Solid state coordination chemistry: Construction of 2D networks and 3D frameworks from phosphomolybdate clusters and binuclear Cu(II) complexes. The syntheses and structures of [{Cu2(tpypyz)(H2O)2}(Mo5O15)(HOPO3)2]·nH2O [n = 2, 3; tpypyz = tetra(2-pyridyl)pyrazine]

Eric Burkholder, Jon Zubieta

Research output: Contribution to journalArticle

110 Scopus citations

Abstract

The hydrothermal reaction of MoO3, Cu(C2H3O2)2·H2O, tpypyz, H3PO4 and H2O yields a 2D material, [{Cu2(tpypyz)(H2O)2}(Mo5O15)(HOPO3)2]·2H2O (1·2H2O), constructed from {Mo5O15(HOPO3)2}4 clusters linked through {Cu2(tpypyz)(H2O)2}2+ components; in contrast, use of Cu2O in the synthesis in place of Cu(C2H3O2)2·H2O yields a 3D material [{Cu2(tpypyz)(H2O)2}(Mo5O15)(HOPO3)2]·3H2O (2·3H2O), constructed from the same building blocks as 1·2H2O.

Original languageEnglish (US)
Pages (from-to)2056-2057
Number of pages2
JournalChemical Communications
Volume1
Issue number20
DOIs
StatePublished - Jan 1 2001

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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