Solid-state coordination chemistry of copper(II) tetrazolates: Anion control of frameworks constructed from trinuclear copper(II) building blocks

Wayne Ouellette; Hongxue Liu; Charles J. O'Connor; Jon Zubieta

doi:10.1021/ic9003802

Solid-state coordination chemistry of copper(II) tetrazolates: Anion control of frameworks constructed from trinuclear copper(II) building blocks

Wayne Ouellette, Hongxue Liu, Charles J. O'Connor, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

67 Scopus citations

Abstract

The products of the reactions of copper(II) starting materials with 4-pyridyltetrazole (4-Hpt) in N,N-dimethylformamide (DMF)/methanol solutions are determined by the anion identity and concentration. In the absence of chloride, the 3-D open-framework material [Cu ₃(OH) ₃(4-pt) ₃(DMF) ₄] · 5DMF · 3MeOH (1 · 5DMF middot; 3MeOH) is isolated, while variations in the chloride concentration yield the 2-D and 3-D materials, 2 and 3, respectively. All three structures exhibit trinuclear copper(II) building blocks: the triangular {Cu ₃(μ ₃-OH)} ⁵⁺ core in 1 and {Cu ₃Cl ₄(4-pt) ₄(4-Hpt) ₂} ^2- and {Cu ₃CI ₂(4-pt) ₈} ^4- chains in 2 and 3, respectively. All three materials display microporosity, which is highly dependent on the method of sample preparation.

Original language	English (US)
Pages (from-to)	4655-4657
Number of pages	3
Journal	Inorganic Chemistry
Volume	48
Issue number	11
DOIs	https://doi.org/10.1021/ic9003802
State	Published - Jun 1 2009

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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@article{acac6ba0e45b49b6ab8b73be8adae0b9,

title = "Solid-state coordination chemistry of copper(II) tetrazolates: Anion control of frameworks constructed from trinuclear copper(II) building blocks",

abstract = "The products of the reactions of copper(II) starting materials with 4-pyridyltetrazole (4-Hpt) in N,N-dimethylformamide (DMF)/methanol solutions are determined by the anion identity and concentration. In the absence of chloride, the 3-D open-framework material [Cu 3(OH) 3(4-pt) 3(DMF) 4] · 5DMF · 3MeOH (1 · 5DMF middot; 3MeOH) is isolated, while variations in the chloride concentration yield the 2-D and 3-D materials, 2 and 3, respectively. All three structures exhibit trinuclear copper(II) building blocks: the triangular {Cu 3(μ 3-OH)} 5+ core in 1 and {Cu 3Cl 4(4-pt) 4(4-Hpt) 2} 2- and {Cu 3CI 2(4-pt) 8} 4- chains in 2 and 3, respectively. All three materials display microporosity, which is highly dependent on the method of sample preparation.",

author = "Wayne Ouellette and Hongxue Liu and O'Connor, {Charles J.} and Jon Zubieta",

year = "2009",

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doi = "10.1021/ic9003802",

language = "English (US)",

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T1 - Solid-state coordination chemistry of copper(II) tetrazolates

T2 - Anion control of frameworks constructed from trinuclear copper(II) building blocks

AU - Ouellette, Wayne

AU - Liu, Hongxue

AU - O'Connor, Charles J.

AU - Zubieta, Jon

PY - 2009/6/1

Y1 - 2009/6/1

N2 - The products of the reactions of copper(II) starting materials with 4-pyridyltetrazole (4-Hpt) in N,N-dimethylformamide (DMF)/methanol solutions are determined by the anion identity and concentration. In the absence of chloride, the 3-D open-framework material [Cu 3(OH) 3(4-pt) 3(DMF) 4] · 5DMF · 3MeOH (1 · 5DMF middot; 3MeOH) is isolated, while variations in the chloride concentration yield the 2-D and 3-D materials, 2 and 3, respectively. All three structures exhibit trinuclear copper(II) building blocks: the triangular {Cu 3(μ 3-OH)} 5+ core in 1 and {Cu 3Cl 4(4-pt) 4(4-Hpt) 2} 2- and {Cu 3CI 2(4-pt) 8} 4- chains in 2 and 3, respectively. All three materials display microporosity, which is highly dependent on the method of sample preparation.

AB - The products of the reactions of copper(II) starting materials with 4-pyridyltetrazole (4-Hpt) in N,N-dimethylformamide (DMF)/methanol solutions are determined by the anion identity and concentration. In the absence of chloride, the 3-D open-framework material [Cu 3(OH) 3(4-pt) 3(DMF) 4] · 5DMF · 3MeOH (1 · 5DMF middot; 3MeOH) is isolated, while variations in the chloride concentration yield the 2-D and 3-D materials, 2 and 3, respectively. All three structures exhibit trinuclear copper(II) building blocks: the triangular {Cu 3(μ 3-OH)} 5+ core in 1 and {Cu 3Cl 4(4-pt) 4(4-Hpt) 2} 2- and {Cu 3CI 2(4-pt) 8} 4- chains in 2 and 3, respectively. All three materials display microporosity, which is highly dependent on the method of sample preparation.

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JF - Inorganic Chemistry

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Solid-state coordination chemistry of copper(II) tetrazolates: Anion control of frameworks constructed from trinuclear copper(II) building blocks

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