Abstract
The hydrothermal reactions of various Cu(II) salts with 3- and 4-pyridinetetrazole and pyrazinetetrazole were exploited in the preparation of a series of Cu(II) and Cu(I) azolate materials. The parent copper/ pyridyltetrazole compositions are observed in the two-dimensional [Cu(3-pyrtet) 2] (1), the reduced three-dimensional [Cu(4-pyrtet)] (2) and reduced two-dimensional [Cu(4-pyrtet)]·0.5DMF (3·0.5DMF) (Hpyrtet = pyridyltetrazole). The consequences of introducing coordinating anions are revealed in the structures of the one-dimensional [CuCl 2(4-Hpyrtet)]·0.5H 2O (4·0.5H 2O) and the two-dimensional [Cu 2I 2(4-Hpyrtet)] (5) and [Cu(acac)(4-pyrtet)] (7) (acac = acetylacetonate; H 2en = ethylenediammonium cation). The pyrazinetetrazolate derivative [H 2en] 0.5[CuCl 2(prztet)] (Hprztet = pyrazinetetrazole) (6) is one-dimensional, but structurally distinct from the chain observed for 4.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 52-60 |
| Number of pages | 9 |
| Journal | Inorganica Chimica Acta |
| Volume | 392 |
| DOIs | |
| State | Published - Sep 30 2012 |
Fingerprint
Keywords
- Copper-pyridyltetrazole coordination polymers
- Hydrothermal synthesis
- Metal-azolate coordination chemistry
- Structural influences of coordinating anions
ASJC Scopus subject areas
- Inorganic Chemistry
- Physical and Theoretical Chemistry
- Materials Chemistry
Cite this
Solid state coordination chemistry of copper with pyridyltetrazoles : Structural consequences of incorporation of coordinating anions. / Darling, Kari; Ouellette, Wayne; Zubieta, Jon A.
In: Inorganica Chimica Acta, Vol. 392, 30.09.2012, p. 52-60.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Solid state coordination chemistry of copper with pyridyltetrazoles
T2 - Structural consequences of incorporation of coordinating anions
AU - Darling, Kari
AU - Ouellette, Wayne
AU - Zubieta, Jon A
PY - 2012/9/30
Y1 - 2012/9/30
N2 - The hydrothermal reactions of various Cu(II) salts with 3- and 4-pyridinetetrazole and pyrazinetetrazole were exploited in the preparation of a series of Cu(II) and Cu(I) azolate materials. The parent copper/ pyridyltetrazole compositions are observed in the two-dimensional [Cu(3-pyrtet) 2] (1), the reduced three-dimensional [Cu(4-pyrtet)] (2) and reduced two-dimensional [Cu(4-pyrtet)]·0.5DMF (3·0.5DMF) (Hpyrtet = pyridyltetrazole). The consequences of introducing coordinating anions are revealed in the structures of the one-dimensional [CuCl 2(4-Hpyrtet)]·0.5H 2O (4·0.5H 2O) and the two-dimensional [Cu 2I 2(4-Hpyrtet)] (5) and [Cu(acac)(4-pyrtet)] (7) (acac = acetylacetonate; H 2en = ethylenediammonium cation). The pyrazinetetrazolate derivative [H 2en] 0.5[CuCl 2(prztet)] (Hprztet = pyrazinetetrazole) (6) is one-dimensional, but structurally distinct from the chain observed for 4.
AB - The hydrothermal reactions of various Cu(II) salts with 3- and 4-pyridinetetrazole and pyrazinetetrazole were exploited in the preparation of a series of Cu(II) and Cu(I) azolate materials. The parent copper/ pyridyltetrazole compositions are observed in the two-dimensional [Cu(3-pyrtet) 2] (1), the reduced three-dimensional [Cu(4-pyrtet)] (2) and reduced two-dimensional [Cu(4-pyrtet)]·0.5DMF (3·0.5DMF) (Hpyrtet = pyridyltetrazole). The consequences of introducing coordinating anions are revealed in the structures of the one-dimensional [CuCl 2(4-Hpyrtet)]·0.5H 2O (4·0.5H 2O) and the two-dimensional [Cu 2I 2(4-Hpyrtet)] (5) and [Cu(acac)(4-pyrtet)] (7) (acac = acetylacetonate; H 2en = ethylenediammonium cation). The pyrazinetetrazolate derivative [H 2en] 0.5[CuCl 2(prztet)] (Hprztet = pyrazinetetrazole) (6) is one-dimensional, but structurally distinct from the chain observed for 4.
KW - Copper-pyridyltetrazole coordination polymers
KW - Hydrothermal synthesis
KW - Metal-azolate coordination chemistry
KW - Structural influences of coordinating anions
UR - http://www.scopus.com/inward/record.url?scp=84865296697&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84865296697&partnerID=8YFLogxK
U2 - 10.1016/j.ica.2012.06.008
DO - 10.1016/j.ica.2012.06.008
M3 - Article
AN - SCOPUS:84865296697
VL - 392
SP - 52
EP - 60
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
SN - 0020-1693
ER -