Solid state coordination chemistry of molybdenum oxides with 1,2,3-triazole (Htrz): The crystal structures of [Cu(I)Cu(II)2(trz)2Mo4O13(OH)], [MoO3(Htrz)0.5] and [Cu(I)trz]

Jessica Chuang; Wayne Ouellette; Jon Zubieta

doi:10.1016/j.ica.2007.12.004

Solid state coordination chemistry of molybdenum oxides with 1,2,3-triazole (Htrz): The crystal structures of [Cu(I)Cu(II)₂(trz)₂Mo₄O₁₃(OH)], [MoO₃(Htrz)_0.5] and [Cu(I)trz]

Jessica Chuang, Wayne Ouellette, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

26 Scopus citations

Abstract

Hydrothermal chemistry was used to prepare the bimetallic organic-inorganic hybrid oxide [Cu(I)Cu(II)₂(trz)₂Mo₄O₁₃(OH)] · 6H₂O (1 · 6H₂O). The structure consists of {HMo₄ O₁₄}_n^{3 n -} chains linked through {Cu₃ (trz)₂}_n^{3 n +} into a three-dimensional framework. The structures of the simple metal-triazole phases [MoO₃(Htrz)_0.5] (2) and [Cu(trz)] (3) are also reported. Compound 2 is two-dimensional, constructed from corner-sharing {MoO₅N} octahedra. Compound 3 consists of {Cu(trz)}_n chains linked through weak Cu⋯Cu contacts into a virtual layer.

Original language	English (US)
Pages (from-to)	2357-2364
Number of pages	8
Journal	Inorganica Chimica Acta
Volume	361
Issue number	8
DOIs	https://doi.org/10.1016/j.ica.2007.12.004
State	Published - Jun 2 2008

Keywords

Hydrothermal synthesis
Metal-triazolate materials
Molybdenum oxide structures
Organic-inorganic hybrid materials

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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@article{c94408e7e61d47d1b040ca145842ade4,

title = "Solid state coordination chemistry of molybdenum oxides with 1,2,3-triazole (Htrz): The crystal structures of [Cu(I)Cu(II)2(trz)2Mo4O13(OH)], [MoO3(Htrz)0.5] and [Cu(I)trz]",

abstract = "Hydrothermal chemistry was used to prepare the bimetallic organic-inorganic hybrid oxide [Cu(I)Cu(II)2(trz)2Mo4O13(OH)] · 6H2O (1 · 6H2O). The structure consists of {HMo4 O14}n3 n - chains linked through {Cu3 (trz)2}n3 n + into a three-dimensional framework. The structures of the simple metal-triazole phases [MoO3(Htrz)0.5] (2) and [Cu(trz)] (3) are also reported. Compound 2 is two-dimensional, constructed from corner-sharing {MoO5N} octahedra. Compound 3 consists of {Cu(trz)}n chains linked through weak Cu⋯Cu contacts into a virtual layer.",

keywords = "Hydrothermal synthesis, Metal-triazolate materials, Molybdenum oxide structures, Organic-inorganic hybrid materials",

author = "Jessica Chuang and Wayne Ouellette and Jon Zubieta",

note = "Funding Information: This work was supported by a grant from the National Science Foundation, CHE-0604527. ",

year = "2008",

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doi = "10.1016/j.ica.2007.12.004",

language = "English (US)",

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journal = "Inorganica Chimica Acta",

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T2 - The crystal structures of [Cu(I)Cu(II)2(trz)2Mo4O13(OH)], [MoO3(Htrz)0.5] and [Cu(I)trz]

AU - Chuang, Jessica

AU - Ouellette, Wayne

AU - Zubieta, Jon

N1 - Funding Information: This work was supported by a grant from the National Science Foundation, CHE-0604527.

PY - 2008/6/2

Y1 - 2008/6/2

N2 - Hydrothermal chemistry was used to prepare the bimetallic organic-inorganic hybrid oxide [Cu(I)Cu(II)2(trz)2Mo4O13(OH)] · 6H2O (1 · 6H2O). The structure consists of {HMo4 O14}n3 n - chains linked through {Cu3 (trz)2}n3 n + into a three-dimensional framework. The structures of the simple metal-triazole phases [MoO3(Htrz)0.5] (2) and [Cu(trz)] (3) are also reported. Compound 2 is two-dimensional, constructed from corner-sharing {MoO5N} octahedra. Compound 3 consists of {Cu(trz)}n chains linked through weak Cu⋯Cu contacts into a virtual layer.

AB - Hydrothermal chemistry was used to prepare the bimetallic organic-inorganic hybrid oxide [Cu(I)Cu(II)2(trz)2Mo4O13(OH)] · 6H2O (1 · 6H2O). The structure consists of {HMo4 O14}n3 n - chains linked through {Cu3 (trz)2}n3 n + into a three-dimensional framework. The structures of the simple metal-triazole phases [MoO3(Htrz)0.5] (2) and [Cu(trz)] (3) are also reported. Compound 2 is two-dimensional, constructed from corner-sharing {MoO5N} octahedra. Compound 3 consists of {Cu(trz)}n chains linked through weak Cu⋯Cu contacts into a virtual layer.

KW - Hydrothermal synthesis

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