[Re(CO)3(5-PAN)Cl], a rhenium(i) naphthalimide complex for the visible light photocatalytic reduction of CO2

Derek R. Case; Alyssa Spear; Adam F. Henwood; Max Nanao; Sara Dampf; Timothy M. Korter; Thorfinnur Gunnlaugsson; Jon Zubieta; Robert P. Doyle

doi:10.1039/d0dt04116e

[Re(CO)₃(5-PAN)Cl], a rhenium(i) naphthalimide complex for the visible light photocatalytic reduction of CO₂

Derek R. Case, Alyssa Spear, Adam F. Henwood, Max Nanao, Sara Dampf, Timothy M. Korter, Thorfinnur Gunnlaugsson, Jon Zubieta, Robert P. Doyle

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Abstract

A rhenium(i) naphthalimide complex [Re(CO)₃(5-PAN)Cl] (Re(5-PAN); 5-PAN = 1-(1,10-phenanthroline)-4-nitro-naphthalimide) was synthesized, characterized, and evaluated as a photocatalyst for CO₂reduction. Characterization included use of MALDI-ToF mass spectrometry, FT-IR, RAMAN,¹H and¹³C NMR, elemental analysis, electronic absorption and emission spectroscopy, single crystal X-ray diffraction, DFT and cyclic voltammetry. Photocatalytic (406 nm) reduction of¹³CO₂to formate (H¹³COO) in the presence of this catalyst was trackedvia¹³C NMR. Results support Re5-PAN (φ= 0.021) functioning as a catalyst for the reduction of CO₂(maximum turn-over 48-50 at 300 equiv. triethylamine as the sacrificial electron donor).

Original language	English (US)
Pages (from-to)	3479-3486
Number of pages	8
Journal	Dalton Transactions
Volume	50
Issue number	10
DOIs	https://doi.org/10.1039/d0dt04116e
State	Published - Mar 14 2021

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Inorganic Chemistry

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title = "[Re(CO)3(5-PAN)Cl], a rhenium(i) naphthalimide complex for the visible light photocatalytic reduction of CO2",

abstract = "A rhenium(i) naphthalimide complex [Re(CO)3(5-PAN)Cl] (Re(5-PAN); 5-PAN = 1-(1,10-phenanthroline)-4-nitro-naphthalimide) was synthesized, characterized, and evaluated as a photocatalyst for CO2reduction. Characterization included use of MALDI-ToF mass spectrometry, FT-IR, RAMAN,1H and13C NMR, elemental analysis, electronic absorption and emission spectroscopy, single crystal X-ray diffraction, DFT and cyclic voltammetry. Photocatalytic (406 nm) reduction of13CO2to formate (H13COO) in the presence of this catalyst was trackedvia13C NMR. Results support Re5-PAN (φ= 0.021) functioning as a catalyst for the reduction of CO2(maximum turn-over 48-50 at 300 equiv. triethylamine as the sacrificial electron donor).",

author = "Case, {Derek R.} and Alyssa Spear and Henwood, {Adam F.} and Max Nanao and Sara Dampf and Korter, {Timothy M.} and Thorfinnur Gunnlaugsson and Jon Zubieta and Doyle, {Robert P.}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2021.",

year = "2021",

month = mar,

day = "14",

doi = "10.1039/d0dt04116e",

language = "English (US)",

volume = "50",

pages = "3479--3486",

journal = "Dalton Transactions",

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T1 - [Re(CO)3(5-PAN)Cl], a rhenium(i) naphthalimide complex for the visible light photocatalytic reduction of CO2

AU - Case, Derek R.

AU - Spear, Alyssa

AU - Henwood, Adam F.

AU - Nanao, Max

AU - Dampf, Sara

AU - Korter, Timothy M.

AU - Gunnlaugsson, Thorfinnur

AU - Zubieta, Jon

AU - Doyle, Robert P.

PY - 2021/3/14

Y1 - 2021/3/14

N2 - A rhenium(i) naphthalimide complex [Re(CO)3(5-PAN)Cl] (Re(5-PAN); 5-PAN = 1-(1,10-phenanthroline)-4-nitro-naphthalimide) was synthesized, characterized, and evaluated as a photocatalyst for CO2reduction. Characterization included use of MALDI-ToF mass spectrometry, FT-IR, RAMAN,1H and13C NMR, elemental analysis, electronic absorption and emission spectroscopy, single crystal X-ray diffraction, DFT and cyclic voltammetry. Photocatalytic (406 nm) reduction of13CO2to formate (H13COO) in the presence of this catalyst was trackedvia13C NMR. Results support Re5-PAN (φ= 0.021) functioning as a catalyst for the reduction of CO2(maximum turn-over 48-50 at 300 equiv. triethylamine as the sacrificial electron donor).

AB - A rhenium(i) naphthalimide complex [Re(CO)3(5-PAN)Cl] (Re(5-PAN); 5-PAN = 1-(1,10-phenanthroline)-4-nitro-naphthalimide) was synthesized, characterized, and evaluated as a photocatalyst for CO2reduction. Characterization included use of MALDI-ToF mass spectrometry, FT-IR, RAMAN,1H and13C NMR, elemental analysis, electronic absorption and emission spectroscopy, single crystal X-ray diffraction, DFT and cyclic voltammetry. Photocatalytic (406 nm) reduction of13CO2to formate (H13COO) in the presence of this catalyst was trackedvia13C NMR. Results support Re5-PAN (φ= 0.021) functioning as a catalyst for the reduction of CO2(maximum turn-over 48-50 at 300 equiv. triethylamine as the sacrificial electron donor).

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[Re(CO)₃(5-PAN)Cl], a rhenium(i) naphthalimide complex for the visible light photocatalytic reduction of CO₂

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