TY - JOUR
T1 - Resonance raman study of the first absorption band of H2S
AU - Brudzynski, Richard J.
AU - Sension, Roseanne J.
AU - Hudson, Bruce
PY - 1990/2/2
Y1 - 1990/2/2
N2 - Raman spectra of hydrogen sulfide excited at nine wavelengths throughout its first absorption feature in the 180-250 nm region are reported. The spectra are dominated by transitions to S-H stretching overtone states. Several bands corresponding to combinations involving one quantum of the bending vibration are also observed. The intensity pattern varies significantly with excitation energy. These results are interpreted in terms of the nature and number of the excited state potential energy surface(s) in this spectral region.
AB - Raman spectra of hydrogen sulfide excited at nine wavelengths throughout its first absorption feature in the 180-250 nm region are reported. The spectra are dominated by transitions to S-H stretching overtone states. Several bands corresponding to combinations involving one quantum of the bending vibration are also observed. The intensity pattern varies significantly with excitation energy. These results are interpreted in terms of the nature and number of the excited state potential energy surface(s) in this spectral region.
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U2 - 10.1016/0009-2614(90)87027-O
DO - 10.1016/0009-2614(90)87027-O
M3 - Article
AN - SCOPUS:0000162599
SN - 0009-2614
VL - 165
SP - 487
EP - 493
JO - Chemical Physics Letters
JF - Chemical Physics Letters
IS - 6
ER -