Solid-state coordination chemistry of metal oxides: Hydrothermal synthesis and structural characterization of o-phenanthroline-ligated copper- and zinc-molybdenum oxides

Pamela J. Hagrman, Jon Zubieta

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69 Scopus citations

Abstract

The hydrothermal chemistry of molybdate with phenanthroline in the presence of M(II) cations was investigated. With Cu(II) starting materials, modifications in reaction conditions yielded the molecular cluster [Cu(o-phen)2Mo4O13] (MOXI-27) and one-dimensional [Cu(o-phen)MoO4]·H2O (MOXI-28). The analogous Zn(II)-containing one-dimensional material [Zn(o-phen)MoO4] (MOXI-29) was isolated under conditions similar to those employed for the preparation of MOXI-28. Crystal data: C24H16CuMo4N4O13 (MOXI-27), monoclinic, P21/c, a = 10.5218(3) Å, b = 12.1113(4) Å, c = 22.0125(7) Å, β= 97.988(1)°, Z = 4; C12H10CuMoN2O5 (MOXI-28), monoclinic, P21/n, a = 14.050(1) Å, b = 5.8818(4) Å, c = 16.227(1) Å, β= 103.586(1)°, Z = 4; C12H8MoN2O4Zn (MOXI-29), monoclinic, P21/m, a = 8.7714(7) Å, b = 6.4172(2) Å, c = 10.652(1) Å, β= 100.702(5)°, Z = 2.

Original languageEnglish (US)
Pages (from-to)4480-4485
Number of pages6
JournalInorganic Chemistry
Volume38
Issue number20
DOIs
StatePublished - 1999

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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