Solid state coordination chemistry of organodiphosphonates with copper(II) and auxilliary aromatic nitrogen heterocyclic ligands

Gundog Yucesan; Wayne Ouellette; Yung Hsu (Jessica) Chuang; Jon Zubieta

doi:10.1016/j.ica.2006.08.022

Solid state coordination chemistry of organodiphosphonates with copper(II) and auxilliary aromatic nitrogen heterocyclic ligands

Gundog Yucesan, Wayne Ouellette, Yung Hsu (Jessica) Chuang, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

The hydrothermal reactions of CuSO₄ · 5H₂O, a phosphonate ligand and an appropriate aromatic nitrogen heterocycle yield a series of materials of the Cu(II)/phosphonate/nitrogen ligand donor family. Two of the materials [Cu(2,2′-bpy)(HO₃PCH₂CH₂CH₂PO₃H)] (1) and [Cu(4,4′-bpy)(H₂O)₂(HO₃PCH₂CH₂CH₂CH₂PO₃H)] (2) are two-dimensional, while [{Cu(2,2′-bpy)}₂(O₃PC₆H₄PO₃)] · 8H₂O (3 · 8H₂O) is three-dimensional. When 1,3,5-benzenetricarboxylic acid is introduced as a reactant, the one-dimensional material [Cu(2,2′-bpy){OC₆H₂(CO₂H)₃}(HOPC₆H₅)] (4) is isolated. This is an example of an in situ hydrothermal ligand transformation in which the 1,3,5-benzene tricarboxylic acid is hydroxylated to give 1,3,5-benzene tricarboxylic acid-2-hydroxide. Compound 5 [Cu(terpy)(HO₃PC₆H₄PO₃H] is molecular.

Original language	English (US)
Pages (from-to)	1502-1509
Number of pages	8
Journal	Inorganica Chimica Acta
Volume	360
Issue number	5
DOIs	https://doi.org/10.1016/j.ica.2006.08.022
State	Published - Apr 1 2007

Keywords

Copper phosphonate networks
Copper-bipyridine chemistry
Hydrothermal synthesis
Solid state coordination chemistry

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/j.ica.2006.08.022

Fingerprint Dive into the research topics of 'Solid state coordination chemistry of organodiphosphonates with copper(II) and auxilliary aromatic nitrogen heterocyclic ligands'. Together they form a unique fingerprint.

Cite this

@article{12fb264e7daa4de695472a976d4d9b26,

title = "Solid state coordination chemistry of organodiphosphonates with copper(II) and auxilliary aromatic nitrogen heterocyclic ligands",

abstract = "The hydrothermal reactions of CuSO4 · 5H2O, a phosphonate ligand and an appropriate aromatic nitrogen heterocycle yield a series of materials of the Cu(II)/phosphonate/nitrogen ligand donor family. Two of the materials [Cu(2,2′-bpy)(HO3PCH2CH2CH2PO3H)] (1) and [Cu(4,4′-bpy)(H2O)2(HO3PCH2CH2CH2CH2PO3H)] (2) are two-dimensional, while [{Cu(2,2′-bpy)}2(O3PC6H4PO3)] · 8H2O (3 · 8H2O) is three-dimensional. When 1,3,5-benzenetricarboxylic acid is introduced as a reactant, the one-dimensional material [Cu(2,2′-bpy){OC6H2(CO2H)3}(HOPC6H5)] (4) is isolated. This is an example of an in situ hydrothermal ligand transformation in which the 1,3,5-benzene tricarboxylic acid is hydroxylated to give 1,3,5-benzene tricarboxylic acid-2-hydroxide. Compound 5 [Cu(terpy)(HO3PC6H4PO3H] is molecular.",

keywords = "Copper phosphonate networks, Copper-bipyridine chemistry, Hydrothermal synthesis, Solid state coordination chemistry",

author = "Gundog Yucesan and Wayne Ouellette and Chuang, {Yung Hsu (Jessica)} and Jon Zubieta",

year = "2007",

month = apr,

day = "1",

doi = "10.1016/j.ica.2006.08.022",

language = "English (US)",

volume = "360",

pages = "1502--1509",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier",

number = "5",

}

TY - JOUR

T1 - Solid state coordination chemistry of organodiphosphonates with copper(II) and auxilliary aromatic nitrogen heterocyclic ligands

AU - Yucesan, Gundog

AU - Ouellette, Wayne

AU - Chuang, Yung Hsu (Jessica)

AU - Zubieta, Jon

PY - 2007/4/1

Y1 - 2007/4/1

N2 - The hydrothermal reactions of CuSO4 · 5H2O, a phosphonate ligand and an appropriate aromatic nitrogen heterocycle yield a series of materials of the Cu(II)/phosphonate/nitrogen ligand donor family. Two of the materials [Cu(2,2′-bpy)(HO3PCH2CH2CH2PO3H)] (1) and [Cu(4,4′-bpy)(H2O)2(HO3PCH2CH2CH2CH2PO3H)] (2) are two-dimensional, while [{Cu(2,2′-bpy)}2(O3PC6H4PO3)] · 8H2O (3 · 8H2O) is three-dimensional. When 1,3,5-benzenetricarboxylic acid is introduced as a reactant, the one-dimensional material [Cu(2,2′-bpy){OC6H2(CO2H)3}(HOPC6H5)] (4) is isolated. This is an example of an in situ hydrothermal ligand transformation in which the 1,3,5-benzene tricarboxylic acid is hydroxylated to give 1,3,5-benzene tricarboxylic acid-2-hydroxide. Compound 5 [Cu(terpy)(HO3PC6H4PO3H] is molecular.

AB - The hydrothermal reactions of CuSO4 · 5H2O, a phosphonate ligand and an appropriate aromatic nitrogen heterocycle yield a series of materials of the Cu(II)/phosphonate/nitrogen ligand donor family. Two of the materials [Cu(2,2′-bpy)(HO3PCH2CH2CH2PO3H)] (1) and [Cu(4,4′-bpy)(H2O)2(HO3PCH2CH2CH2CH2PO3H)] (2) are two-dimensional, while [{Cu(2,2′-bpy)}2(O3PC6H4PO3)] · 8H2O (3 · 8H2O) is three-dimensional. When 1,3,5-benzenetricarboxylic acid is introduced as a reactant, the one-dimensional material [Cu(2,2′-bpy){OC6H2(CO2H)3}(HOPC6H5)] (4) is isolated. This is an example of an in situ hydrothermal ligand transformation in which the 1,3,5-benzene tricarboxylic acid is hydroxylated to give 1,3,5-benzene tricarboxylic acid-2-hydroxide. Compound 5 [Cu(terpy)(HO3PC6H4PO3H] is molecular.

KW - Copper phosphonate networks

KW - Copper-bipyridine chemistry

KW - Hydrothermal synthesis

KW - Solid state coordination chemistry

UR - http://www.scopus.com/inward/record.url?scp=33847660564&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33847660564&partnerID=8YFLogxK

U2 - 10.1016/j.ica.2006.08.022

DO - 10.1016/j.ica.2006.08.022

M3 - Article

AN - SCOPUS:33847660564

VL - 360

SP - 1502

EP - 1509

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

IS - 5

ER -