Solid state coordination chemistry of the copper cyanide-organoamine system: Hydrothermal synthesis and structural characterization of [{Cu2(bpy)2(CN)}2Cu5(CN) 7]·0.17H2O

Douglas J. Chesnut; Anakarin Kusnetzow; Jon Zubieta

doi:10.1039/a806500d

Solid state coordination chemistry of the copper cyanide-organoamine system: Hydrothermal synthesis and structural characterization of [{Cu₂(bpy)₂(CN)}₂Cu₅(CN) ₇]·0.17H₂O

Douglas J. Chesnut, Anakarin Kusnetzow, Jon Zubieta

Department of Chemistry

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Abstract

The hydrothermal reaction of CuCN, KCN, 2,2′-bipyridyl (bpy) and water yields [{Cu₂(bpy)₂(CN)}₂Cu₅(CN) ₇]· 0.17H₂O 1, a two-dimensional copper-cyano network intercalated by [(bpy)₂(Cu)₂(CN)]⁺ cations and water of crystallization.

Original language	English (US)
Pages (from-to)	4081-4083
Number of pages	3
Journal	Journal of the Chemical Society - Dalton Transactions
Issue number	24
DOIs	https://doi.org/10.1039/a806500d
State	Published - Dec 21 1998

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Solid state coordination chemistry of the copper cyanide-organoamine system: Hydrothermal synthesis and structural characterization of [{Cu₂(bpy)₂(CN)}₂Cu₅(CN) ₇]·0.17H₂O. / Chesnut, Douglas J.; Kusnetzow, Anakarin; Zubieta, Jon.
In: Journal of the Chemical Society - Dalton Transactions, No. 24, 21.12.1998, p. 4081-4083.

Research output: Contribution to journal › Article › peer-review

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Solid state coordination chemistry of the copper cyanide-organoamine system: Hydrothermal synthesis and structural characterization of [{Cu₂(bpy)₂(CN)}₂Cu₅(CN) ₇]·0.17H₂O

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