Rational Design of Two-Dimensional Bimetallic Wave Structures from Zigzag Chains via Site-Specific Coordination around the 2,6-Naphthalenediphosphonic Acid Motif

Aysun Bulut; Yunus Zorlu; Michael Wörle; Salih Paşa; Hüseyin Kurt; Jon Zubieta; Jens Beckmann; Gündoğ Yücesan

doi:10.1002/ejic.201600309

Rational Design of Two-Dimensional Bimetallic Wave Structures from Zigzag Chains via Site-Specific Coordination around the 2,6-Naphthalenediphosphonic Acid Motif

Aysun Bulut, Yunus Zorlu, Michael Wörle, Salih Paşa, Hüseyin Kurt, Jon Zubieta, Jens Beckmann, Gündoğ Yücesan

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

We report the synthesis of a novel aromatic 2,6-naphthalenediphosphonic acid (2,6-NDPA-H₄) and the rational design of molecular, one-, two-, and three-dimensional structures of the resulting copper organophosphonate materials: [{Cu(terpy)}(2,6-NDPA-H₃)][{Cu(terpy)}(2,6-NDPA-H₃)(2,6-NDPA-H₂)]·3H₂O (2), [{Cu(terpy)}VO₂(2,6-NDPA-H)]·H₂O (4), [{Cu(terpy)}VO₂(2,6-NDPA-H)] (3) and [{Cu(H₂O)}(NDPA)_0.5] (1). Engineering the copper coordination sphere and pH-controlled phosphonate protonation enabled the site specific dimensional evolution of Cu^II-organophosphonate frameworks exploiting the deprotonated phosphonate oxygen arms.

Original language	English (US)
Pages (from-to)	3506-3512
Number of pages	7
Journal	European Journal of Inorganic Chemistry
Volume	2016
Issue number	21
DOIs	https://doi.org/10.1002/ejic.201600309
State	Published - Jul 2016

Keywords

Coordination modes
Copper
Ligand design
Magnetic properties
Metal-organic frameworks
Metal–organic solids
Organophosphonates

ASJC Scopus subject areas

Inorganic Chemistry

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Rational Design of Two-Dimensional Bimetallic Wave Structures from Zigzag Chains via Site-Specific Coordination around the 2,6-Naphthalenediphosphonic Acid Motif. / Bulut, Aysun; Zorlu, Yunus; Wörle, Michael et al.

In: European Journal of Inorganic Chemistry, Vol. 2016, No. 21, 07.2016, p. 3506-3512.

Research output: Contribution to journal › Article › peer-review

Bulut, A, Zorlu, Y, Wörle, M, Paşa, S, Kurt, H, Zubieta, J, Beckmann, J & Yücesan, G 2016, 'Rational Design of Two-Dimensional Bimetallic Wave Structures from Zigzag Chains via Site-Specific Coordination around the 2,6-Naphthalenediphosphonic Acid Motif', European Journal of Inorganic Chemistry, vol. 2016, no. 21, pp. 3506-3512. https://doi.org/10.1002/ejic.201600309

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title = "Rational Design of Two-Dimensional Bimetallic Wave Structures from Zigzag Chains via Site-Specific Coordination around the 2,6-Naphthalenediphosphonic Acid Motif",

abstract = "We report the synthesis of a novel aromatic 2,6-naphthalenediphosphonic acid (2,6-NDPA-H4) and the rational design of molecular, one-, two-, and three-dimensional structures of the resulting copper organophosphonate materials: [{Cu(terpy)}(2,6-NDPA-H3)][{Cu(terpy)}(2,6-NDPA-H3)(2,6-NDPA-H2)]·3H2O (2), [{Cu(terpy)}VO2(2,6-NDPA-H)]·H2O (4), [{Cu(terpy)}VO2(2,6-NDPA-H)] (3) and [{Cu(H2O)}(NDPA)0.5] (1). Engineering the copper coordination sphere and pH-controlled phosphonate protonation enabled the site specific dimensional evolution of CuII-organophosphonate frameworks exploiting the deprotonated phosphonate oxygen arms.",

keywords = "Coordination modes, Copper, Ligand design, Magnetic properties, Metal-organic frameworks, Metal–organic solids, Organophosphonates",

author = "Aysun Bulut and Yunus Zorlu and Michael W{\"o}rle and Salih Pa{\c s}a and H{\"u}seyin Kurt and Jon Zubieta and Jens Beckmann and G{\"u}ndoğ Y{\"u}cesan",

note = "Funding Information: This work has been supported by the T{\"U}BİTAK (the Scientific and Technical Research Council of Turkey) (grant number 212T060) and the European Union (EU), TD 1304, COST action. Ramazan Topkaya and Prof. Dr. Bekir Akta{\c s} are thanked for their help with the magnetic measurements. Publisher Copyright: {\textcopyright} 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim",

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AU - Zorlu, Yunus

AU - Wörle, Michael

AU - Paşa, Salih

AU - Kurt, Hüseyin

AU - Zubieta, Jon

AU - Beckmann, Jens

AU - Yücesan, Gündoğ

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PY - 2016/7

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N2 - We report the synthesis of a novel aromatic 2,6-naphthalenediphosphonic acid (2,6-NDPA-H4) and the rational design of molecular, one-, two-, and three-dimensional structures of the resulting copper organophosphonate materials: [{Cu(terpy)}(2,6-NDPA-H3)][{Cu(terpy)}(2,6-NDPA-H3)(2,6-NDPA-H2)]·3H2O (2), [{Cu(terpy)}VO2(2,6-NDPA-H)]·H2O (4), [{Cu(terpy)}VO2(2,6-NDPA-H)] (3) and [{Cu(H2O)}(NDPA)0.5] (1). Engineering the copper coordination sphere and pH-controlled phosphonate protonation enabled the site specific dimensional evolution of CuII-organophosphonate frameworks exploiting the deprotonated phosphonate oxygen arms.

AB - We report the synthesis of a novel aromatic 2,6-naphthalenediphosphonic acid (2,6-NDPA-H4) and the rational design of molecular, one-, two-, and three-dimensional structures of the resulting copper organophosphonate materials: [{Cu(terpy)}(2,6-NDPA-H3)][{Cu(terpy)}(2,6-NDPA-H3)(2,6-NDPA-H2)]·3H2O (2), [{Cu(terpy)}VO2(2,6-NDPA-H)]·H2O (4), [{Cu(terpy)}VO2(2,6-NDPA-H)] (3) and [{Cu(H2O)}(NDPA)0.5] (1). Engineering the copper coordination sphere and pH-controlled phosphonate protonation enabled the site specific dimensional evolution of CuII-organophosphonate frameworks exploiting the deprotonated phosphonate oxygen arms.

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KW - Copper

KW - Ligand design

KW - Magnetic properties

KW - Metal-organic frameworks

KW - Metal–organic solids

KW - Organophosphonates

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Rational Design of Two-Dimensional Bimetallic Wave Structures from Zigzag Chains via Site-Specific Coordination around the 2,6-Naphthalenediphosphonic Acid Motif

Abstract

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