tendency of oxovanadium polyhedra to form oligomeric arrays, the variable modes of polyhedral connectivity associated with vanadium square pyramids and phosphorus tetrahedra and the steric influences of the copper(II)-bpy subunit.

Original language	English (US)
Pages (from-to)	445-458
Number of pages	14
Journal	Solid State Sciences
Volume	7
Issue number	4
DOIs	https://doi.org/10.1016/j.solidstatesciences.2005.01.009
State	Published - Apr 2005

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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Yucesan, G., Ouellette, W., Golub, V., O'Connor, C. J., & Zubieta, J. (2005). Solid state coordination chemistry: Temperature dependence of the crystal chemistry of the oxovanadium-phenylphosphonate-copper(II)-2,2′-bipyridine system. Crystal structures of the one-dimensional [{Cu(bpy)}VO ₂(O₃PC₆H₅)(HO₃PC ₆H₅)]. Solid State Sciences, 7(4), 445-458. https://doi.org/10.1016/j.solidstatesciences.2005.01.009

Solid state coordination chemistry: Temperature dependence of the crystal chemistry of the oxovanadium-phenylphosphonate-copper(II)-2,2′-bipyridine system. Crystal structures of the one-dimensional [{Cu(bpy)}VO ₂(O₃PC₆H₅)(HO₃PC ₆H₅)]. / Yucesan, Gundog; Ouellette, Wayne; Golub, Vladimir et al.
In: Solid State Sciences, Vol. 7, No. 4, 04.2005, p. 445-458.

Research output: Contribution to journal › Article › peer-review

Yucesan, G, Ouellette, W, Golub, V, O'Connor, CJ & Zubieta, J 2005, 'Solid state coordination chemistry: Temperature dependence of the crystal chemistry of the oxovanadium-phenylphosphonate-copper(II)-2,2′-bipyridine system. Crystal structures of the one-dimensional [{Cu(bpy)}VO ₂(O₃PC₆H₅)(HO₃PC ₆H₅)]', Solid State Sciences, vol. 7, no. 4, pp. 445-458. https://doi.org/10.1016/j.solidstatesciences.2005.01.009

Yucesan G, Ouellette W, Golub V, O'Connor CJ, Zubieta J. Solid state coordination chemistry: Temperature dependence of the crystal chemistry of the oxovanadium-phenylphosphonate-copper(II)-2,2′-bipyridine system. Crystal structures of the one-dimensional [{Cu(bpy)}VO ₂(O₃PC₆H₅)(HO₃PC ₆H₅)]. Solid State Sciences. 2005 Apr;7(4):445-458. doi: 10.1016/j.solidstatesciences.2005.01.009

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title = "Solid state coordination chemistry: Temperature dependence of the crystal chemistry of the oxovanadium-phenylphosphonate-copper(II)-2,2′-bipyridine system. Crystal structures of the one-dimensional [{Cu(bpy)}VO 2(O3PC6H5)(HO3PC 6H5)]",

abstract = "The temperature dependence of the hydrothermal chemistry of the oxovanadium-phenylphosphonate/copper(II)-bipyridine system has been investigated. Reactions of identical compositions of CuSO 4ṡ5H2O, bipyridine, C6H5PO 3H2 and Na3VO4 in H2O yielded [{Cu(bpy)}VO2(O3PC6H 5)(HOC6H5)] (1), [{Cu3(bpy) 3(H2O)}V4O9(O3PC 6H5)4]ṡ3.9H2O (2ṡ3.9H 2O) and [{Cu(bpy)}VO(O3PC6H5) 2] (4) at 120 °C, 150 °C and 180-230 °C, respectively. Furthermore, variations in stoichiometry at 150 °C provided yet a fourth one-dimensional phase [{Cu(bpy)}2V3O6(O 3PC6H5)3(HO3PC 6H5)] (3). Substitution of a methyl substituent for the phenyl group yielded another one-dimensional material [{Cu(bpy)}V 2O4(O3PCH3)2ṡH 2O (5ṡH2O). The structural chemistry is discussed in terms of the polyhedral variability of vanadium oxides, the tendency of oxovanadium polyhedra to form oligomeric arrays, the variable modes of polyhedral connectivity associated with vanadium square pyramids and phosphorus tetrahedra and the steric influences of the copper(II)-bpy subunit.",

author = "Gundog Yucesan and Wayne Ouellette and Vladimir Golub and O'Connor, {Charles J.} and Jon Zubieta",

note = "Funding Information: This work was supported by a grant from the National Science Foundation (CHE0242153). We also thank Prof. Yan-Yeung Luk for his assistance with the optical microscopy. ",

year = "2005",

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T1 - Solid state coordination chemistry

T2 - Temperature dependence of the crystal chemistry of the oxovanadium-phenylphosphonate-copper(II)-2,2′-bipyridine system. Crystal structures of the one-dimensional [{Cu(bpy)}VO 2(O3PC6H5)(HO3PC 6H5)]

AU - Yucesan, Gundog

AU - Ouellette, Wayne

AU - Golub, Vladimir

AU - O'Connor, Charles J.

AU - Zubieta, Jon

N1 - Funding Information: This work was supported by a grant from the National Science Foundation (CHE0242153). We also thank Prof. Yan-Yeung Luk for his assistance with the optical microscopy.

PY - 2005/4

Y1 - 2005/4

N2 - The temperature dependence of the hydrothermal chemistry of the oxovanadium-phenylphosphonate/copper(II)-bipyridine system has been investigated. Reactions of identical compositions of CuSO 4ṡ5H2O, bipyridine, C6H5PO 3H2 and Na3VO4 in H2O yielded [{Cu(bpy)}VO2(O3PC6H 5)(HOC6H5)] (1), [{Cu3(bpy) 3(H2O)}V4O9(O3PC 6H5)4]ṡ3.9H2O (2ṡ3.9H 2O) and [{Cu(bpy)}VO(O3PC6H5) 2] (4) at 120 °C, 150 °C and 180-230 °C, respectively. Furthermore, variations in stoichiometry at 150 °C provided yet a fourth one-dimensional phase [{Cu(bpy)}2V3O6(O 3PC6H5)3(HO3PC 6H5)] (3). Substitution of a methyl substituent for the phenyl group yielded another one-dimensional material [{Cu(bpy)}V 2O4(O3PCH3)2ṡH 2O (5ṡH2O). The structural chemistry is discussed in terms of the polyhedral variability of vanadium oxides, the tendency of oxovanadium polyhedra to form oligomeric arrays, the variable modes of polyhedral connectivity associated with vanadium square pyramids and phosphorus tetrahedra and the steric influences of the copper(II)-bpy subunit.

AB - The temperature dependence of the hydrothermal chemistry of the oxovanadium-phenylphosphonate/copper(II)-bipyridine system has been investigated. Reactions of identical compositions of CuSO 4ṡ5H2O, bipyridine, C6H5PO 3H2 and Na3VO4 in H2O yielded [{Cu(bpy)}VO2(O3PC6H 5)(HOC6H5)] (1), [{Cu3(bpy) 3(H2O)}V4O9(O3PC 6H5)4]ṡ3.9H2O (2ṡ3.9H 2O) and [{Cu(bpy)}VO(O3PC6H5) 2] (4) at 120 °C, 150 °C and 180-230 °C, respectively. Furthermore, variations in stoichiometry at 150 °C provided yet a fourth one-dimensional phase [{Cu(bpy)}2V3O6(O 3PC6H5)3(HO3PC 6H5)] (3). Substitution of a methyl substituent for the phenyl group yielded another one-dimensional material [{Cu(bpy)}V 2O4(O3PCH3)2ṡH 2O (5ṡH2O). The structural chemistry is discussed in terms of the polyhedral variability of vanadium oxides, the tendency of oxovanadium polyhedra to form oligomeric arrays, the variable modes of polyhedral connectivity associated with vanadium square pyramids and phosphorus tetrahedra and the steric influences of the copper(II)-bpy subunit.

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