Solid state coordination chemistry of molybdenum oxides with 1,2,3-triazole (Htrz): The crystal structures of [Cu(I)Cu(II)2(trz)2Mo4O13(OH)], [MoO3(Htrz)0.5] and [Cu(I)trz]

Jessica Chuang, Wayne Ouellette, Jon Zubieta

Research output: Contribution to journalArticle

25 Scopus citations

Abstract

Hydrothermal chemistry was used to prepare the bimetallic organic-inorganic hybrid oxide [Cu(I)Cu(II)2(trz)2Mo4O13(OH)] · 6H2O (1 · 6H2O). The structure consists of {HMo4 O14}n3 n - chains linked through {Cu3 (trz)2}n3 n + into a three-dimensional framework. The structures of the simple metal-triazole phases [MoO3(Htrz)0.5] (2) and [Cu(trz)] (3) are also reported. Compound 2 is two-dimensional, constructed from corner-sharing {MoO5N} octahedra. Compound 3 consists of {Cu(trz)}n chains linked through weak Cu⋯Cu contacts into a virtual layer.

Original languageEnglish (US)
Pages (from-to)2357-2364
Number of pages8
JournalInorganica Chimica Acta
Volume361
Issue number8
DOIs
StatePublished - Jun 2 2008

Keywords

  • Hydrothermal synthesis
  • Metal-triazolate materials
  • Molybdenum oxide structures
  • Organic-inorganic hybrid materials

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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