Resonance Raman scattering in the 1Σg+ → 1B2 (1Σu+) transition of CS2

R. A. Desiderio; D. P. Gerrity; B. S. Hudson

doi:10.1016/0009-2614(85)80096-8

Resonance Raman scattering in the ¹Σ_g⁺ → ¹B₂ (¹Σ_u⁺) transition of CS₂

R. A. Desiderio, D. P. Gerrity, B. S. Hudson

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

Resonance Raman spectra of CS₂ are presented at excitation wavelengths of 204 and 200 nm. Both spectra show activity in the symmetric (ν₁) stretch and bending (ν₂) modes consistent with a bent, symmetrically stretched ¹B₂(¹Σ_u⁺) upper state. In addition, these spectra show activity of the transition involving two quanta in the asymmetric (ν₃) stretch as well as progressions in ν₁ and ν₂ based upon this asymmetric mode overtone.

Original language	English (US)
Pages (from-to)	29-33
Number of pages	5
Journal	Chemical Physics Letters
Volume	115
Issue number	1
DOIs	https://doi.org/10.1016/0009-2614(85)80096-8
State	Published - Mar 22 1985

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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title = "Resonance Raman scattering in the 1Σg+ → 1B2 (1Σu+) transition of CS2",

abstract = "Resonance Raman spectra of CS2 are presented at excitation wavelengths of 204 and 200 nm. Both spectra show activity in the symmetric (ν1) stretch and bending (ν2) modes consistent with a bent, symmetrically stretched 1B2(1Σu+) upper state. In addition, these spectra show activity of the transition involving two quanta in the asymmetric (ν3) stretch as well as progressions in ν1 and ν2 based upon this asymmetric mode overtone.",

author = "Desiderio, {R. A.} and Gerrity, {D. P.} and Hudson, {B. S.}",

note = "Funding Information: Acknowledgement is made to the National Science Foundation (CHES l-19630), and to the Donors of The Petroleum Research Fund (13672-AC6), adminis-tered by the American Chemical Society, for the sup-pert of this research.",

year = "1985",

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doi = "10.1016/0009-2614(85)80096-8",

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T1 - Resonance Raman scattering in the 1Σg+ → 1B2 (1Σu+) transition of CS2

AU - Desiderio, R. A.

AU - Gerrity, D. P.

AU - Hudson, B. S.

N1 - Funding Information: Acknowledgement is made to the National Science Foundation (CHES l-19630), and to the Donors of The Petroleum Research Fund (13672-AC6), adminis-tered by the American Chemical Society, for the sup-pert of this research.

PY - 1985/3/22

Y1 - 1985/3/22

N2 - Resonance Raman spectra of CS2 are presented at excitation wavelengths of 204 and 200 nm. Both spectra show activity in the symmetric (ν1) stretch and bending (ν2) modes consistent with a bent, symmetrically stretched 1B2(1Σu+) upper state. In addition, these spectra show activity of the transition involving two quanta in the asymmetric (ν3) stretch as well as progressions in ν1 and ν2 based upon this asymmetric mode overtone.

AB - Resonance Raman spectra of CS2 are presented at excitation wavelengths of 204 and 200 nm. Both spectra show activity in the symmetric (ν1) stretch and bending (ν2) modes consistent with a bent, symmetrically stretched 1B2(1Σu+) upper state. In addition, these spectra show activity of the transition involving two quanta in the asymmetric (ν3) stretch as well as progressions in ν1 and ν2 based upon this asymmetric mode overtone.

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Resonance Raman scattering in the ¹Σ_g⁺ → ¹B₂ (¹Σ_u⁺) transition of CS₂

Abstract

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