TY - JOUR
T1 - Solid state coordination chemistry of molybdenum oxides
T2 - Construction of bimetallic organic-inorganic hybrid materials from Keggin clusters and copper-imine building blocks
AU - Jones, Stephanie
AU - Aldous, Amanda
AU - Burkholder, Eric
AU - Zubieta, Jon
PY - 2013/3/22
Y1 - 2013/3/22
N2 - The unexpected hydrolysis of organophosphonic acid ligands under hydrothermal reaction conditions yielded four bimetallic oxide materials incorporating Keggin type polyanions. The one-dimensional [Cu 4O(Htpyprz)(tpyprz)2Cl4] [Mo 12PO40] (1), [Cu6(4-pyrtet)2(4- Hpyrtet)4][MoVMoV11 IPO40]·2.5H2O (2·2.5H 2O), and [Cu3(OH)(4-pyrtet)2(4-Hpyrtet) 2(H2O)2] [Mo12PO40] ·10.5H2O (3·10.5H2O) and the two-dimensional [Cu3(OH)(4-pyrtet)3(4-H2pyrtet)(H 2O)] [Mo12PO40]·7.5H2O (4·7.5H2O) (tpyprz = tetra-4-pyridyl pyrazine; 4-Hpyrtet = 4-pyridyltetrazole) demonstrate the variety of ways in which Keggin clusters may influence the configuration of the secondary metal-ligand substructure.
AB - The unexpected hydrolysis of organophosphonic acid ligands under hydrothermal reaction conditions yielded four bimetallic oxide materials incorporating Keggin type polyanions. The one-dimensional [Cu 4O(Htpyprz)(tpyprz)2Cl4] [Mo 12PO40] (1), [Cu6(4-pyrtet)2(4- Hpyrtet)4][MoVMoV11 IPO40]·2.5H2O (2·2.5H 2O), and [Cu3(OH)(4-pyrtet)2(4-Hpyrtet) 2(H2O)2] [Mo12PO40] ·10.5H2O (3·10.5H2O) and the two-dimensional [Cu3(OH)(4-pyrtet)3(4-H2pyrtet)(H 2O)] [Mo12PO40]·7.5H2O (4·7.5H2O) (tpyprz = tetra-4-pyridyl pyrazine; 4-Hpyrtet = 4-pyridyltetrazole) demonstrate the variety of ways in which Keggin clusters may influence the configuration of the secondary metal-ligand substructure.
KW - Bimetallic oxides
KW - Copper-organonitrogen ligand chains and networks
KW - Hydrothermal synthesis
KW - Keggin cluster building units
UR - http://www.scopus.com/inward/record.url?scp=84875413967&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84875413967&partnerID=8YFLogxK
U2 - 10.1016/j.poly.2012.08.007
DO - 10.1016/j.poly.2012.08.007
M3 - Article
AN - SCOPUS:84875413967
SN - 0277-5387
VL - 52
SP - 582
EP - 590
JO - Polyhedron
JF - Polyhedron
ER -