TY - JOUR
T1 - Rational Design of Two-Dimensional Bimetallic Wave Structures from Zigzag Chains via Site-Specific Coordination around the 2,6-Naphthalenediphosphonic Acid Motif
AU - Bulut, Aysun
AU - Zorlu, Yunus
AU - Wörle, Michael
AU - Paşa, Salih
AU - Kurt, Hüseyin
AU - Zubieta, Jon
AU - Beckmann, Jens
AU - Yücesan, Gündoğ
N1 - Funding Information:
This work has been supported by the TÜBİTAK (the Scientific and Technical Research Council of Turkey) (grant number 212T060) and the European Union (EU), TD 1304, COST action. Ramazan Topkaya and Prof. Dr. Bekir Aktaş are thanked for their help with the magnetic measurements.
Publisher Copyright:
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
PY - 2016/7
Y1 - 2016/7
N2 - We report the synthesis of a novel aromatic 2,6-naphthalenediphosphonic acid (2,6-NDPA-H4) and the rational design of molecular, one-, two-, and three-dimensional structures of the resulting copper organophosphonate materials: [{Cu(terpy)}(2,6-NDPA-H3)][{Cu(terpy)}(2,6-NDPA-H3)(2,6-NDPA-H2)]·3H2O (2), [{Cu(terpy)}VO2(2,6-NDPA-H)]·H2O (4), [{Cu(terpy)}VO2(2,6-NDPA-H)] (3) and [{Cu(H2O)}(NDPA)0.5] (1). Engineering the copper coordination sphere and pH-controlled phosphonate protonation enabled the site specific dimensional evolution of CuII-organophosphonate frameworks exploiting the deprotonated phosphonate oxygen arms.
AB - We report the synthesis of a novel aromatic 2,6-naphthalenediphosphonic acid (2,6-NDPA-H4) and the rational design of molecular, one-, two-, and three-dimensional structures of the resulting copper organophosphonate materials: [{Cu(terpy)}(2,6-NDPA-H3)][{Cu(terpy)}(2,6-NDPA-H3)(2,6-NDPA-H2)]·3H2O (2), [{Cu(terpy)}VO2(2,6-NDPA-H)]·H2O (4), [{Cu(terpy)}VO2(2,6-NDPA-H)] (3) and [{Cu(H2O)}(NDPA)0.5] (1). Engineering the copper coordination sphere and pH-controlled phosphonate protonation enabled the site specific dimensional evolution of CuII-organophosphonate frameworks exploiting the deprotonated phosphonate oxygen arms.
KW - Coordination modes
KW - Copper
KW - Ligand design
KW - Magnetic properties
KW - Metal-organic frameworks
KW - Metal–organic solids
KW - Organophosphonates
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U2 - 10.1002/ejic.201600309
DO - 10.1002/ejic.201600309
M3 - Article
AN - SCOPUS:84977485969
SN - 1434-1948
VL - 2016
SP - 3506
EP - 3512
JO - European Journal of Inorganic Chemistry
JF - European Journal of Inorganic Chemistry
IS - 21
ER -