Solid state coordination chemistry of microporous metal-organic frameworks of the cadmium(ii)-4-pyridyltetrazolate family: The structural influences of chloride incorporation

Wayne Ouellette, Jon Zubieta

Research output: Contribution to journalArticle

52 Scopus citations

Abstract

While the metal-organic framework [Cd4(OH)2(4-pt) 6(DMF)4]·12DMF (1·12DMF) (4-pt = 4-pyridyltetrazolate) is constructed from binuclear metal subunits, linked into porous {Cd2(OH)(DMF)2(4-pt)3}6 cages, introduction of increasing concentrations of chloride yields the 3-D framework materials, [Cd4Cl3(4-pt)4(OH)(DMF) 3]·8DMF·14MeOH (2·8DMF·14MeOH) and [Cd5Cl6(4-pt)(DMF)2(H2O) 2]·10DMF (3·10DMF), constructed from tetranuclear and chain building blocks, respectively.

Original languageEnglish (US)
Pages (from-to)4533-4535
Number of pages3
JournalChemical Communications
Issue number30
DOIs
StatePublished - 2009

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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