Silylamines with Pyramidal Coordination at Nitrogen

Karin Ruhlandt‐Senge, Ruth A. Bartlett, Marilyn M. Olmstead, Philip P. Power

Research output: Contribution to journalArticle

49 Scopus citations

Abstract

The π component of the SiN bond in silylamines has little if any influence on their structure—this was established from the X‐ray structures of the silylamines 1–3. The structural analyses show that the coordination at the nitrogen centers is pyramidal rather than planar and that the SiN distances are essentially invariant. Mes = 2,4,6‐Me3C6H2, Triph = 2,4,6‐Ph3C6H2. (Formula Presented.)

Original languageEnglish (US)
Pages (from-to)425-427
Number of pages3
JournalAngewandte Chemie International Edition in English
Volume32
Issue number3
DOIs
StatePublished - Mar 1993
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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