Solid state coordination chemistry of the copper(II)/bisterpy/vanadate system: The structures of [Cu2(bisterpy)V4O12]·2H2O and [Cu2(bisterpy)V4F2O11] (bisterpy = 2,2′:4′,4′′:2′′,2′′′-quarter-pyridyl, 6′,6′′-di-2-pyridine)

Wayne Ouellette, Jon Zubieta

Research output: Contribution to journalArticle

7 Scopus citations

Abstract

Hydrothermal methods were exploited in the preparation of bimetallic organic-inorganic hybrid materials of the metal-bisterpy/vanadate class. [Cu2(bisterpy)V4O12]·2H2O exhibits a two-dimensional structure constructed from {Cu2V4O12}n chains linked through bisterpy ligands. The isomorphous materials [M2(bisterpy)V4F2O11] (M = Cu, Zn) are also two-dimensional. In these cases, {M2V4F2O11}n chains are linked through bisterpy ligands to generate the two-dimensional network.

Original languageEnglish (US)
Pages (from-to)658-663
Number of pages6
JournalSolid State Sciences
Volume9
Issue number8
DOIs
StatePublished - Aug 1 2007

Keywords

  • Copper(II)-bisterpy building blocks
  • Fluorooxovanadates
  • Hydrothermal synthesis
  • Organic/inorganic hybrid materials
  • Vanadium oxide structures

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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