Solid state coordination chemistry of metal oxides: Structural consequences of fluoride incorporation into the oxovanadium-copper-bisterpy-{O3P(CH2)nPO 3}4- system, n = 1-5 (bisterpy = 2,2′:4′,4″:2″,2‴-quaterpyridyl-6′, 6″-di-2-pyridine)

Wayne Ouellette; Vladimir Golub; Charles J. O'Connor; Jon Zubieta

doi:10.1039/b412808g

Solid state coordination chemistry of metal oxides: Structural consequences of fluoride incorporation into the oxovanadium-copper-bisterpy-{O₃P(CH₂)_nPO ₃}^4- system, n = 1-5 (bisterpy = 2,2′:4′,4″:2″,2‴-quaterpyridyl-6′, 6″-di-2-pyridine)

Wayne Ouellette, Vladimir Golub, Charles J. O'Connor, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

47 Scopus citations

Abstract

Hydrothermal reactions of a vanadate source, an appropriate Cu(II) source, bisterpy and an organodiphosphonate, H₂O₃P(CH ₂)_nPO₃H₂ (n = 1-5), in the presence of HF, yielded a family of materials of the type oxyfluorovanadium/ copper-bisterpy/organodiphosphonate. Under similar reaction conditions, variations in diphosphonate tether length n provided the one-dimensional [{Cu₂(bisterpy)}V₂F₂O₂{HO ₃PCH₂PO₃}{O₃PCH₂PO ₃}] (1) and [{Cu₂(bisterpy)}-V₂F ₄O₄{HO₃P(CH₂)₂PO ₃H}] (3), the two-dimensional [{Cu₂(bisterpy)}V ₂F₂O₂(H₂O)₂{HO ₃P(CH₂)₂PO₃} ₂]·2H₂O (2-2H₂O), [{Cu ₂(bisterpy)(H₂O)₂}V₂F ₂O₂{O₃P(CH₂)₃PO ₃}{HO₃P(CH₂)₃PO₃H} (4) and [{Cu₂(bisterpy)}V₄F₄O ₄-(OH)(H₂O){HO₃P(CH₂) ₅PO₃}{O₃P(CH₂)₅PO ₃}]· H₂O (9·H₂O) and the three-dimensional [{Cu₂(bisterpy)}₃V₈F ₆O₁₇-{HO₃P(CH₂)₃PO ₃}₄]·0.8H₂O (5·0.8H ₂O), [{Cu₂(bisterpy)}V₄F₂O ₆{O₃P(CH₂)₄PO₃} ₂] (8) and [{Cu₂(bisterpy)(H₂O)} ₂-V₈F₄O₃(OH)₄{HO ₃P(CH₂)₅PO₃H}₂{O ₃P(CH₂)₅PO₃}3]·4.8H ₂O (10·4.8H₂O). In addition, two members of the oxovanadium/Cu₂(bisterpy)/organodiphosphonate family [{Cu ₂(bisterpy)}V₂O₄{HO₃P(CH ₂)₃PO₃}₂] (6) and [{Cu ₂(bisterpy)}₃V₄O₃(OH) ₂{O₃P(CH₂)₃PO₃} ₂{HO₃P(CH₂)₃PO₃} ₂]·5H₂O (7·5H₂O) cocrystallized from the reaction mixture which provided 5. The overall architectures reveal embedded substructures based on V/P/O(F) clusters, chains, networks, and frameworks. In contrast to the oxovanadium/Cu ₂(bisterpy)/organodiphosphonate family, several of the materials of this study also exhibit the direct condensation of vanadium polyhedra to produce binuclear and/or tetranuclear building units.

Original language	English (US)
Pages (from-to)	291-309
Number of pages	19
Journal	Dalton Transactions
Issue number	2
DOIs	https://doi.org/10.1039/b412808g
State	Published - Jan 21 2005

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Inorganic Chemistry

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Ouellette, W., Golub, V., O'Connor, C. J., & Zubieta, J. (2005). Solid state coordination chemistry of metal oxides: Structural consequences of fluoride incorporation into the oxovanadium-copper-bisterpy-{O₃P(CH₂)_nPO ₃}^4- system, n = 1-5 (bisterpy = 2,2′:4′,4″:2″,2‴-quaterpyridyl-6′, 6″-di-2-pyridine). Dalton Transactions, (2), 291-309. https://doi.org/10.1039/b412808g

Solid state coordination chemistry of metal oxides: Structural consequences of fluoride incorporation into the oxovanadium-copper-bisterpy-{O₃P(CH₂)_nPO ₃}^4- system, n = 1-5 (bisterpy = 2,2′:4′,4″:2″,2‴-quaterpyridyl-6′, 6″-di-2-pyridine). / Ouellette, Wayne; Golub, Vladimir; O'Connor, Charles J. et al.
In: Dalton Transactions, No. 2, 21.01.2005, p. 291-309.

Research output: Contribution to journal › Article › peer-review

Ouellette, W, Golub, V, O'Connor, CJ & Zubieta, J 2005, 'Solid state coordination chemistry of metal oxides: Structural consequences of fluoride incorporation into the oxovanadium-copper-bisterpy-{O₃P(CH₂)_nPO ₃}^4- system, n = 1-5 (bisterpy = 2,2′:4′,4″:2″,2‴-quaterpyridyl-6′, 6″-di-2-pyridine)', Dalton Transactions, no. 2, pp. 291-309. https://doi.org/10.1039/b412808g

Ouellette, Wayne ; Golub, Vladimir ; O'Connor, Charles J. et al. / Solid state coordination chemistry of metal oxides : Structural consequences of fluoride incorporation into the oxovanadium-copper-bisterpy-{O₃P(CH₂)_nPO ₃}^4- system, n = 1-5 (bisterpy = 2,2′:4′,4″:2″,2‴-quaterpyridyl-6′, 6″-di-2-pyridine). In: Dalton Transactions. 2005 ; No. 2. pp. 291-309.

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title = "Solid state coordination chemistry of metal oxides: Structural consequences of fluoride incorporation into the oxovanadium-copper-bisterpy-{O3P(CH2)nPO 3}4- system, n = 1-5 (bisterpy = 2,2′:4′,4″:2″,2‴-quaterpyridyl-6′, 6″-di-2-pyridine)",

abstract = "Hydrothermal reactions of a vanadate source, an appropriate Cu(II) source, bisterpy and an organodiphosphonate, H2O3P(CH 2)nPO3H2 (n = 1-5), in the presence of HF, yielded a family of materials of the type oxyfluorovanadium/ copper-bisterpy/organodiphosphonate. Under similar reaction conditions, variations in diphosphonate tether length n provided the one-dimensional [{Cu2(bisterpy)}V2F2O2{HO 3PCH2PO3}{O3PCH2PO 3}] (1) and [{Cu2(bisterpy)}-V2F 4O4{HO3P(CH2)2PO 3H}] (3), the two-dimensional [{Cu2(bisterpy)}V 2F2O2(H2O)2{HO 3P(CH2)2PO3} 2]·2H2O (2-2H2O), [{Cu 2(bisterpy)(H2O)2}V2F 2O2{O3P(CH2)3PO 3}{HO3P(CH2)3PO3H} (4) and [{Cu2(bisterpy)}V4F4O 4-(OH)(H2O){HO3P(CH2) 5PO3}{O3P(CH2)5PO 3}]· H2O (9·H2O) and the three-dimensional [{Cu2(bisterpy)}3V8F 6O17-{HO3P(CH2)3PO 3}4]·0.8H2O (5·0.8H 2O), [{Cu2(bisterpy)}V4F2O 6{O3P(CH2)4PO3} 2] (8) and [{Cu2(bisterpy)(H2O)} 2-V8F4O3(OH)4{HO 3P(CH2)5PO3H}2{O 3P(CH2)5PO3}3]·4.8H 2O (10·4.8H2O). In addition, two members of the oxovanadium/Cu2(bisterpy)/organodiphosphonate family [{Cu 2(bisterpy)}V2O4{HO3P(CH 2)3PO3}2] (6) and [{Cu 2(bisterpy)}3V4O3(OH) 2{O3P(CH2)3PO3} 2{HO3P(CH2)3PO3} 2]·5H2O (7·5H2O) cocrystallized from the reaction mixture which provided 5. The overall architectures reveal embedded substructures based on V/P/O(F) clusters, chains, networks, and frameworks. In contrast to the oxovanadium/Cu 2(bisterpy)/organodiphosphonate family, several of the materials of this study also exhibit the direct condensation of vanadium polyhedra to produce binuclear and/or tetranuclear building units.",

author = "Wayne Ouellette and Vladimir Golub and O'Connor, {Charles J.} and Jon Zubieta",

year = "2005",

month = jan,

day = "21",

doi = "10.1039/b412808g",

language = "English (US)",

pages = "291--309",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "2",

}

TY - JOUR

T1 - Solid state coordination chemistry of metal oxides

T2 - Structural consequences of fluoride incorporation into the oxovanadium-copper-bisterpy-{O3P(CH2)nPO 3}4- system, n = 1-5 (bisterpy = 2,2′:4′,4″:2″,2‴-quaterpyridyl-6′, 6″-di-2-pyridine)

AU - Ouellette, Wayne

AU - Golub, Vladimir

AU - O'Connor, Charles J.

AU - Zubieta, Jon

PY - 2005/1/21

Y1 - 2005/1/21

N2 - Hydrothermal reactions of a vanadate source, an appropriate Cu(II) source, bisterpy and an organodiphosphonate, H2O3P(CH 2)nPO3H2 (n = 1-5), in the presence of HF, yielded a family of materials of the type oxyfluorovanadium/ copper-bisterpy/organodiphosphonate. Under similar reaction conditions, variations in diphosphonate tether length n provided the one-dimensional [{Cu2(bisterpy)}V2F2O2{HO 3PCH2PO3}{O3PCH2PO 3}] (1) and [{Cu2(bisterpy)}-V2F 4O4{HO3P(CH2)2PO 3H}] (3), the two-dimensional [{Cu2(bisterpy)}V 2F2O2(H2O)2{HO 3P(CH2)2PO3} 2]·2H2O (2-2H2O), [{Cu 2(bisterpy)(H2O)2}V2F 2O2{O3P(CH2)3PO 3}{HO3P(CH2)3PO3H} (4) and [{Cu2(bisterpy)}V4F4O 4-(OH)(H2O){HO3P(CH2) 5PO3}{O3P(CH2)5PO 3}]· H2O (9·H2O) and the three-dimensional [{Cu2(bisterpy)}3V8F 6O17-{HO3P(CH2)3PO 3}4]·0.8H2O (5·0.8H 2O), [{Cu2(bisterpy)}V4F2O 6{O3P(CH2)4PO3} 2] (8) and [{Cu2(bisterpy)(H2O)} 2-V8F4O3(OH)4{HO 3P(CH2)5PO3H}2{O 3P(CH2)5PO3}3]·4.8H 2O (10·4.8H2O). In addition, two members of the oxovanadium/Cu2(bisterpy)/organodiphosphonate family [{Cu 2(bisterpy)}V2O4{HO3P(CH 2)3PO3}2] (6) and [{Cu 2(bisterpy)}3V4O3(OH) 2{O3P(CH2)3PO3} 2{HO3P(CH2)3PO3} 2]·5H2O (7·5H2O) cocrystallized from the reaction mixture which provided 5. The overall architectures reveal embedded substructures based on V/P/O(F) clusters, chains, networks, and frameworks. In contrast to the oxovanadium/Cu 2(bisterpy)/organodiphosphonate family, several of the materials of this study also exhibit the direct condensation of vanadium polyhedra to produce binuclear and/or tetranuclear building units.

AB - Hydrothermal reactions of a vanadate source, an appropriate Cu(II) source, bisterpy and an organodiphosphonate, H2O3P(CH 2)nPO3H2 (n = 1-5), in the presence of HF, yielded a family of materials of the type oxyfluorovanadium/ copper-bisterpy/organodiphosphonate. Under similar reaction conditions, variations in diphosphonate tether length n provided the one-dimensional [{Cu2(bisterpy)}V2F2O2{HO 3PCH2PO3}{O3PCH2PO 3}] (1) and [{Cu2(bisterpy)}-V2F 4O4{HO3P(CH2)2PO 3H}] (3), the two-dimensional [{Cu2(bisterpy)}V 2F2O2(H2O)2{HO 3P(CH2)2PO3} 2]·2H2O (2-2H2O), [{Cu 2(bisterpy)(H2O)2}V2F 2O2{O3P(CH2)3PO 3}{HO3P(CH2)3PO3H} (4) and [{Cu2(bisterpy)}V4F4O 4-(OH)(H2O){HO3P(CH2) 5PO3}{O3P(CH2)5PO 3}]· H2O (9·H2O) and the three-dimensional [{Cu2(bisterpy)}3V8F 6O17-{HO3P(CH2)3PO 3}4]·0.8H2O (5·0.8H 2O), [{Cu2(bisterpy)}V4F2O 6{O3P(CH2)4PO3} 2] (8) and [{Cu2(bisterpy)(H2O)} 2-V8F4O3(OH)4{HO 3P(CH2)5PO3H}2{O 3P(CH2)5PO3}3]·4.8H 2O (10·4.8H2O). In addition, two members of the oxovanadium/Cu2(bisterpy)/organodiphosphonate family [{Cu 2(bisterpy)}V2O4{HO3P(CH 2)3PO3}2] (6) and [{Cu 2(bisterpy)}3V4O3(OH) 2{O3P(CH2)3PO3} 2{HO3P(CH2)3PO3} 2]·5H2O (7·5H2O) cocrystallized from the reaction mixture which provided 5. The overall architectures reveal embedded substructures based on V/P/O(F) clusters, chains, networks, and frameworks. In contrast to the oxovanadium/Cu 2(bisterpy)/organodiphosphonate family, several of the materials of this study also exhibit the direct condensation of vanadium polyhedra to produce binuclear and/or tetranuclear building units.

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