TY - JOUR
T1 - Silylamines with Pyramidal Coordination at Nitrogen
AU - Ruhlandt‐Senge, Karin
AU - Bartlett, Ruth A.
AU - Olmstead, Marilyn M.
AU - Power, Philip P.
PY - 1993/3
Y1 - 1993/3
N2 - The π component of the SiN bond in silylamines has little if any influence on their structure—this was established from the X‐ray structures of the silylamines 1–3. The structural analyses show that the coordination at the nitrogen centers is pyramidal rather than planar and that the SiN distances are essentially invariant. Mes = 2,4,6‐Me3C6H2, Triph = 2,4,6‐Ph3C6H2. (Formula Presented.)
AB - The π component of the SiN bond in silylamines has little if any influence on their structure—this was established from the X‐ray structures of the silylamines 1–3. The structural analyses show that the coordination at the nitrogen centers is pyramidal rather than planar and that the SiN distances are essentially invariant. Mes = 2,4,6‐Me3C6H2, Triph = 2,4,6‐Ph3C6H2. (Formula Presented.)
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U2 - 10.1002/anie.199304251
DO - 10.1002/anie.199304251
M3 - Article
AN - SCOPUS:33745120472
SN - 0570-0833
VL - 32
SP - 425
EP - 427
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
IS - 3
ER -