Reduction of a Tetraaryldigallane to Afford a Radical Anion with GaGa Multiple Bonding Character

Xiaoming He; Ruth A. Bartlett; Marilyn M. Olmstead; Karin Ruhlandt‐Senge; Bradley E. Sturgeon; Philip P. Power

doi:10.1002/anie.199307171

Reduction of a Tetraaryldigallane to Afford a Radical Anion with GaGa Multiple Bonding Character

Xiaoming He, Ruth A. Bartlett, Marilyn M. Olmstead, Karin Ruhlandt‐Senge, Bradley E. Sturgeon, Philip P. Power

Research output: Contribution to journal › Article › peer-review

127 Scopus citations

Abstract

The shortening of the GaGa bond in Trip₂GaGaTrip₂ (1, TripH  2,4,6‐iPr₃C₆H₃) by 0.17 Å to 2.343(2) Å on formation of the radical anion 1^˙− is due, at least in part, to the formation of a one‐electron π bond between the gallium atoms. (Figure Presented.)

Original language	English (US)
Pages (from-to)	717-719
Number of pages	3
Journal	Angewandte Chemie International Edition in English
Volume	32
Issue number	5
DOIs	https://doi.org/10.1002/anie.199307171
State	Published - May 1993
Externally published	Yes

ASJC Scopus subject areas

Catalysis
General Chemistry

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@article{61ef5b9f05224903898f75e7652e32b8,

title = "Reduction of a Tetraaryldigallane to Afford a Radical Anion with GaGa Multiple Bonding Character",

abstract = "The shortening of the GaGa bond in Trip2GaGaTrip2 (1, TripH  2,4,6‐iPr3C6H3) by 0.17 {\AA} to 2.343(2) {\AA} on formation of the radical anion 1˙− is due, at least in part, to the formation of a one‐electron π bond between the gallium atoms. (Figure Presented.)",

author = "Xiaoming He and Bartlett, {Ruth A.} and Olmstead, {Marilyn M.} and Karin Ruhlandt‐Senge and Sturgeon, {Bradley E.} and Power, {Philip P.}",

year = "1993",

month = may,

doi = "10.1002/anie.199307171",

language = "English (US)",

volume = "32",

pages = "717--719",

journal = "Angewandte Chemie International Edition in English",

issn = "0570-0833",

publisher = "John Wiley and Sons Ltd",

number = "5",

}

TY - JOUR

T1 - Reduction of a Tetraaryldigallane to Afford a Radical Anion with GaGa Multiple Bonding Character

AU - He, Xiaoming

AU - Bartlett, Ruth A.

AU - Olmstead, Marilyn M.

AU - Ruhlandt‐Senge, Karin

AU - Sturgeon, Bradley E.

AU - Power, Philip P.

PY - 1993/5

Y1 - 1993/5

N2 - The shortening of the GaGa bond in Trip2GaGaTrip2 (1, TripH  2,4,6‐iPr3C6H3) by 0.17 Å to 2.343(2) Å on formation of the radical anion 1˙− is due, at least in part, to the formation of a one‐electron π bond between the gallium atoms. (Figure Presented.)

AB - The shortening of the GaGa bond in Trip2GaGaTrip2 (1, TripH  2,4,6‐iPr3C6H3) by 0.17 Å to 2.343(2) Å on formation of the radical anion 1˙− is due, at least in part, to the formation of a one‐electron π bond between the gallium atoms. (Figure Presented.)

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U2 - 10.1002/anie.199307171

DO - 10.1002/anie.199307171

M3 - Article

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SN - 0570-0833

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JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 5

ER -

Reduction of a Tetraaryldigallane to Afford a Radical Anion with GaGa Multiple Bonding Character

Abstract

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