Solid state coordination chemistry of the copper cyanide-organoamine system: Hydrothermal syntheses and structural characterization of [{Cu2(bpy)2(CN)}Cu5(CN)6] and [Cu4(CN)4(biquin)]

Douglas J. Chesnut, Jon Zubieta

Research output: Contribution to journalArticle

85 Scopus citations

Abstract

The hydrothermal reactions of CuCN and Cu(NO3)2·2.5H2O with the appropriate organonitrogen ligand in water yielded a one-dimensional chain, [Cu4(CN)4(biquin)] 1, and a material with a two-dimensional anionic honeycomb network and interpenetrating binuclear cations, [{Cu2- (bpy)2(CN))Cu5(CN)6] 2.

Original languageEnglish (US)
Pages (from-to)1707-1708
Number of pages2
JournalChemical Communications
Issue number16
DOIs
StatePublished - Aug 21 1998

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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