TY - JOUR
T1 - Reactions of coordinated nitride to generate novel rhenium and molybdenum imido complexes
T2 - The crystal and molecular structures of [Mo(NCPh3)(S2CNMe2)3)]BF4 and [Mo(NSO2Ph)(S2CNMe2)3]PF6
AU - W. Bishop, Michael
AU - Chatt, Joseph
AU - R. Dilworth, Jonathan
AU - D. Neaves, Bryan
AU - Dahlstrom, Phillip
AU - Hyde, Jeffery
AU - Zubieta, Jon
PY - 1981/6/16
Y1 - 1981/6/16
N2 - The nitrido complexes [MoN(S2CNR2)3] (R2 Me2, Et2) and [ReN)S2CNR2)2-(PMe2Ph)n] (R2 Me2; Et2; n 0, 1) react with halides R′X (R′ PhCO, PhSO2, 2,4-(NO2)2C6H3, 2,4-(NO2)2C6H3S; X Cl, R′ Me, X I), [R′3O]BF4 (R′ Me, Et) or [Ph3C]BF4 to give the imido complexes [Mo(NR′)(S2CNR2)3]+ and [Re(NR′)(S2CNR2)2(PME2Ph)n] (R′ Me, Et, Ph3C+, PhSO2, PhCO, 2,4(O2N)2-C6H3, 2,4-(O2N)2C6H3S); the X-ray crystal structures of [Mo(NCPh3)(S2-CNMe2)3]BF4 and [Mo(NSO2Ph)(S2CNMe2)3]PF6 have been determined. Both complexes have approximately pentagonal bipyramidal geometries although the NSO2Ph complex is more distorted. The NCPh3 and NSO2Ph complexes have MoNC and MoNS angles of 175.1(5) ° and 161.3(13)° and MoN distances of 1.731(2) and 1.70(2)Å, respectively.
AB - The nitrido complexes [MoN(S2CNR2)3] (R2 Me2, Et2) and [ReN)S2CNR2)2-(PMe2Ph)n] (R2 Me2; Et2; n 0, 1) react with halides R′X (R′ PhCO, PhSO2, 2,4-(NO2)2C6H3, 2,4-(NO2)2C6H3S; X Cl, R′ Me, X I), [R′3O]BF4 (R′ Me, Et) or [Ph3C]BF4 to give the imido complexes [Mo(NR′)(S2CNR2)3]+ and [Re(NR′)(S2CNR2)2(PME2Ph)n] (R′ Me, Et, Ph3C+, PhSO2, PhCO, 2,4(O2N)2-C6H3, 2,4-(O2N)2C6H3S); the X-ray crystal structures of [Mo(NCPh3)(S2-CNMe2)3]BF4 and [Mo(NSO2Ph)(S2CNMe2)3]PF6 have been determined. Both complexes have approximately pentagonal bipyramidal geometries although the NSO2Ph complex is more distorted. The NCPh3 and NSO2Ph complexes have MoNC and MoNS angles of 175.1(5) ° and 161.3(13)° and MoN distances of 1.731(2) and 1.70(2)Å, respectively.
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U2 - 10.1016/S0022-328X(00)93953-6
DO - 10.1016/S0022-328X(00)93953-6
M3 - Article
AN - SCOPUS:0001689302
SN - 0022-328X
VL - 213
SP - 109
EP - 124
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 1
ER -