Abstract
Hydrothermal chemistry was used to prepare the bimetallic organic-inorganic hybrid oxide [Cu(I)Cu(II)2(trz)2Mo4O13(OH)] · 6H2O (1 · 6H2O). The structure consists of {HMo4 O14}n3 n - chains linked through {Cu3 (trz)2}n3 n + into a three-dimensional framework. The structures of the simple metal-triazole phases [MoO3(Htrz)0.5] (2) and [Cu(trz)] (3) are also reported. Compound 2 is two-dimensional, constructed from corner-sharing {MoO5N} octahedra. Compound 3 consists of {Cu(trz)}n chains linked through weak Cu⋯Cu contacts into a virtual layer.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 2357-2364 |
| Number of pages | 8 |
| Journal | Inorganica Chimica Acta |
| Volume | 361 |
| Issue number | 8 |
| DOIs | |
| State | Published - Jun 2 2008 |
Keywords
- Hydrothermal synthesis
- Metal-triazolate materials
- Molybdenum oxide structures
- Organic-inorganic hybrid materials
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
- Materials Chemistry
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Chuang, J., Ouellette, W., & Zubieta, J. (2008). Solid state coordination chemistry of molybdenum oxides with 1,2,3-triazole (Htrz): The crystal structures of [Cu(I)Cu(II)2(trz)2Mo4O13(OH)], [MoO3(Htrz)0.5] and [Cu(I)trz]. Inorganica Chimica Acta, 361(8), 2357-2364. https://doi.org/10.1016/j.ica.2007.12.004