Solid state coordination chemistry: Construction of 2D networks and 3D frameworks from phosphomolybdate clusters and binuclear Cu(II) complexes. The syntheses and structures of [{Cu2(tpypyz)(H2O)2}(Mo5O15)(HOPO3)2]·nH2O [n = 2, 3; tpypyz = tetra(2-pyridyl)pyrazine]

Eric Burkholder; Jon Zubieta

doi:10.1039/b105563c

Solid state coordination chemistry: Construction of 2D networks and 3D frameworks from phosphomolybdate clusters and binuclear Cu(II) complexes. The syntheses and structures of [{Cu₂(tpypyz)(H₂O)₂}(Mo₅O₁₅)(HOPO₃)₂]·nH₂O [n = 2, 3; tpypyz = tetra(2-pyridyl)pyrazine]

Eric Burkholder, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

110 Scopus citations

Abstract

The hydrothermal reaction of MoO3, Cu(C₂H₃O₂)₂·H₂O, tpypyz, H₃PO₄ and H₂O yields a 2D material, [{Cu₂(tpypyz)(H₂O)₂}(Mo₅O₁₅)(HOPO₃)₂]·2H₂O (1·2H₂O), constructed from {Mo₅O₁₅(HOPO₃)₂}₄⁻ clusters linked through {Cu₂(tpypyz)(H₂O)₂}2⁺ components; in contrast, use of Cu₂O in the synthesis in place of Cu(C₂H₃O₂)2·H2O yields a 3D material [{Cu₂(tpypyz)(H₂O)₂}(Mo₅O₁₅)(HOPO₃)₂]·3H₂O (2·3H₂O), constructed from the same building blocks as 1·2H₂O.

Original language	English (US)
Pages (from-to)	2056-2057
Number of pages	2
Journal	Chemical Communications
Volume	1
Issue number	20
DOIs	https://doi.org/10.1039/b105563c
State	Published - 2001

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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Burkholder, E., & Zubieta, J. (2001). Solid state coordination chemistry: Construction of 2D networks and 3D frameworks from phosphomolybdate clusters and binuclear Cu(II) complexes. The syntheses and structures of [{Cu₂(tpypyz)(H₂O)₂}(Mo₅O₁₅)(HOPO₃)₂]·nH₂O [n = 2, 3; tpypyz = tetra(2-pyridyl)pyrazine]. Chemical Communications, 1(20), 2056-2057. https://doi.org/10.1039/b105563c

Solid state coordination chemistry: Construction of 2D networks and 3D frameworks from phosphomolybdate clusters and binuclear Cu(II) complexes. The syntheses and structures of [{Cu₂(tpypyz)(H₂O)₂}(Mo₅O₁₅)(HOPO₃)₂]·nH₂O [n = 2, 3; tpypyz = tetra(2-pyridyl)pyrazine]. / Burkholder, Eric; Zubieta, Jon.
In: Chemical Communications, Vol. 1, No. 20, 2001, p. 2056-2057.

Research output: Contribution to journal › Article › peer-review

Burkholder, E & Zubieta, J 2001, 'Solid state coordination chemistry: Construction of 2D networks and 3D frameworks from phosphomolybdate clusters and binuclear Cu(II) complexes. The syntheses and structures of [{Cu₂(tpypyz)(H₂O)₂}(Mo₅O₁₅)(HOPO₃)₂]·nH₂O [n = 2, 3; tpypyz = tetra(2-pyridyl)pyrazine]', Chemical Communications, vol. 1, no. 20, pp. 2056-2057. https://doi.org/10.1039/b105563c

Burkholder, Eric ; Zubieta, Jon. / Solid state coordination chemistry : Construction of 2D networks and 3D frameworks from phosphomolybdate clusters and binuclear Cu(II) complexes. The syntheses and structures of [{Cu₂(tpypyz)(H₂O)₂}(Mo₅O₁₅)(HOPO₃)₂]·nH₂O [n = 2, 3; tpypyz = tetra(2-pyridyl)pyrazine]. In: Chemical Communications. 2001 ; Vol. 1, No. 20. pp. 2056-2057.

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title = "Solid state coordination chemistry: Construction of 2D networks and 3D frameworks from phosphomolybdate clusters and binuclear Cu(II) complexes. The syntheses and structures of [{Cu2(tpypyz)(H2O)2}(Mo5O15)(HOPO3)2]·nH2O [n = 2, 3; tpypyz = tetra(2-pyridyl)pyrazine]",

abstract = "The hydrothermal reaction of MoO3, Cu(C2H3O2)2·H2O, tpypyz, H3PO4 and H2O yields a 2D material, [{Cu2(tpypyz)(H2O)2}(Mo5O15)(HOPO3)2]·2H2O (1·2H2O), constructed from {Mo5O15(HOPO3)2}4− clusters linked through {Cu2(tpypyz)(H2O)2}2+ components; in contrast, use of Cu2O in the synthesis in place of Cu(C2H3O2)2·H2O yields a 3D material [{Cu2(tpypyz)(H2O)2}(Mo5O15)(HOPO3)2]·3H2O (2·3H2O), constructed from the same building blocks as 1·2H2O.",

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