Resonance raman study of the first absorption band of H2S

Richard J. Brudzynski, Roseanne J. Sension, Bruce Hudson

Research output: Contribution to journalArticle

37 Scopus citations

Abstract

Raman spectra of hydrogen sulfide excited at nine wavelengths throughout its first absorption feature in the 180-250 nm region are reported. The spectra are dominated by transitions to S-H stretching overtone states. Several bands corresponding to combinations involving one quantum of the bending vibration are also observed. The intensity pattern varies significantly with excitation energy. These results are interpreted in terms of the nature and number of the excited state potential energy surface(s) in this spectral region.

Original languageEnglish (US)
Pages (from-to)487-493
Number of pages7
JournalChemical Physics Letters
Volume165
Issue number6
DOIs
StatePublished - Feb 2 1990

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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