Solid state coordination chemistry: Structural consequences of variations in tether length in the oxovanadium–copper–bisterpy–(O3P(CH2)nPO3)4−system, n = 1–6 (bisterpy = 2,2′:4′,4′:2′,2‴-quarterpyridyl-6′,6′-di-2-pyridine)

Wayne Ouellette; Bon Kweon Koo; Eric Burkholder; Vladimir Golub; C. J. O’Connor; Jon Zubieta

doi:10.1039/b401669f

Solid state coordination chemistry: Structural consequences of variations in tether length in the oxovanadium–copper–bisterpy–(O₃P(CH₂)_nPO₃)⁴⁻system, n = 1–6 (bisterpy = 2,2′:4′,4′:2′,2‴-quarterpyridyl-6′,6′-di-2-pyridine)

Wayne Ouellette, Bon Kweon Koo, Eric Burkholder, Vladimir Golub, C. J. O’Connor, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

Hydrothermal reactions of Na₃VO₄, an appropriate Cu(ii) source, bisterpy and an organodiphosphonate, H₂O₃P(CH₂)_nPO₃H₂(n = 1–6) yielded a family of materials of the type (Cu₂(bisterpy))⁴⁺/V_xO_yⁿ⁻/(O₃P(CH₂)_nPO₃)⁴⁻. This family of bimetallic oxides is characterized by an unusual structural diversity. The oxides [(Cu₂(bisterpy))V₂O₄(O₃PCH₂PO₃H)₂] (1), [(Cu₂(bisterpy)(H₂O))VO₂(O₃P(CH₂)₃PO₃)(HO₃P(CH₂)₃PO₃H₂)] (4) and [(Cu₂(bisterpy))V₂O₄(O₃P(CH₂)₆PO₃H)₂]·2H₂O (7·2H₂O) are one-dimensional, while [(Cu₂(bisterpy)(H₂O)₂)V₂O₄(O₃P(CH₂)₂PO₃)(HO₃P(CH₂)₂PO₃H)₂] (2), [(Cu₂(bisterpy))V₄O₈(O₃P(CH₂)₃PO₃)₂]·4H₂O (3·4H₂O) and [(Cu₂(bisterpy))V₂O₄(OH)₂(O₃P(CH₂)₄PO₃)]·4H₂O (5·4H₂O) are two-dimensional. The V(iv) oxide [(Cu₂(bisterpy))V₄O₄(O₃P(CH₂)₅PO₃H)₄]·7.3H₂O (6·7.3H₂O) provides a relatively unusual example of a three-dimensional bimetallic oxide phosphonate. The structures reveal a variety of V/P/O substructures as building blocks.

Original language	English (US)
Pages (from-to)	1527-1538
Number of pages	12
Journal	Journal of the Chemical Society. Dalton Transactions
Volume	4
Issue number	10
DOIs	https://doi.org/10.1039/b401669f
State	Published - May 7 2004

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General Chemistry

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Ouellette, W., Koo, B. K., Burkholder, E., Golub, V., O’Connor, C. J., & Zubieta, J. (2004). Solid state coordination chemistry: Structural consequences of variations in tether length in the oxovanadium–copper–bisterpy–(O₃P(CH₂)_nPO₃)⁴⁻system, n = 1–6 (bisterpy = 2,2′:4′,4′:2′,2‴-quarterpyridyl-6′,6′-di-2-pyridine). Journal of the Chemical Society. Dalton Transactions, 4(10), 1527-1538. https://doi.org/10.1039/b401669f

Solid state coordination chemistry: Structural consequences of variations in tether length in the oxovanadium–copper–bisterpy–(O₃P(CH₂)_nPO₃)⁴⁻system, n = 1–6 (bisterpy = 2,2′:4′,4′:2′,2‴-quarterpyridyl-6′,6′-di-2-pyridine). / Ouellette, Wayne; Koo, Bon Kweon; Burkholder, Eric et al.
In: Journal of the Chemical Society. Dalton Transactions, Vol. 4, No. 10, 07.05.2004, p. 1527-1538.

Research output: Contribution to journal › Article › peer-review

Ouellette, W, Koo, BK, Burkholder, E, Golub, V, O’Connor, CJ & Zubieta, J 2004, 'Solid state coordination chemistry: Structural consequences of variations in tether length in the oxovanadium–copper–bisterpy–(O₃P(CH₂)_nPO₃)⁴⁻system, n = 1–6 (bisterpy = 2,2′:4′,4′:2′,2‴-quarterpyridyl-6′,6′-di-2-pyridine)', Journal of the Chemical Society. Dalton Transactions, vol. 4, no. 10, pp. 1527-1538. https://doi.org/10.1039/b401669f

Ouellette W, Koo BK, Burkholder E, Golub V, O’Connor CJ, Zubieta J. Solid state coordination chemistry: Structural consequences of variations in tether length in the oxovanadium–copper–bisterpy–(O₃P(CH₂)_nPO₃)⁴⁻system, n = 1–6 (bisterpy = 2,2′:4′,4′:2′,2‴-quarterpyridyl-6′,6′-di-2-pyridine). Journal of the Chemical Society. Dalton Transactions. 2004 May 7;4(10):1527-1538. doi: 10.1039/b401669f

Ouellette, Wayne ; Koo, Bon Kweon ; Burkholder, Eric et al. / Solid state coordination chemistry : Structural consequences of variations in tether length in the oxovanadium–copper–bisterpy–(O₃P(CH₂)_nPO₃)⁴⁻system, n = 1–6 (bisterpy = 2,2′:4′,4′:2′,2‴-quarterpyridyl-6′,6′-di-2-pyridine). In: Journal of the Chemical Society. Dalton Transactions. 2004 ; Vol. 4, No. 10. pp. 1527-1538.

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title = "Solid state coordination chemistry: Structural consequences of variations in tether length in the oxovanadium–copper–bisterpy–(O3P(CH2)nPO3)4−system, n = 1–6 (bisterpy = 2,2′:4′,4′:2′,2‴-quarterpyridyl-6′,6′-di-2-pyridine)",

abstract = "Hydrothermal reactions of Na3VO4, an appropriate Cu(ii) source, bisterpy and an organodiphosphonate, H2O3P(CH2)nPO3H2(n = 1–6) yielded a family of materials of the type (Cu2(bisterpy))4+/VxOyn−/(O3P(CH2)nPO3)4−. This family of bimetallic oxides is characterized by an unusual structural diversity. The oxides [(Cu2(bisterpy))V2O4(O3PCH2PO3H)2] (1), [(Cu2(bisterpy)(H2O))VO2(O3P(CH2)3PO3)(HO3P(CH2)3PO3H2)] (4) and [(Cu2(bisterpy))V2O4(O3P(CH2)6PO3H)2]·2H2O (7·2H2O) are one-dimensional, while [(Cu2(bisterpy)(H2O)2)V2O4(O3P(CH2)2PO3)(HO3P(CH2)2PO3H)2] (2), [(Cu2(bisterpy))V4O8(O3P(CH2)3PO3)2]·4H2O (3·4H2O) and [(Cu2(bisterpy))V2O4(OH)2(O3P(CH2)4PO3)]·4H2O (5·4H2O) are two-dimensional. The V(iv) oxide [(Cu2(bisterpy))V4O4(O3P(CH2)5PO3H)4]·7.3H2O (6·7.3H2O) provides a relatively unusual example of a three-dimensional bimetallic oxide phosphonate. The structures reveal a variety of V/P/O substructures as building blocks.",

author = "Wayne Ouellette and Koo, {Bon Kweon} and Eric Burkholder and Vladimir Golub and O{\textquoteright}Connor, {C. J.} and Jon Zubieta",

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AU - Ouellette, Wayne

AU - Koo, Bon Kweon

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AU - Golub, Vladimir

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N2 - Hydrothermal reactions of Na3VO4, an appropriate Cu(ii) source, bisterpy and an organodiphosphonate, H2O3P(CH2)nPO3H2(n = 1–6) yielded a family of materials of the type (Cu2(bisterpy))4+/VxOyn−/(O3P(CH2)nPO3)4−. This family of bimetallic oxides is characterized by an unusual structural diversity. The oxides [(Cu2(bisterpy))V2O4(O3PCH2PO3H)2] (1), [(Cu2(bisterpy)(H2O))VO2(O3P(CH2)3PO3)(HO3P(CH2)3PO3H2)] (4) and [(Cu2(bisterpy))V2O4(O3P(CH2)6PO3H)2]·2H2O (7·2H2O) are one-dimensional, while [(Cu2(bisterpy)(H2O)2)V2O4(O3P(CH2)2PO3)(HO3P(CH2)2PO3H)2] (2), [(Cu2(bisterpy))V4O8(O3P(CH2)3PO3)2]·4H2O (3·4H2O) and [(Cu2(bisterpy))V2O4(OH)2(O3P(CH2)4PO3)]·4H2O (5·4H2O) are two-dimensional. The V(iv) oxide [(Cu2(bisterpy))V4O4(O3P(CH2)5PO3H)4]·7.3H2O (6·7.3H2O) provides a relatively unusual example of a three-dimensional bimetallic oxide phosphonate. The structures reveal a variety of V/P/O substructures as building blocks.

AB - Hydrothermal reactions of Na3VO4, an appropriate Cu(ii) source, bisterpy and an organodiphosphonate, H2O3P(CH2)nPO3H2(n = 1–6) yielded a family of materials of the type (Cu2(bisterpy))4+/VxOyn−/(O3P(CH2)nPO3)4−. This family of bimetallic oxides is characterized by an unusual structural diversity. The oxides [(Cu2(bisterpy))V2O4(O3PCH2PO3H)2] (1), [(Cu2(bisterpy)(H2O))VO2(O3P(CH2)3PO3)(HO3P(CH2)3PO3H2)] (4) and [(Cu2(bisterpy))V2O4(O3P(CH2)6PO3H)2]·2H2O (7·2H2O) are one-dimensional, while [(Cu2(bisterpy)(H2O)2)V2O4(O3P(CH2)2PO3)(HO3P(CH2)2PO3H)2] (2), [(Cu2(bisterpy))V4O8(O3P(CH2)3PO3)2]·4H2O (3·4H2O) and [(Cu2(bisterpy))V2O4(OH)2(O3P(CH2)4PO3)]·4H2O (5·4H2O) are two-dimensional. The V(iv) oxide [(Cu2(bisterpy))V4O4(O3P(CH2)5PO3H)4]·7.3H2O (6·7.3H2O) provides a relatively unusual example of a three-dimensional bimetallic oxide phosphonate. The structures reveal a variety of V/P/O substructures as building blocks.

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