Abstract
The hydrothermal reaction of the appropriate Co(II) salt and 3- or 4-carboxyphenyltetrazole yielded the molecular [Co(3-trzphCO 2H) 2(H 2O) 4] (2) and the three-dimensional phases [Co(3-trzphCO 2)] (3), [Co(4-trzphCO 2)(H 2O)] (4), and [Co(SO 4)(OH)(3-trzphCO 2H)] (5). The compounds exhibit a range of tetrazolate bonding motifs, including monodentate in 2, bidentate bridging in 3, bridging to three cobalt sites in 4 and bridging four cobalt sites in 5. The three-dimensional connectivities of 3-5 are achieved through the additional linkages provided by the carboxylate groups. The secondary building units include Co-tetrazolate chains in 3, Co-tetrazolate double chains in 4 and {Co 3(tetrazolate) 3(OH)} 2+ trinuclear units in 5.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 36-43 |
| Number of pages | 8 |
| Journal | Inorganica Chimica Acta |
| Volume | 391 |
| DOIs | |
| State | Published - Aug 30 2012 |
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Keywords
- Cobalt-tetrazolate structures
- Hydrothermal synthesis
- Metal-azolates
ASJC Scopus subject areas
- Inorganic Chemistry
- Physical and Theoretical Chemistry
- Materials Chemistry
Cite this
Solid state coordination chemistry of cobalt(II) with carboxyphenyltetrazoles. / Ouellette, Wayne; Darling, Kari; Zubieta, Jon A.
In: Inorganica Chimica Acta, Vol. 391, 30.08.2012, p. 36-43.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Solid state coordination chemistry of cobalt(II) with carboxyphenyltetrazoles
AU - Ouellette, Wayne
AU - Darling, Kari
AU - Zubieta, Jon A
PY - 2012/8/30
Y1 - 2012/8/30
N2 - The hydrothermal reaction of the appropriate Co(II) salt and 3- or 4-carboxyphenyltetrazole yielded the molecular [Co(3-trzphCO 2H) 2(H 2O) 4] (2) and the three-dimensional phases [Co(3-trzphCO 2)] (3), [Co(4-trzphCO 2)(H 2O)] (4), and [Co(SO 4)(OH)(3-trzphCO 2H)] (5). The compounds exhibit a range of tetrazolate bonding motifs, including monodentate in 2, bidentate bridging in 3, bridging to three cobalt sites in 4 and bridging four cobalt sites in 5. The three-dimensional connectivities of 3-5 are achieved through the additional linkages provided by the carboxylate groups. The secondary building units include Co-tetrazolate chains in 3, Co-tetrazolate double chains in 4 and {Co 3(tetrazolate) 3(OH)} 2+ trinuclear units in 5.
AB - The hydrothermal reaction of the appropriate Co(II) salt and 3- or 4-carboxyphenyltetrazole yielded the molecular [Co(3-trzphCO 2H) 2(H 2O) 4] (2) and the three-dimensional phases [Co(3-trzphCO 2)] (3), [Co(4-trzphCO 2)(H 2O)] (4), and [Co(SO 4)(OH)(3-trzphCO 2H)] (5). The compounds exhibit a range of tetrazolate bonding motifs, including monodentate in 2, bidentate bridging in 3, bridging to three cobalt sites in 4 and bridging four cobalt sites in 5. The three-dimensional connectivities of 3-5 are achieved through the additional linkages provided by the carboxylate groups. The secondary building units include Co-tetrazolate chains in 3, Co-tetrazolate double chains in 4 and {Co 3(tetrazolate) 3(OH)} 2+ trinuclear units in 5.
KW - Cobalt-tetrazolate structures
KW - Hydrothermal synthesis
KW - Metal-azolates
UR - http://www.scopus.com/inward/record.url?scp=84862753563&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84862753563&partnerID=8YFLogxK
U2 - 10.1016/j.ica.2012.05.001
DO - 10.1016/j.ica.2012.05.001
M3 - Article
AN - SCOPUS:84862753563
VL - 391
SP - 36
EP - 43
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
SN - 0020-1693
ER -