Rational Design of Two-Dimensional Bimetallic Wave Structures from Zigzag Chains via Site-Specific Coordination around the 2,6-Naphthalenediphosphonic Acid Motif

Aysun Bulut; Yunus Zorlu; Michael Wörle; Salih Paşa; Hüseyin Kurt; Jon A Zubieta; Jens Beckmann; Gündoğ Yücesan

doi:10.1002/ejic.201600309

Rational Design of Two-Dimensional Bimetallic Wave Structures from Zigzag Chains via Site-Specific Coordination around the 2,6-Naphthalenediphosphonic Acid Motif

Aysun Bulut, Yunus Zorlu, Michael Wörle, Salih Paşa, Hüseyin Kurt, Jon A Zubieta, Jens Beckmann, Gündoğ Yücesan

Department of Chemistry

Research output: Contribution to journal › Article

8 Scopus citations

Abstract

We report the synthesis of a novel aromatic 2,6-naphthalenediphosphonic acid (2,6-NDPA-H₄) and the rational design of molecular, one-, two-, and three-dimensional structures of the resulting copper organophosphonate materials: [{Cu(terpy)}(2,6-NDPA-H₃)][{Cu(terpy)}(2,6-NDPA-H₃)(2,6-NDPA-H₂)]·3H₂O (2), [{Cu(terpy)}VO₂(2,6-NDPA-H)]·H₂O (4), [{Cu(terpy)}VO₂(2,6-NDPA-H)] (3) and [{Cu(H₂O)}(NDPA)_0.5] (1). Engineering the copper coordination sphere and pH-controlled phosphonate protonation enabled the site specific dimensional evolution of Cu^II-organophosphonate frameworks exploiting the deprotonated phosphonate oxygen arms.

Original language	English (US)
Pages (from-to)	3506-3512
Number of pages	7
Journal	European Journal of Inorganic Chemistry
Volume	2016
Issue number	21
DOIs	https://doi.org/10.1002/ejic.201600309
State	Published - 2016

Keywords

Coordination modes
Copper
Ligand design
Magnetic properties
Metal-organic frameworks
Metal–organic solids
Organophosphonates

ASJC Scopus subject areas

Inorganic Chemistry

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10.1002/ejic.201600309

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Bulut, A., Zorlu, Y., Wörle, M., Paşa, S., Kurt, H., Zubieta, J. A., Beckmann, J., & Yücesan, G. (2016). Rational Design of Two-Dimensional Bimetallic Wave Structures from Zigzag Chains via Site-Specific Coordination around the 2,6-Naphthalenediphosphonic Acid Motif. European Journal of Inorganic Chemistry, 2016(21), 3506-3512. https://doi.org/10.1002/ejic.201600309

Rational Design of Two-Dimensional Bimetallic Wave Structures from Zigzag Chains via Site-Specific Coordination around the 2,6-Naphthalenediphosphonic Acid Motif. / Bulut, Aysun; Zorlu, Yunus; Wörle, Michael; Paşa, Salih; Kurt, Hüseyin; Zubieta, Jon A; Beckmann, Jens; Yücesan, Gündoğ.

In: European Journal of Inorganic Chemistry, Vol. 2016, No. 21, 2016, p. 3506-3512.

Research output: Contribution to journal › Article

Bulut, A, Zorlu, Y, Wörle, M, Paşa, S, Kurt, H, Zubieta, JA, Beckmann, J & Yücesan, G 2016, 'Rational Design of Two-Dimensional Bimetallic Wave Structures from Zigzag Chains via Site-Specific Coordination around the 2,6-Naphthalenediphosphonic Acid Motif', European Journal of Inorganic Chemistry, vol. 2016, no. 21, pp. 3506-3512. https://doi.org/10.1002/ejic.201600309

Bulut, Aysun ; Zorlu, Yunus ; Wörle, Michael ; Paşa, Salih ; Kurt, Hüseyin ; Zubieta, Jon A ; Beckmann, Jens ; Yücesan, Gündoğ. / Rational Design of Two-Dimensional Bimetallic Wave Structures from Zigzag Chains via Site-Specific Coordination around the 2,6-Naphthalenediphosphonic Acid Motif. In: European Journal of Inorganic Chemistry. 2016 ; Vol. 2016, No. 21. pp. 3506-3512.

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abstract = "We report the synthesis of a novel aromatic 2,6-naphthalenediphosphonic acid (2,6-NDPA-H4) and the rational design of molecular, one-, two-, and three-dimensional structures of the resulting copper organophosphonate materials: [{Cu(terpy)}(2,6-NDPA-H3)][{Cu(terpy)}(2,6-NDPA-H3)(2,6-NDPA-H2)]·3H2O (2), [{Cu(terpy)}VO2(2,6-NDPA-H)]·H2O (4), [{Cu(terpy)}VO2(2,6-NDPA-H)] (3) and [{Cu(H2O)}(NDPA)0.5] (1). Engineering the copper coordination sphere and pH-controlled phosphonate protonation enabled the site specific dimensional evolution of CuII-organophosphonate frameworks exploiting the deprotonated phosphonate oxygen arms.",

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AU - Wörle, Michael

AU - Paşa, Salih

AU - Kurt, Hüseyin

AU - Zubieta, Jon A

AU - Beckmann, Jens

AU - Yücesan, Gündoğ

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N2 - We report the synthesis of a novel aromatic 2,6-naphthalenediphosphonic acid (2,6-NDPA-H4) and the rational design of molecular, one-, two-, and three-dimensional structures of the resulting copper organophosphonate materials: [{Cu(terpy)}(2,6-NDPA-H3)][{Cu(terpy)}(2,6-NDPA-H3)(2,6-NDPA-H2)]·3H2O (2), [{Cu(terpy)}VO2(2,6-NDPA-H)]·H2O (4), [{Cu(terpy)}VO2(2,6-NDPA-H)] (3) and [{Cu(H2O)}(NDPA)0.5] (1). Engineering the copper coordination sphere and pH-controlled phosphonate protonation enabled the site specific dimensional evolution of CuII-organophosphonate frameworks exploiting the deprotonated phosphonate oxygen arms.

AB - We report the synthesis of a novel aromatic 2,6-naphthalenediphosphonic acid (2,6-NDPA-H4) and the rational design of molecular, one-, two-, and three-dimensional structures of the resulting copper organophosphonate materials: [{Cu(terpy)}(2,6-NDPA-H3)][{Cu(terpy)}(2,6-NDPA-H3)(2,6-NDPA-H2)]·3H2O (2), [{Cu(terpy)}VO2(2,6-NDPA-H)]·H2O (4), [{Cu(terpy)}VO2(2,6-NDPA-H)] (3) and [{Cu(H2O)}(NDPA)0.5] (1). Engineering the copper coordination sphere and pH-controlled phosphonate protonation enabled the site specific dimensional evolution of CuII-organophosphonate frameworks exploiting the deprotonated phosphonate oxygen arms.

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KW - Metal-organic frameworks

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