Solid state coordination chemistry of the copper cyanide-organoamine system: Hydrothermal syntheses and structural characterization of [{Cu2(bpy)2(CN)}Cu5(CN)6] and [Cu4(CN)4(biquin)]

Douglas J. Chesnut; Jon Zubieta

doi:10.1039/a802641f

Solid state coordination chemistry of the copper cyanide-organoamine system: Hydrothermal syntheses and structural characterization of [{Cu₂(bpy)2(CN)}Cu₅(CN)₆] and [Cu₄(CN)₄(biquin)]

Douglas J. Chesnut, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

90 Scopus citations

Abstract

The hydrothermal reactions of CuCN and Cu(NO₃)₂·2.5H₂O with the appropriate organonitrogen ligand in water yielded a one-dimensional chain, [Cu₄(CN)₄(biquin)] 1, and a material with a two-dimensional anionic honeycomb network and interpenetrating binuclear cations, [{Cu_2- (bpy)₂(CN))Cu₅(CN)₆] 2.

Original language	English (US)
Pages (from-to)	1707-1708
Number of pages	2
Journal	Chemical Communications
Issue number	16
DOIs	https://doi.org/10.1039/a802641f
State	Published - Aug 21 1998

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "The hydrothermal reactions of CuCN and Cu(NO3)2·2.5H2O with the appropriate organonitrogen ligand in water yielded a one-dimensional chain, [Cu4(CN)4(biquin)] 1, and a material with a two-dimensional anionic honeycomb network and interpenetrating binuclear cations, [{Cu2- (bpy)2(CN))Cu5(CN)6] 2.",

author = "Chesnut, {Douglas J.} and Jon Zubieta",

year = "1998",

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doi = "10.1039/a802641f",

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T2 - Hydrothermal syntheses and structural characterization of [{Cu2(bpy)2(CN)}Cu5(CN)6] and [Cu4(CN)4(biquin)]

AU - Chesnut, Douglas J.

AU - Zubieta, Jon

PY - 1998/8/21

Y1 - 1998/8/21

N2 - The hydrothermal reactions of CuCN and Cu(NO3)2·2.5H2O with the appropriate organonitrogen ligand in water yielded a one-dimensional chain, [Cu4(CN)4(biquin)] 1, and a material with a two-dimensional anionic honeycomb network and interpenetrating binuclear cations, [{Cu2- (bpy)2(CN))Cu5(CN)6] 2.

AB - The hydrothermal reactions of CuCN and Cu(NO3)2·2.5H2O with the appropriate organonitrogen ligand in water yielded a one-dimensional chain, [Cu4(CN)4(biquin)] 1, and a material with a two-dimensional anionic honeycomb network and interpenetrating binuclear cations, [{Cu2- (bpy)2(CN))Cu5(CN)6] 2.

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Solid state coordination chemistry of the copper cyanide-organoamine system: Hydrothermal syntheses and structural characterization of [{Cu₂(bpy)2(CN)}Cu₅(CN)₆] and [Cu₄(CN)₄(biquin)]

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