Solid state coordination chemistry of oxovanadium phosphates: Hydrothermal syntheses and structures of the network and chain phosphate phases [{Cu(bpy)}2(VO)3(PO4)2(HPO4)]·2H2O and [{Cu(terpy)}2(VO2)3(PO4)HPO4)2]

Robert Finn, Jon A Zubieta

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Abstract

The hydrothermal reactions of Cu2O, the appropriate polypyridine ligand, Na3VO4, H3PO4 and H2O at 200°C yield the two-dimensional material [{Cu(bpy)}2(VO)3(PO4)2(HPO4)2]·2H2O and the one- dimensional phosphate [{Cu(terpy)}2(VO2)3(PO4)(HPO4)2], examples of the structure-directing role of secondary metal-ligand subunits on the architectures of vanadium phosphates.

Original languageEnglish (US)
Pages (from-to)1321-1322
Number of pages2
JournalChemical Communications
Issue number14
StatePublished - Jul 21 2000

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ASJC Scopus subject areas

  • Chemistry(all)

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