Solid state coordination chemistry: Organic/inorganic hybrid frameworks constructed from tetrapyridylporphyrin and vanadium oxide chains

Gundog Yucesan; Vladimir Golub; Charles J. O'Connor; Jon Zubieta

doi:10.1039/b414430a

Solid state coordination chemistry: Organic/inorganic hybrid frameworks constructed from tetrapyridylporphyrin and vanadium oxide chains

Gundog Yucesan, Vladimir Golub, Charles J. O'Connor, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

The hydrothermal reactions of Na₃VO₄, tetrapyridylporphyrin (tpypor), phenylphosphonic acid and the appropriate M(II) salt yielded the three-dimensional oxide frameworks [Cu(tpypor){Cu ₂V₂O₂(O₃PC₆H ₅)₄}] •2H₂O (1•2H₂O) and [Ni(tpypor){V₄O₄(O₃PC₆H ₅)₄}]•2H₂O (2•2H₂O), which are constructed from {X₂V₂O₂ (O ₃PC₆H₅)₄} _n chains [X = Cu (1), VO (2)] linked through {M(tpypor)} subunits [M = Cu (1), Ni (2)]; the structures differ only in the replacement of the Cu(II) sites on the chain of 1 by {VO}₂₊ units in the structure of 2, a manifestation of the retention of structural motifs derived from common secondary building units.

Original language	English (US)
Pages (from-to)	323-325
Number of pages	3
Journal	CrystEngComm
Volume	6
DOIs	https://doi.org/10.1039/b414430a
State	Published - Sep 30 2004

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

Access to Document

10.1039/b414430a

Cite this

@article{2f0f97d0f26047e18044888aa83c1d96,

title = "Solid state coordination chemistry: Organic/inorganic hybrid frameworks constructed from tetrapyridylporphyrin and vanadium oxide chains",

abstract = "The hydrothermal reactions of Na3VO4, tetrapyridylporphyrin (tpypor), phenylphosphonic acid and the appropriate M(II) salt yielded the three-dimensional oxide frameworks [Cu(tpypor){Cu 2V2O2(O3PC6H 5)4}] •2H2O (1•2H2O) and [Ni(tpypor){V4O4(O3PC6H 5)4}]•2H2O (2•2H2O), which are constructed from {X2V2O2 (O 3PC6H5)4} n chains [X = Cu (1), VO (2)] linked through {M(tpypor)} subunits [M = Cu (1), Ni (2)]; the structures differ only in the replacement of the Cu(II) sites on the chain of 1 by {VO}2+ units in the structure of 2, a manifestation of the retention of structural motifs derived from common secondary building units.",

author = "Gundog Yucesan and Vladimir Golub and O'Connor, {Charles J.} and Jon Zubieta",

year = "2004",

month = sep,

day = "30",

doi = "10.1039/b414430a",

language = "English (US)",

volume = "6",

pages = "323--325",

journal = "CrystEngComm",

issn = "1466-8033",

publisher = "Royal Society of Chemistry",

}

TY - JOUR

T1 - Solid state coordination chemistry

T2 - Organic/inorganic hybrid frameworks constructed from tetrapyridylporphyrin and vanadium oxide chains

AU - Yucesan, Gundog

AU - Golub, Vladimir

AU - O'Connor, Charles J.

AU - Zubieta, Jon

PY - 2004/9/30

Y1 - 2004/9/30

N2 - The hydrothermal reactions of Na3VO4, tetrapyridylporphyrin (tpypor), phenylphosphonic acid and the appropriate M(II) salt yielded the three-dimensional oxide frameworks [Cu(tpypor){Cu 2V2O2(O3PC6H 5)4}] •2H2O (1•2H2O) and [Ni(tpypor){V4O4(O3PC6H 5)4}]•2H2O (2•2H2O), which are constructed from {X2V2O2 (O 3PC6H5)4} n chains [X = Cu (1), VO (2)] linked through {M(tpypor)} subunits [M = Cu (1), Ni (2)]; the structures differ only in the replacement of the Cu(II) sites on the chain of 1 by {VO}2+ units in the structure of 2, a manifestation of the retention of structural motifs derived from common secondary building units.

AB - The hydrothermal reactions of Na3VO4, tetrapyridylporphyrin (tpypor), phenylphosphonic acid and the appropriate M(II) salt yielded the three-dimensional oxide frameworks [Cu(tpypor){Cu 2V2O2(O3PC6H 5)4}] •2H2O (1•2H2O) and [Ni(tpypor){V4O4(O3PC6H 5)4}]•2H2O (2•2H2O), which are constructed from {X2V2O2 (O 3PC6H5)4} n chains [X = Cu (1), VO (2)] linked through {M(tpypor)} subunits [M = Cu (1), Ni (2)]; the structures differ only in the replacement of the Cu(II) sites on the chain of 1 by {VO}2+ units in the structure of 2, a manifestation of the retention of structural motifs derived from common secondary building units.

UR - http://www.scopus.com/inward/record.url?scp=16244396714&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=16244396714&partnerID=8YFLogxK

U2 - 10.1039/b414430a

DO - 10.1039/b414430a

M3 - Article

AN - SCOPUS:16244396714

SN - 1466-8033

VL - 6

SP - 323

EP - 325

JO - CrystEngComm

JF - CrystEngComm

ER -

Solid state coordination chemistry: Organic/inorganic hybrid frameworks constructed from tetrapyridylporphyrin and vanadium oxide chains

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this