Reactive extraction of levulinate esters and conversion to γ-Valerolactone for production of liquid fuels

Elif I. Gürbüz; David Martin Alonso; Jesse Q. Bond; James A. Dumesic

doi:10.1002/cssc.201000396

Reactive extraction of levulinate esters and conversion to γ-Valerolactone for production of liquid fuels

Elif I. Gürbüz, David Martin Alonso, Jesse Q. Bond, James A. Dumesic

Research output: Contribution to journal › Article › peer-review

163 Scopus citations

Abstract

Reactive extraction of cellulose-derived levulinic and formic acids with butene is utilized to obtain levulinate and formate esters, thereby allowing for recovery and recycle of H₂SO₄. The esters are converted over a dual-catalyst-bed system to GVL and 2-butanol, followed by production of butene to be recycled for reactive extraction and to be converted to liquid fuels by oligomerization.

Original language	English (US)
Pages (from-to)	357-361
Number of pages	5
Journal	ChemSusChem
Volume	4
Issue number	3
DOIs	https://doi.org/10.1002/cssc.201000396
State	Published - Mar 21 2011
Externally published	Yes

Keywords

Biofuels
Heterogeneous catalysis
Reactive extraction
Sustainable chemistry
Valerolactone

ASJC Scopus subject areas

Environmental Chemistry
Chemical Engineering(all)
Materials Science(all)
Energy(all)

Access to Document

10.1002/cssc.201000396

Cite this

@article{aa24c60e4238433bacb7dd923ba8da7d,

title = "Reactive extraction of levulinate esters and conversion to γ-Valerolactone for production of liquid fuels",

abstract = "Reactive extraction of cellulose-derived levulinic and formic acids with butene is utilized to obtain levulinate and formate esters, thereby allowing for recovery and recycle of H2SO4. The esters are converted over a dual-catalyst-bed system to GVL and 2-butanol, followed by production of butene to be recycled for reactive extraction and to be converted to liquid fuels by oligomerization.",

keywords = "Biofuels, Heterogeneous catalysis, Reactive extraction, Sustainable chemistry, Valerolactone",

author = "G{\"u}rb{\"u}z, {Elif I.} and Alonso, {David Martin} and Bond, {Jesse Q.} and Dumesic, {James A.}",

year = "2011",

month = mar,

day = "21",

doi = "10.1002/cssc.201000396",

language = "English (US)",

volume = "4",

pages = "357--361",

journal = "ChemSusChem",

issn = "1864-5631",

publisher = "Wiley-VCH Verlag",

number = "3",

}

TY - JOUR

T1 - Reactive extraction of levulinate esters and conversion to γ-Valerolactone for production of liquid fuels

AU - Gürbüz, Elif I.

AU - Alonso, David Martin

AU - Bond, Jesse Q.

AU - Dumesic, James A.

PY - 2011/3/21

Y1 - 2011/3/21

N2 - Reactive extraction of cellulose-derived levulinic and formic acids with butene is utilized to obtain levulinate and formate esters, thereby allowing for recovery and recycle of H2SO4. The esters are converted over a dual-catalyst-bed system to GVL and 2-butanol, followed by production of butene to be recycled for reactive extraction and to be converted to liquid fuels by oligomerization.

AB - Reactive extraction of cellulose-derived levulinic and formic acids with butene is utilized to obtain levulinate and formate esters, thereby allowing for recovery and recycle of H2SO4. The esters are converted over a dual-catalyst-bed system to GVL and 2-butanol, followed by production of butene to be recycled for reactive extraction and to be converted to liquid fuels by oligomerization.

KW - Biofuels

KW - Heterogeneous catalysis

KW - Reactive extraction

KW - Sustainable chemistry

KW - Valerolactone

UR - http://www.scopus.com/inward/record.url?scp=79955578043&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=79955578043&partnerID=8YFLogxK

U2 - 10.1002/cssc.201000396

DO - 10.1002/cssc.201000396

M3 - Article

C2 - 21394926

AN - SCOPUS:79955578043

SN - 1864-5631

VL - 4

SP - 357

EP - 361

JO - ChemSusChem

JF - ChemSusChem

IS - 3

ER -

Reactive extraction of levulinate esters and conversion to γ-Valerolactone for production of liquid fuels

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this