Solid-state coordination chemistry of metal oxides: Hydrothermal synthesis and structural characterization of o-phenanthroline-ligated copper- and zinc-molybdenum oxides

Pamela J. Hagrman; Jon Zubieta

doi:10.1021/ic990340p

Solid-state coordination chemistry of metal oxides: Hydrothermal synthesis and structural characterization of o-phenanthroline-ligated copper- and zinc-molybdenum oxides

Pamela J. Hagrman, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

70 Scopus citations

Abstract

The hydrothermal chemistry of molybdate with phenanthroline in the presence of M(II) cations was investigated. With Cu(II) starting materials, modifications in reaction conditions yielded the molecular cluster [Cu(o-phen)₂Mo₄O₁₃] (MOXI-27) and one-dimensional [Cu(o-phen)MoO₄]·H₂O (MOXI-28). The analogous Zn(II)-containing one-dimensional material [Zn(o-phen)MoO₄] (MOXI-29) was isolated under conditions similar to those employed for the preparation of MOXI-28. Crystal data: C₂₄H₁₆CuMo₄N₄O₁₃ (MOXI-27), monoclinic, P2₁/c, a = 10.5218(3) Å, b = 12.1113(4) Å, c = 22.0125(7) Å, β= 97.988(1)°, Z = 4; C₁₂H₁₀CuMoN₂O₅ (MOXI-28), monoclinic, P2₁/n, a = 14.050(1) Å, b = 5.8818(4) Å, c = 16.227(1) Å, β= 103.586(1)°, Z = 4; C₁₂H₈MoN₂O₄Zn (MOXI-29), monoclinic, P2₁/m, a = 8.7714(7) Å, b = 6.4172(2) Å, c = 10.652(1) Å, β= 100.702(5)°, Z = 2.

Original language	English (US)
Pages (from-to)	4480-4485
Number of pages	6
Journal	Inorganic Chemistry
Volume	38
Issue number	20
DOIs	https://doi.org/10.1021/ic990340p
State	Published - 1999

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

Access to Document

10.1021/ic990340p

Cite this

@article{791bdacec2ce440eb35e9838aaa9bc38,

title = "Solid-state coordination chemistry of metal oxides: Hydrothermal synthesis and structural characterization of o-phenanthroline-ligated copper- and zinc-molybdenum oxides",

abstract = "The hydrothermal chemistry of molybdate with phenanthroline in the presence of M(II) cations was investigated. With Cu(II) starting materials, modifications in reaction conditions yielded the molecular cluster [Cu(o-phen)2Mo4O13] (MOXI-27) and one-dimensional [Cu(o-phen)MoO4]·H2O (MOXI-28). The analogous Zn(II)-containing one-dimensional material [Zn(o-phen)MoO4] (MOXI-29) was isolated under conditions similar to those employed for the preparation of MOXI-28. Crystal data: C24H16CuMo4N4O13 (MOXI-27), monoclinic, P21/c, a = 10.5218(3) {\AA}, b = 12.1113(4) {\AA}, c = 22.0125(7) {\AA}, β= 97.988(1)°, Z = 4; C12H10CuMoN2O5 (MOXI-28), monoclinic, P21/n, a = 14.050(1) {\AA}, b = 5.8818(4) {\AA}, c = 16.227(1) {\AA}, β= 103.586(1)°, Z = 4; C12H8MoN2O4Zn (MOXI-29), monoclinic, P21/m, a = 8.7714(7) {\AA}, b = 6.4172(2) {\AA}, c = 10.652(1) {\AA}, β= 100.702(5)°, Z = 2.",

author = "Hagrman, {Pamela J.} and Jon Zubieta",

year = "1999",

doi = "10.1021/ic990340p",

language = "English (US)",

volume = "38",

pages = "4480--4485",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "20",

}

TY - JOUR

T1 - Solid-state coordination chemistry of metal oxides

T2 - Hydrothermal synthesis and structural characterization of o-phenanthroline-ligated copper- and zinc-molybdenum oxides

AU - Hagrman, Pamela J.

AU - Zubieta, Jon

PY - 1999

Y1 - 1999

N2 - The hydrothermal chemistry of molybdate with phenanthroline in the presence of M(II) cations was investigated. With Cu(II) starting materials, modifications in reaction conditions yielded the molecular cluster [Cu(o-phen)2Mo4O13] (MOXI-27) and one-dimensional [Cu(o-phen)MoO4]·H2O (MOXI-28). The analogous Zn(II)-containing one-dimensional material [Zn(o-phen)MoO4] (MOXI-29) was isolated under conditions similar to those employed for the preparation of MOXI-28. Crystal data: C24H16CuMo4N4O13 (MOXI-27), monoclinic, P21/c, a = 10.5218(3) Å, b = 12.1113(4) Å, c = 22.0125(7) Å, β= 97.988(1)°, Z = 4; C12H10CuMoN2O5 (MOXI-28), monoclinic, P21/n, a = 14.050(1) Å, b = 5.8818(4) Å, c = 16.227(1) Å, β= 103.586(1)°, Z = 4; C12H8MoN2O4Zn (MOXI-29), monoclinic, P21/m, a = 8.7714(7) Å, b = 6.4172(2) Å, c = 10.652(1) Å, β= 100.702(5)°, Z = 2.

AB - The hydrothermal chemistry of molybdate with phenanthroline in the presence of M(II) cations was investigated. With Cu(II) starting materials, modifications in reaction conditions yielded the molecular cluster [Cu(o-phen)2Mo4O13] (MOXI-27) and one-dimensional [Cu(o-phen)MoO4]·H2O (MOXI-28). The analogous Zn(II)-containing one-dimensional material [Zn(o-phen)MoO4] (MOXI-29) was isolated under conditions similar to those employed for the preparation of MOXI-28. Crystal data: C24H16CuMo4N4O13 (MOXI-27), monoclinic, P21/c, a = 10.5218(3) Å, b = 12.1113(4) Å, c = 22.0125(7) Å, β= 97.988(1)°, Z = 4; C12H10CuMoN2O5 (MOXI-28), monoclinic, P21/n, a = 14.050(1) Å, b = 5.8818(4) Å, c = 16.227(1) Å, β= 103.586(1)°, Z = 4; C12H8MoN2O4Zn (MOXI-29), monoclinic, P21/m, a = 8.7714(7) Å, b = 6.4172(2) Å, c = 10.652(1) Å, β= 100.702(5)°, Z = 2.

UR - http://www.scopus.com/inward/record.url?scp=0001011166&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0001011166&partnerID=8YFLogxK

U2 - 10.1021/ic990340p

DO - 10.1021/ic990340p

M3 - Article

AN - SCOPUS:0001011166

SN - 0020-1669

VL - 38

SP - 4480

EP - 4485

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 20

ER -

Solid-state coordination chemistry of metal oxides: Hydrothermal synthesis and structural characterization of o-phenanthroline-ligated copper- and zinc-molybdenum oxides

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this