Reactions of molybdenum (V) oxychloride with diimidophosphenic acid N,N,N',N''-tetrakis(trimethylsilyl)amide and thiophosphenic acid N,N-bis(trimethylsilyl)amide and N'-tert-butylimide

V. V. Trachevskij; A. I. Brusilovets; I. V. Korendovich; V. G. Bdzhola; I. G. Ryabokon'

Reactions of molybdenum (V) oxychloride with diimidophosphenic acid N,N,N',N''-tetrakis(trimethylsilyl)amide and thiophosphenic acid N,N-bis(trimethylsilyl)amide and N'-tert-butylimide

V. V. Trachevskij, A. I. Brusilovets, I. V. Korendovich, V. G. Bdzhola, I. G. Ryabokon'

Research output: Contribution to journal › Article › peer-review

Abstract

The interaction of (Me₃Si)₂NPNSiMe₃ and (Me₃Si)₂NP(S)NCMe₃ compounds with MoOCl₃ in methylene chloride has been studied using ESR spectroscopy, preparative and X-ray diffraction analysis. It has been shown that, in both cases, reactions of 1,2-addition to double P=N bonds proceed to form four-member molybdenum-containing heterocycles.

Original language	English (US)
Pages (from-to)	14-18
Number of pages	5
Journal	Ukrainskij Khimicheskij Zhurnal
Volume	68
Issue number	7-8
State	Published - 2002
Externally published	Yes

ASJC Scopus subject areas

General Chemical Engineering

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Reactions of molybdenum (V) oxychloride with diimidophosphenic acid N,N,N',N''-tetrakis(trimethylsilyl)amide and thiophosphenic acid N,N-bis(trimethylsilyl)amide and N'-tert-butylimide. / Trachevskij, V. V.; Brusilovets, A. I.; Korendovich, I. V. et al.
In: Ukrainskij Khimicheskij Zhurnal, Vol. 68, No. 7-8, 2002, p. 14-18.

Research output: Contribution to journal › Article › peer-review

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title = "Reactions of molybdenum (V) oxychloride with diimidophosphenic acid N,N,N',N''-tetrakis(trimethylsilyl)amide and thiophosphenic acid N,N-bis(trimethylsilyl)amide and N'-tert-butylimide",

abstract = "The interaction of (Me3Si)2NPNSiMe3 and (Me3Si)2NP(S)NCMe3 compounds with MoOCl3 in methylene chloride has been studied using ESR spectroscopy, preparative and X-ray diffraction analysis. It has been shown that, in both cases, reactions of 1,2-addition to double P=N bonds proceed to form four-member molybdenum-containing heterocycles.",

author = "Trachevskij, {V. V.} and Brusilovets, {A. I.} and Korendovich, {I. V.} and Bdzhola, {V. G.} and Ryabokon', {I. G.}",

year = "2002",

language = "English (US)",

volume = "68",

pages = "14--18",

journal = "Ukrainskij Khimicheskij Zhurnal",

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publisher = "Natsional'na Akademiya Nauk Ukrainy",

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AU - Trachevskij, V. V.

AU - Brusilovets, A. I.

AU - Korendovich, I. V.

AU - Bdzhola, V. G.

AU - Ryabokon', I. G.

PY - 2002

Y1 - 2002

N2 - The interaction of (Me3Si)2NPNSiMe3 and (Me3Si)2NP(S)NCMe3 compounds with MoOCl3 in methylene chloride has been studied using ESR spectroscopy, preparative and X-ray diffraction analysis. It has been shown that, in both cases, reactions of 1,2-addition to double P=N bonds proceed to form four-member molybdenum-containing heterocycles.

AB - The interaction of (Me3Si)2NPNSiMe3 and (Me3Si)2NP(S)NCMe3 compounds with MoOCl3 in methylene chloride has been studied using ESR spectroscopy, preparative and X-ray diffraction analysis. It has been shown that, in both cases, reactions of 1,2-addition to double P=N bonds proceed to form four-member molybdenum-containing heterocycles.

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JF - Ukrainskij Khimicheskij Zhurnal

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ER -

Reactions of molybdenum (V) oxychloride with diimidophosphenic acid N,N,N',N''-tetrakis(trimethylsilyl)amide and thiophosphenic acid N,N-bis(trimethylsilyl)amide and N'-tert-butylimide

Abstract

ASJC Scopus subject areas

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