Rhodium(III) complexes with sterically-hindered thiolate ligands. Crystal structures of [Rh(2-SC5H3N-3-SiMe3)3] and [Rh(2-SC5H3N-3-SiMe3)2(C5Me5)]·CH3CN

Eric Block; Gabriel Ofori-Okai; Kang Hyunkyu; Chen Oin; Jon Zubieta

doi:10.1016/S0020-1693(00)80237-6

Rhodium(III) complexes with sterically-hindered thiolate ligands. Crystal structures of [Rh(2-SC₅H₃N-3-SiMe₃)₃] and [Rh(2-SC₅H₃N-3-SiMe₃)₂(C₅Me₅)]·CH₃CN

Eric Block, Gabriel Ofori-Okai, Kang Hyunkyu, Chen Oin, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

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Abstract

The complex [Rh(2-SC₅H₃N-3-SiMe₃)₃] (1) may be prepared by the reaction of Rh(NO₃)₃ with 2-HSC₅H₃N-3-SiMe₃ in ethanol. The structure of 1 is similar to that of [Rh(2-SC₅H₄N)₃]. The reaction of [Rh(C₅Me₅)Cl₂]₂ with 2-HSC₅H₃N-3-SiMe₃ in acetonitrile yields [Rh(2-SC₅H₃N-3- SiMe₃)₂(C₅Me₅)]·CH₃CN (2), whose structure exhibits two distinct types of pyridinethiolato ligation: monodentate through the S donor and bidentate through S and N donors. Crystal data: 1, orthorhombic, Pbca, a=23.444(4), b=21.138(4), c=13.348(2) Å, V=6615.1(12) Å³, Z=8; 2, monoclinic, C2/c, a=18.978(3), b=14.437(2), c=24.309(5) Å, β=100.09(1)°, V=6557.4(11) Å³, Z=8.

Original language	English (US)
Pages (from-to)	97-102
Number of pages	6
Journal	Inorganica Chimica Acta
Volume	190
Issue number	1
DOIs	https://doi.org/10.1016/S0020-1693(00)80237-6
State	Published - Dec 1 1991

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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title = "Rhodium(III) complexes with sterically-hindered thiolate ligands. Crystal structures of [Rh(2-SC5H3N-3-SiMe3)3] and [Rh(2-SC5H3N-3-SiMe3)2(C5Me5)]·CH3CN",

abstract = "The complex [Rh(2-SC5H3N-3-SiMe3)3] (1) may be prepared by the reaction of Rh(NO3)3 with 2-HSC5H3N-3-SiMe3 in ethanol. The structure of 1 is similar to that of [Rh(2-SC5H4N)3]. The reaction of [Rh(C5Me5)Cl2]2 with 2-HSC5H3N-3-SiMe3 in acetonitrile yields [Rh(2-SC5H3N-3- SiMe3)2(C5Me5)]·CH3CN (2), whose structure exhibits two distinct types of pyridinethiolato ligation: monodentate through the S donor and bidentate through S and N donors. Crystal data: 1, orthorhombic, Pbca, a=23.444(4), b=21.138(4), c=13.348(2) {\AA}, V=6615.1(12) {\AA}3, Z=8; 2, monoclinic, C2/c, a=18.978(3), b=14.437(2), c=24.309(5) {\AA}, β=100.09(1)°, V=6557.4(11) {\AA}3, Z=8.",

author = "Eric Block and Gabriel Ofori-Okai and Kang Hyunkyu and Chen Oin and Jon Zubieta",

note = "Funding Information: Support from the National Institutes (GM22566) is gratefully acknowledged.",

year = "1991",

month = dec,

day = "1",

doi = "10.1016/S0020-1693(00)80237-6",

language = "English (US)",

volume = "190",

pages = "97--102",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier",

number = "1",

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TY - JOUR

T1 - Rhodium(III) complexes with sterically-hindered thiolate ligands. Crystal structures of [Rh(2-SC5H3N-3-SiMe3)3] and [Rh(2-SC5H3N-3-SiMe3)2(C5Me5)]·CH3CN

AU - Block, Eric

AU - Ofori-Okai, Gabriel

AU - Hyunkyu, Kang

AU - Oin, Chen

AU - Zubieta, Jon

N1 - Funding Information: Support from the National Institutes (GM22566) is gratefully acknowledged.

PY - 1991/12/1

Y1 - 1991/12/1

N2 - The complex [Rh(2-SC5H3N-3-SiMe3)3] (1) may be prepared by the reaction of Rh(NO3)3 with 2-HSC5H3N-3-SiMe3 in ethanol. The structure of 1 is similar to that of [Rh(2-SC5H4N)3]. The reaction of [Rh(C5Me5)Cl2]2 with 2-HSC5H3N-3-SiMe3 in acetonitrile yields [Rh(2-SC5H3N-3- SiMe3)2(C5Me5)]·CH3CN (2), whose structure exhibits two distinct types of pyridinethiolato ligation: monodentate through the S donor and bidentate through S and N donors. Crystal data: 1, orthorhombic, Pbca, a=23.444(4), b=21.138(4), c=13.348(2) Å, V=6615.1(12) Å3, Z=8; 2, monoclinic, C2/c, a=18.978(3), b=14.437(2), c=24.309(5) Å, β=100.09(1)°, V=6557.4(11) Å3, Z=8.

AB - The complex [Rh(2-SC5H3N-3-SiMe3)3] (1) may be prepared by the reaction of Rh(NO3)3 with 2-HSC5H3N-3-SiMe3 in ethanol. The structure of 1 is similar to that of [Rh(2-SC5H4N)3]. The reaction of [Rh(C5Me5)Cl2]2 with 2-HSC5H3N-3-SiMe3 in acetonitrile yields [Rh(2-SC5H3N-3- SiMe3)2(C5Me5)]·CH3CN (2), whose structure exhibits two distinct types of pyridinethiolato ligation: monodentate through the S donor and bidentate through S and N donors. Crystal data: 1, orthorhombic, Pbca, a=23.444(4), b=21.138(4), c=13.348(2) Å, V=6615.1(12) Å3, Z=8; 2, monoclinic, C2/c, a=18.978(3), b=14.437(2), c=24.309(5) Å, β=100.09(1)°, V=6557.4(11) Å3, Z=8.

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DO - 10.1016/S0020-1693(00)80237-6

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EP - 102

JO - Inorganica Chimica Acta

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ER -

Rhodium(III) complexes with sterically-hindered thiolate ligands. Crystal structures of [Rh(2-SC₅H₃N-3-SiMe₃)₃] and [Rh(2-SC₅H₃N-3-SiMe₃)₂(C₅Me₅)]·CH₃CN

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