Solid state coordination chemistry of microporous metal-organic frameworks of the cadmium(ii)-4-pyridyltetrazolate family: The structural influences of chloride incorporation

Wayne Ouellette; Jon Zubieta

doi:10.1039/b907149k

Solid state coordination chemistry of microporous metal-organic frameworks of the cadmium(ii)-4-pyridyltetrazolate family: The structural influences of chloride incorporation

Wayne Ouellette, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

54 Scopus citations

Abstract

While the metal-organic framework [Cd₄(OH)₂(4-pt) ₆(DMF)₄]·12DMF (1·12DMF) (4-pt = 4-pyridyltetrazolate) is constructed from binuclear metal subunits, linked into porous {Cd₂(OH)(DMF)₂(4-pt)₃}₆ cages, introduction of increasing concentrations of chloride yields the 3-D framework materials, [Cd₄Cl₃(4-pt)₄(OH)(DMF) ₃]·8DMF·14MeOH (2·8DMF·14MeOH) and [Cd₅Cl₆(4-pt)(DMF)₂(H₂O) ₂]·10DMF (3·10DMF), constructed from tetranuclear and chain building blocks, respectively.

Original language	English (US)
Pages (from-to)	4533-4535
Number of pages	3
Journal	Chemical Communications
Issue number	30
DOIs	https://doi.org/10.1039/b907149k
State	Published - 2009

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1039/b907149k

Cite this

@article{3db3cbec992e4d088c83a644bc375b78,

title = "Solid state coordination chemistry of microporous metal-organic frameworks of the cadmium(ii)-4-pyridyltetrazolate family: The structural influences of chloride incorporation",

abstract = "While the metal-organic framework [Cd4(OH)2(4-pt) 6(DMF)4]·12DMF (1·12DMF) (4-pt = 4-pyridyltetrazolate) is constructed from binuclear metal subunits, linked into porous {Cd2(OH)(DMF)2(4-pt)3}6 cages, introduction of increasing concentrations of chloride yields the 3-D framework materials, [Cd4Cl3(4-pt)4(OH)(DMF) 3]·8DMF·14MeOH (2·8DMF·14MeOH) and [Cd5Cl6(4-pt)(DMF)2(H2O) 2]·10DMF (3·10DMF), constructed from tetranuclear and chain building blocks, respectively.",

author = "Wayne Ouellette and Jon Zubieta",

year = "2009",

doi = "10.1039/b907149k",

language = "English (US)",

pages = "4533--4535",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "30",

}

TY - JOUR

T1 - Solid state coordination chemistry of microporous metal-organic frameworks of the cadmium(ii)-4-pyridyltetrazolate family

T2 - The structural influences of chloride incorporation

AU - Ouellette, Wayne

AU - Zubieta, Jon

PY - 2009

Y1 - 2009

N2 - While the metal-organic framework [Cd4(OH)2(4-pt) 6(DMF)4]·12DMF (1·12DMF) (4-pt = 4-pyridyltetrazolate) is constructed from binuclear metal subunits, linked into porous {Cd2(OH)(DMF)2(4-pt)3}6 cages, introduction of increasing concentrations of chloride yields the 3-D framework materials, [Cd4Cl3(4-pt)4(OH)(DMF) 3]·8DMF·14MeOH (2·8DMF·14MeOH) and [Cd5Cl6(4-pt)(DMF)2(H2O) 2]·10DMF (3·10DMF), constructed from tetranuclear and chain building blocks, respectively.

AB - While the metal-organic framework [Cd4(OH)2(4-pt) 6(DMF)4]·12DMF (1·12DMF) (4-pt = 4-pyridyltetrazolate) is constructed from binuclear metal subunits, linked into porous {Cd2(OH)(DMF)2(4-pt)3}6 cages, introduction of increasing concentrations of chloride yields the 3-D framework materials, [Cd4Cl3(4-pt)4(OH)(DMF) 3]·8DMF·14MeOH (2·8DMF·14MeOH) and [Cd5Cl6(4-pt)(DMF)2(H2O) 2]·10DMF (3·10DMF), constructed from tetranuclear and chain building blocks, respectively.

UR - http://www.scopus.com/inward/record.url?scp=68149153145&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=68149153145&partnerID=8YFLogxK

U2 - 10.1039/b907149k

DO - 10.1039/b907149k

M3 - Article

C2 - 19617974

AN - SCOPUS:68149153145

SN - 1359-7345

SP - 4533

EP - 4535

JO - Chemical Communications

JF - Chemical Communications

IS - 30

ER -

Solid state coordination chemistry of microporous metal-organic frameworks of the cadmium(ii)-4-pyridyltetrazolate family: The structural influences of chloride incorporation

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this