Solid state coordination chemistry of the copper(II)/bisterpy/vanadate system: The structures of [Cu2(bisterpy)V4O12]·2H2O and [Cu2(bisterpy)V4F2O11] (bisterpy = 2,2′:4′,4′′:2′′,2′′′-quarter-pyridyl, 6′,6′′-di-2-pyridine)

Wayne Ouellette; Jon Zubieta

doi:10.1016/j.solidstatesciences.2007.05.002

Solid state coordination chemistry of the copper(II)/bisterpy/vanadate system: The structures of [Cu₂(bisterpy)V₄O₁₂]·2H₂O and [Cu₂(bisterpy)V₄F₂O₁₁] (bisterpy = 2,2′:4′,4′′:2′′,2′′′-quarter-pyridyl, 6′,6′′-di-2-pyridine)

Wayne Ouellette, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

Hydrothermal methods were exploited in the preparation of bimetallic organic-inorganic hybrid materials of the metal-bisterpy/vanadate class. [Cu₂(bisterpy)V₄O₁₂]·2H₂O exhibits a two-dimensional structure constructed from {Cu₂V₄O₁₂}_n chains linked through bisterpy ligands. The isomorphous materials [M₂(bisterpy)V₄F₂O₁₁] (M = Cu, Zn) are also two-dimensional. In these cases, {M₂V₄F₂O₁₁}_n chains are linked through bisterpy ligands to generate the two-dimensional network.

Original language	English (US)
Pages (from-to)	658-663
Number of pages	6
Journal	Solid State Sciences
Volume	9
Issue number	8
DOIs	https://doi.org/10.1016/j.solidstatesciences.2007.05.002
State	Published - Aug 2007

Keywords

Copper(II)-bisterpy building blocks
Fluorooxovanadates
Hydrothermal synthesis
Organic/inorganic hybrid materials
Vanadium oxide structures

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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10.1016/j.solidstatesciences.2007.05.002

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Ouellette, W., & Zubieta, J. (2007). Solid state coordination chemistry of the copper(II)/bisterpy/vanadate system: The structures of [Cu₂(bisterpy)V₄O₁₂]·2H₂O and [Cu₂(bisterpy)V₄F₂O₁₁] (bisterpy = 2,2′:4′,4′′:2′′,2′′′-quarter-pyridyl, 6′,6′′-di-2-pyridine). Solid State Sciences, 9(8), 658-663. https://doi.org/10.1016/j.solidstatesciences.2007.05.002

Solid state coordination chemistry of the copper(II)/bisterpy/vanadate system: The structures of [Cu₂(bisterpy)V₄O₁₂]·2H₂O and [Cu₂(bisterpy)V₄F₂O₁₁] (bisterpy = 2,2′:4′,4′′:2′′,2′′′-quarter-pyridyl, 6′,6′′-di-2-pyridine). / Ouellette, Wayne; Zubieta, Jon.
In: Solid State Sciences, Vol. 9, No. 8, 08.2007, p. 658-663.

Research output: Contribution to journal › Article › peer-review

Ouellette, W & Zubieta, J 2007, 'Solid state coordination chemistry of the copper(II)/bisterpy/vanadate system: The structures of [Cu₂(bisterpy)V₄O₁₂]·2H₂O and [Cu₂(bisterpy)V₄F₂O₁₁] (bisterpy = 2,2′:4′,4′′:2′′,2′′′-quarter-pyridyl, 6′,6′′-di-2-pyridine)', Solid State Sciences, vol. 9, no. 8, pp. 658-663. https://doi.org/10.1016/j.solidstatesciences.2007.05.002

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title = "Solid state coordination chemistry of the copper(II)/bisterpy/vanadate system: The structures of [Cu2(bisterpy)V4O12]·2H2O and [Cu2(bisterpy)V4F2O11] (bisterpy = 2,2′:4′,4′′:2′′,2′′′-quarter-pyridyl, 6′,6′′-di-2-pyridine)",

abstract = "Hydrothermal methods were exploited in the preparation of bimetallic organic-inorganic hybrid materials of the metal-bisterpy/vanadate class. [Cu2(bisterpy)V4O12]·2H2O exhibits a two-dimensional structure constructed from {Cu2V4O12}n chains linked through bisterpy ligands. The isomorphous materials [M2(bisterpy)V4F2O11] (M = Cu, Zn) are also two-dimensional. In these cases, {M2V4F2O11}n chains are linked through bisterpy ligands to generate the two-dimensional network.",

keywords = "Copper(II)-bisterpy building blocks, Fluorooxovanadates, Hydrothermal synthesis, Organic/inorganic hybrid materials, Vanadium oxide structures",

author = "Wayne Ouellette and Jon Zubieta",

note = "Funding Information: This work was supported by a grant from the National Science Foundation, CHE-0604527. ",

year = "2007",

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AB - Hydrothermal methods were exploited in the preparation of bimetallic organic-inorganic hybrid materials of the metal-bisterpy/vanadate class. [Cu2(bisterpy)V4O12]·2H2O exhibits a two-dimensional structure constructed from {Cu2V4O12}n chains linked through bisterpy ligands. The isomorphous materials [M2(bisterpy)V4F2O11] (M = Cu, Zn) are also two-dimensional. In these cases, {M2V4F2O11}n chains are linked through bisterpy ligands to generate the two-dimensional network.

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