Rational Design of Two-Dimensional Bimetallic Wave Structures from Zigzag Chains via Site-Specific Coordination around the 2,6-Naphthalenediphosphonic Acid Motif

Aysun Bulut; Yunus Zorlu; Michael Wörle; Salih Paşa; Hüseyin Kurt; Jon Zubieta; Jens Beckmann; Gündoğ Yücesan

doi:10.1002/ejic.201600309

Rational Design of Two-Dimensional Bimetallic Wave Structures from Zigzag Chains via Site-Specific Coordination around the 2,6-Naphthalenediphosphonic Acid Motif

Aysun Bulut, Yunus Zorlu, Michael Wörle, Salih Paşa, Hüseyin Kurt, Jon Zubieta, Jens Beckmann, Gündoğ Yücesan

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

We report the synthesis of a novel aromatic 2,6-naphthalenediphosphonic acid (2,6-NDPA-H₄) and the rational design of molecular, one-, two-, and three-dimensional structures of the resulting copper organophosphonate materials: [{Cu(terpy)}(2,6-NDPA-H₃)][{Cu(terpy)}(2,6-NDPA-H₃)(2,6-NDPA-H₂)]·3H₂O (2), [{Cu(terpy)}VO₂(2,6-NDPA-H)]·H₂O (4), [{Cu(terpy)}VO₂(2,6-NDPA-H)] (3) and [{Cu(H₂O)}(NDPA)_0.5] (1). Engineering the copper coordination sphere and pH-controlled phosphonate protonation enabled the site specific dimensional evolution of Cu^II-organophosphonate frameworks exploiting the deprotonated phosphonate oxygen arms.

Original language	English (US)
Pages (from-to)	3506-3512
Number of pages	7
Journal	European Journal of Inorganic Chemistry
Volume	2016
Issue number	21
DOIs	https://doi.org/10.1002/ejic.201600309
State	Published - Jul 2016

Keywords

Coordination modes
Copper
Ligand design
Magnetic properties
Metal-organic frameworks
Metal–organic solids
Organophosphonates

ASJC Scopus subject areas

Inorganic Chemistry

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10.1002/ejic.201600309

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Rational Design of Two-Dimensional Bimetallic Wave Structures from Zigzag Chains via Site-Specific Coordination around the 2,6-Naphthalenediphosphonic Acid Motif. / Bulut, Aysun; Zorlu, Yunus; Wörle, Michael; Paşa, Salih; Kurt, Hüseyin; Zubieta, Jon; Beckmann, Jens; Yücesan, Gündoğ.

In: European Journal of Inorganic Chemistry, Vol. 2016, No. 21, 07.2016, p. 3506-3512.

Research output: Contribution to journal › Article › peer-review

Bulut, A, Zorlu, Y, Wörle, M, Paşa, S, Kurt, H, Zubieta, J, Beckmann, J & Yücesan, G 2016, 'Rational Design of Two-Dimensional Bimetallic Wave Structures from Zigzag Chains via Site-Specific Coordination around the 2,6-Naphthalenediphosphonic Acid Motif', European Journal of Inorganic Chemistry, vol. 2016, no. 21, pp. 3506-3512. https://doi.org/10.1002/ejic.201600309

Bulut, Aysun ; Zorlu, Yunus ; Wörle, Michael ; Paşa, Salih ; Kurt, Hüseyin ; Zubieta, Jon ; Beckmann, Jens ; Yücesan, Gündoğ. / Rational Design of Two-Dimensional Bimetallic Wave Structures from Zigzag Chains via Site-Specific Coordination around the 2,6-Naphthalenediphosphonic Acid Motif. In: European Journal of Inorganic Chemistry. 2016 ; Vol. 2016, No. 21. pp. 3506-3512.

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title = "Rational Design of Two-Dimensional Bimetallic Wave Structures from Zigzag Chains via Site-Specific Coordination around the 2,6-Naphthalenediphosphonic Acid Motif",

abstract = "We report the synthesis of a novel aromatic 2,6-naphthalenediphosphonic acid (2,6-NDPA-H4) and the rational design of molecular, one-, two-, and three-dimensional structures of the resulting copper organophosphonate materials: [{Cu(terpy)}(2,6-NDPA-H3)][{Cu(terpy)}(2,6-NDPA-H3)(2,6-NDPA-H2)]·3H2O (2), [{Cu(terpy)}VO2(2,6-NDPA-H)]·H2O (4), [{Cu(terpy)}VO2(2,6-NDPA-H)] (3) and [{Cu(H2O)}(NDPA)0.5] (1). Engineering the copper coordination sphere and pH-controlled phosphonate protonation enabled the site specific dimensional evolution of CuII-organophosphonate frameworks exploiting the deprotonated phosphonate oxygen arms.",

keywords = "Coordination modes, Copper, Ligand design, Magnetic properties, Metal-organic frameworks, Metal–organic solids, Organophosphonates",

author = "Aysun Bulut and Yunus Zorlu and Michael W{\"o}rle and Salih Pa{\c s}a and H{\"u}seyin Kurt and Jon Zubieta and Jens Beckmann and G{\"u}ndoğ Y{\"u}cesan",

note = "Funding Information: This work has been supported by the T?B?TAK (the Scientific and Technical Research Council of Turkey) (grant number 212T060) and the European Union (EU), TD 1304, COST action. Ramazan Topkaya and Prof. Dr. Bekir Akta? are thanked for their help with the magnetic measurements. Publisher Copyright: {\textcopyright} 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim",

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AU - Wörle, Michael

AU - Paşa, Salih

AU - Kurt, Hüseyin

AU - Zubieta, Jon

AU - Beckmann, Jens

AU - Yücesan, Gündoğ

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N2 - We report the synthesis of a novel aromatic 2,6-naphthalenediphosphonic acid (2,6-NDPA-H4) and the rational design of molecular, one-, two-, and three-dimensional structures of the resulting copper organophosphonate materials: [{Cu(terpy)}(2,6-NDPA-H3)][{Cu(terpy)}(2,6-NDPA-H3)(2,6-NDPA-H2)]·3H2O (2), [{Cu(terpy)}VO2(2,6-NDPA-H)]·H2O (4), [{Cu(terpy)}VO2(2,6-NDPA-H)] (3) and [{Cu(H2O)}(NDPA)0.5] (1). Engineering the copper coordination sphere and pH-controlled phosphonate protonation enabled the site specific dimensional evolution of CuII-organophosphonate frameworks exploiting the deprotonated phosphonate oxygen arms.

AB - We report the synthesis of a novel aromatic 2,6-naphthalenediphosphonic acid (2,6-NDPA-H4) and the rational design of molecular, one-, two-, and three-dimensional structures of the resulting copper organophosphonate materials: [{Cu(terpy)}(2,6-NDPA-H3)][{Cu(terpy)}(2,6-NDPA-H3)(2,6-NDPA-H2)]·3H2O (2), [{Cu(terpy)}VO2(2,6-NDPA-H)]·H2O (4), [{Cu(terpy)}VO2(2,6-NDPA-H)] (3) and [{Cu(H2O)}(NDPA)0.5] (1). Engineering the copper coordination sphere and pH-controlled phosphonate protonation enabled the site specific dimensional evolution of CuII-organophosphonate frameworks exploiting the deprotonated phosphonate oxygen arms.

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KW - Ligand design

KW - Magnetic properties

KW - Metal-organic frameworks

KW - Metal–organic solids

KW - Organophosphonates

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Rational Design of Two-Dimensional Bimetallic Wave Structures from Zigzag Chains via Site-Specific Coordination around the 2,6-Naphthalenediphosphonic Acid Motif

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