Reactions of molybdenum (V) oxychloride with diimidophosphenic acid N,N,N',N''-tetrakis(trimethylsilyl)amide and thiophosphenic acid N,N-bis(trimethylsilyl)amide and N'-tert-butylimide

V. V. Trachevskij, A. I. Brusilovets, I. V. Korendovich, V. G. Bdzhola, I. G. Ryabokon'

Research output: Contribution to journalArticle

2 Scopus citations

Abstract

The interaction of (Me3Si)2NPNSiMe3 and (Me3Si)2NP(S)NCMe3 compounds with MoOCl3 in methylene chloride has been studied using ESR spectroscopy, preparative and X-ray diffraction analysis. It has been shown that, in both cases, reactions of 1,2-addition to double P=N bonds proceed to form four-member molybdenum-containing heterocycles.

Original languageEnglish (US)
Pages (from-to)14-18
Number of pages5
JournalUkrainskij Khimicheskij Zhurnal
Volume68
Issue number7-8
StatePublished - 2002

ASJC Scopus subject areas

  • Chemical Engineering(all)

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