Solid state coordination chemistry of the oxofluorovanadium-diphosphonate system in the presence of Cu(II)-tetrapyridylpyrazine complex cations. The crystal structures of [{Cu2(tpyprz)(H2O)2}V4FO 8(HO3PCH2PO3)2], [{Cu2(tpyprz)(H2O)2}V4F 6O...

Wayne Ouellette; Vladimir Golub; Charles J. O'Connor; Jon Zubieta

doi:10.1016/j.jssc.2007.06.020

Solid state coordination chemistry of the oxofluorovanadium-diphosphonate system in the presence of Cu(II)-tetrapyridylpyrazine complex cations. The crystal structures of [{Cu₂(tpyprz)(H₂O)₂}V₄FO ₈(HO₃PCH₂PO₃)₂], [{Cu₂(tpyprz)(H₂O)₂}V₄F ₆O...

Wayne Ouellette, Vladimir Golub, Charles J. O'Connor, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

Full title: Solid state coordination chemistry of the oxofluorovanadium-diphosphonate system in the presence of Cu(II)-tetrapyridylpyrazine complex cations. The crystal structures of [{Cu₂(tpyprz)(H₂O)₂}V₄FO ₈(HO₃PCH₂PO₃)₂], [{Cu₂(tpyprz)(H₂O)₂}V₄F ₆O₆(O₃PCH₂CH₂PO ₃)], and [Cu₂(tpyprz){HO₃P(CH₂)₃PO ₃H}][V₂F₂O₅] (tpyprz=tetra-4-pyridylpyrazine). The hydrothermal reactions of V₂O₅, Cu(CH₃CO₂)₂·H₂O, tetrapyridylpyrazine (tpyprz), HF and the appropriate diphosphonic acid yielded a series of compounds of the {Cu² (tpyprz)} ⁴⁺ / V_x O_y F_z^{n -} / {O₃ P (CH₂)_n PO₃} ^4- family of materials. The structure of [{Cu₂(tpyprz)(H₂O)₂}V₄F ₆O₆(HO₃PCH₂PO₃) ₂] (1) is one-dimensional, constructed from mixed valence {V₃^V V^IV FO₈ (HO₃ PCH₂ PO₃)₂}^{4 -} clusters linked through {Cu₂(tpyprz)(H₂O)₂}⁴⁺ rods. The two-dimensional [{Cu₂(tpyprz)(H₂O)₂}V₄F ₆O₆(O₃PCH₂CH₂PO ₃)] (2) is constructed from {V₄ F₆ O₆ (O₃ PCH₂ CH₂ PO₃)}_n^{4 n -} chains crosslinked by {Cu₂(tpyprz))(H₂O)₂}⁴⁺ rods; mixed valence {V₂^V V₂^IV F₆ O₆ (O₃ PCH₂ CH₂ PO₃)}^{4 -} clusters are embedded in the network. Compound 3, [Cu₂(tpyprz){HO₃P(CH₂)₃PO ₃H}][V₂F₂O₅], consists of [Cu₂ (tpyprz) {HO₃ P (CH₂)₃ PO₃ H}]_n^{2 n +} chains and isolated {V₂F₂O₅}^2- anions. Structures 1-3 are compared to the structures of the analogous series {Cu₂ (bisterpy)}^{4 +} / V_x O_y F_z^{n -} / {O₃ P (CH₂)_n PO₃}^{4 -}, where bisterpy is 2,2′:4′:4″:2″,2‴-quaterpyridine, 6′,6″-di-2-pyridinyl. The temperature-dependent magnetic susceptibilities of 2 and 3 are also discussed.

Original language	English (US)
Pages (from-to)	2500-2509
Number of pages	10
Journal	Journal of Solid State Chemistry
Volume	180
Issue number	9
DOIs	https://doi.org/10.1016/j.jssc.2007.06.020
State	Published - Sep 2007

Keywords

Bimetallic oxides
Copper-tetrapyridylpyridine components
Organic-inorganic hybrid materials
Oxyfluorovanadates
Vanadium organophosphonates

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Condensed Matter Physics
Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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Ouellette, W., Golub, V., O'Connor, C. J., & Zubieta, J. (2007). Solid state coordination chemistry of the oxofluorovanadium-diphosphonate system in the presence of Cu(II)-tetrapyridylpyrazine complex cations. The crystal structures of [{Cu₂(tpyprz)(H₂O)₂}V₄FO ₈(HO₃PCH₂PO₃)₂], [{Cu₂(tpyprz)(H₂O)₂}V₄F ₆O... Journal of Solid State Chemistry, 180(9), 2500-2509. https://doi.org/10.1016/j.jssc.2007.06.020

Solid state coordination chemistry of the oxofluorovanadium-diphosphonate system in the presence of Cu(II)-tetrapyridylpyrazine complex cations. The crystal structures of [{Cu₂(tpyprz)(H₂O)₂}V₄FO ₈(HO₃PCH₂PO₃)₂], [{Cu₂(tpyprz)(H₂O)₂}V₄F ₆O... / Ouellette, Wayne; Golub, Vladimir; O'Connor, Charles J. et al.
In: Journal of Solid State Chemistry, Vol. 180, No. 9, 09.2007, p. 2500-2509.

Research output: Contribution to journal › Article › peer-review

Ouellette, W, Golub, V, O'Connor, CJ & Zubieta, J 2007, 'Solid state coordination chemistry of the oxofluorovanadium-diphosphonate system in the presence of Cu(II)-tetrapyridylpyrazine complex cations. The crystal structures of [{Cu₂(tpyprz)(H₂O)₂}V₄FO ₈(HO₃PCH₂PO₃)₂], [{Cu₂(tpyprz)(H₂O)₂}V₄F ₆O...', Journal of Solid State Chemistry, vol. 180, no. 9, pp. 2500-2509. https://doi.org/10.1016/j.jssc.2007.06.020

Ouellette W, Golub V, O'Connor CJ, Zubieta J. Solid state coordination chemistry of the oxofluorovanadium-diphosphonate system in the presence of Cu(II)-tetrapyridylpyrazine complex cations. The crystal structures of [{Cu₂(tpyprz)(H₂O)₂}V₄FO ₈(HO₃PCH₂PO₃)₂], [{Cu₂(tpyprz)(H₂O)₂}V₄F ₆O... Journal of Solid State Chemistry. 2007 Sep;180(9):2500-2509. doi: 10.1016/j.jssc.2007.06.020

Ouellette, Wayne ; Golub, Vladimir ; O'Connor, Charles J. et al. / Solid state coordination chemistry of the oxofluorovanadium-diphosphonate system in the presence of Cu(II)-tetrapyridylpyrazine complex cations. The crystal structures of [{Cu₂(tpyprz)(H₂O)₂}V₄FO ₈(HO₃PCH₂PO₃)₂], [{Cu₂(tpyprz)(H₂O)₂}V₄F ₆O... In: Journal of Solid State Chemistry. 2007 ; Vol. 180, No. 9. pp. 2500-2509.

@article{ca4a36b72b4342bd8c4e5485c3ba3ef8,

title = "Solid state coordination chemistry of the oxofluorovanadium-diphosphonate system in the presence of Cu(II)-tetrapyridylpyrazine complex cations. The crystal structures of [{Cu2(tpyprz)(H2O)2}V4FO 8(HO3PCH2PO3)2], [{Cu2(tpyprz)(H2O)2}V4F 6O...",

abstract = "Full title: Solid state coordination chemistry of the oxofluorovanadium-diphosphonate system in the presence of Cu(II)-tetrapyridylpyrazine complex cations. The crystal structures of [{Cu2(tpyprz)(H2O)2}V4FO 8(HO3PCH2PO3)2], [{Cu2(tpyprz)(H2O)2}V4F 6O6(O3PCH2CH2PO 3)], and [Cu2(tpyprz){HO3P(CH2)3PO 3H}][V2F2O5] (tpyprz=tetra-4-pyridylpyrazine). The hydrothermal reactions of V2O5, Cu(CH3CO2)2·H2O, tetrapyridylpyrazine (tpyprz), HF and the appropriate diphosphonic acid yielded a series of compounds of the {Cu2 (tpyprz)} 4+ / Vx Oy Fzn - / {O3 P (CH2)n PO3} 4- family of materials. The structure of [{Cu2(tpyprz)(H2O)2}V4F 6O6(HO3PCH2PO3) 2] (1) is one-dimensional, constructed from mixed valence {V3V VIV FO8 (HO3 PCH2 PO3)2}4 - clusters linked through {Cu2(tpyprz)(H2O)2}4+ rods. The two-dimensional [{Cu2(tpyprz)(H2O)2}V4F 6O6(O3PCH2CH2PO 3)] (2) is constructed from {V4 F6 O6 (O3 PCH2 CH2 PO3)}n4 n - chains crosslinked by {Cu2(tpyprz))(H2O)2}4+ rods; mixed valence {V2V V2IV F6 O6 (O3 PCH2 CH2 PO3)}4 - clusters are embedded in the network. Compound 3, [Cu2(tpyprz){HO3P(CH2)3PO 3H}][V2F2O5], consists of [Cu2 (tpyprz) {HO3 P (CH2)3 PO3 H}]n2 n + chains and isolated {V2F2O5}2- anions. Structures 1-3 are compared to the structures of the analogous series {Cu2 (bisterpy)}4 + / Vx Oy Fzn - / {O3 P (CH2)n PO3}4 -, where bisterpy is 2,2′:4′:4″:2″,2‴-quaterpyridine, 6′,6″-di-2-pyridinyl. The temperature-dependent magnetic susceptibilities of 2 and 3 are also discussed.",

keywords = "Bimetallic oxides, Copper-tetrapyridylpyridine components, Organic-inorganic hybrid materials, Oxyfluorovanadates, Vanadium organophosphonates",

author = "Wayne Ouellette and Vladimir Golub and O'Connor, {Charles J.} and Jon Zubieta",

note = "Funding Information: This work was supported by a grant from the National Science Foundation, CHE-0604527 and by the Defense Advances Research Projects Agency (MDA972-04-1-0029). ",

year = "2007",

month = sep,

doi = "10.1016/j.jssc.2007.06.020",

language = "English (US)",

volume = "180",

pages = "2500--2509",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

number = "9",

}

TY - JOUR

T1 - Solid state coordination chemistry of the oxofluorovanadium-diphosphonate system in the presence of Cu(II)-tetrapyridylpyrazine complex cations. The crystal structures of [{Cu2(tpyprz)(H2O)2}V4FO 8(HO3PCH2PO3)2], [{Cu2(tpyprz)(H2O)2}V4F 6O...

AU - Ouellette, Wayne

AU - Golub, Vladimir

AU - O'Connor, Charles J.

AU - Zubieta, Jon

N1 - Funding Information: This work was supported by a grant from the National Science Foundation, CHE-0604527 and by the Defense Advances Research Projects Agency (MDA972-04-1-0029).

PY - 2007/9

Y1 - 2007/9

N2 - Full title: Solid state coordination chemistry of the oxofluorovanadium-diphosphonate system in the presence of Cu(II)-tetrapyridylpyrazine complex cations. The crystal structures of [{Cu2(tpyprz)(H2O)2}V4FO 8(HO3PCH2PO3)2], [{Cu2(tpyprz)(H2O)2}V4F 6O6(O3PCH2CH2PO 3)], and [Cu2(tpyprz){HO3P(CH2)3PO 3H}][V2F2O5] (tpyprz=tetra-4-pyridylpyrazine). The hydrothermal reactions of V2O5, Cu(CH3CO2)2·H2O, tetrapyridylpyrazine (tpyprz), HF and the appropriate diphosphonic acid yielded a series of compounds of the {Cu2 (tpyprz)} 4+ / Vx Oy Fzn - / {O3 P (CH2)n PO3} 4- family of materials. The structure of [{Cu2(tpyprz)(H2O)2}V4F 6O6(HO3PCH2PO3) 2] (1) is one-dimensional, constructed from mixed valence {V3V VIV FO8 (HO3 PCH2 PO3)2}4 - clusters linked through {Cu2(tpyprz)(H2O)2}4+ rods. The two-dimensional [{Cu2(tpyprz)(H2O)2}V4F 6O6(O3PCH2CH2PO 3)] (2) is constructed from {V4 F6 O6 (O3 PCH2 CH2 PO3)}n4 n - chains crosslinked by {Cu2(tpyprz))(H2O)2}4+ rods; mixed valence {V2V V2IV F6 O6 (O3 PCH2 CH2 PO3)}4 - clusters are embedded in the network. Compound 3, [Cu2(tpyprz){HO3P(CH2)3PO 3H}][V2F2O5], consists of [Cu2 (tpyprz) {HO3 P (CH2)3 PO3 H}]n2 n + chains and isolated {V2F2O5}2- anions. Structures 1-3 are compared to the structures of the analogous series {Cu2 (bisterpy)}4 + / Vx Oy Fzn - / {O3 P (CH2)n PO3}4 -, where bisterpy is 2,2′:4′:4″:2″,2‴-quaterpyridine, 6′,6″-di-2-pyridinyl. The temperature-dependent magnetic susceptibilities of 2 and 3 are also discussed.

AB - Full title: Solid state coordination chemistry of the oxofluorovanadium-diphosphonate system in the presence of Cu(II)-tetrapyridylpyrazine complex cations. The crystal structures of [{Cu2(tpyprz)(H2O)2}V4FO 8(HO3PCH2PO3)2], [{Cu2(tpyprz)(H2O)2}V4F 6O6(O3PCH2CH2PO 3)], and [Cu2(tpyprz){HO3P(CH2)3PO 3H}][V2F2O5] (tpyprz=tetra-4-pyridylpyrazine). The hydrothermal reactions of V2O5, Cu(CH3CO2)2·H2O, tetrapyridylpyrazine (tpyprz), HF and the appropriate diphosphonic acid yielded a series of compounds of the {Cu2 (tpyprz)} 4+ / Vx Oy Fzn - / {O3 P (CH2)n PO3} 4- family of materials. The structure of [{Cu2(tpyprz)(H2O)2}V4F 6O6(HO3PCH2PO3) 2] (1) is one-dimensional, constructed from mixed valence {V3V VIV FO8 (HO3 PCH2 PO3)2}4 - clusters linked through {Cu2(tpyprz)(H2O)2}4+ rods. The two-dimensional [{Cu2(tpyprz)(H2O)2}V4F 6O6(O3PCH2CH2PO 3)] (2) is constructed from {V4 F6 O6 (O3 PCH2 CH2 PO3)}n4 n - chains crosslinked by {Cu2(tpyprz))(H2O)2}4+ rods; mixed valence {V2V V2IV F6 O6 (O3 PCH2 CH2 PO3)}4 - clusters are embedded in the network. Compound 3, [Cu2(tpyprz){HO3P(CH2)3PO 3H}][V2F2O5], consists of [Cu2 (tpyprz) {HO3 P (CH2)3 PO3 H}]n2 n + chains and isolated {V2F2O5}2- anions. Structures 1-3 are compared to the structures of the analogous series {Cu2 (bisterpy)}4 + / Vx Oy Fzn - / {O3 P (CH2)n PO3}4 -, where bisterpy is 2,2′:4′:4″:2″,2‴-quaterpyridine, 6′,6″-di-2-pyridinyl. The temperature-dependent magnetic susceptibilities of 2 and 3 are also discussed.

KW - Bimetallic oxides

KW - Copper-tetrapyridylpyridine components

KW - Organic-inorganic hybrid materials

KW - Oxyfluorovanadates

KW - Vanadium organophosphonates

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