Abstract
We report the synthesis of a novel aromatic 2,6-naphthalenediphosphonic acid (2,6-NDPA-H4) and the rational design of molecular, one-, two-, and three-dimensional structures of the resulting copper organophosphonate materials: [{Cu(terpy)}(2,6-NDPA-H3)][{Cu(terpy)}(2,6-NDPA-H3)(2,6-NDPA-H2)]·3H2O (2), [{Cu(terpy)}VO2(2,6-NDPA-H)]·H2O (4), [{Cu(terpy)}VO2(2,6-NDPA-H)] (3) and [{Cu(H2O)}(NDPA)0.5] (1). Engineering the copper coordination sphere and pH-controlled phosphonate protonation enabled the site specific dimensional evolution of CuII-organophosphonate frameworks exploiting the deprotonated phosphonate oxygen arms.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 3506-3512 |
| Number of pages | 7 |
| Journal | European Journal of Inorganic Chemistry |
| Volume | 2016 |
| Issue number | 21 |
| DOIs | |
| State | Published - 2016 |
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Keywords
- Coordination modes
- Copper
- Ligand design
- Magnetic properties
- Metal-organic frameworks
- Metal–organic solids
- Organophosphonates
ASJC Scopus subject areas
- Inorganic Chemistry
Cite this
Rational Design of Two-Dimensional Bimetallic Wave Structures from Zigzag Chains via Site-Specific Coordination around the 2,6-Naphthalenediphosphonic Acid Motif. / Bulut, Aysun; Zorlu, Yunus; Wörle, Michael; Paşa, Salih; Kurt, Hüseyin; Zubieta, Jon A; Beckmann, Jens; Yücesan, Gündoğ.
In: European Journal of Inorganic Chemistry, Vol. 2016, No. 21, 2016, p. 3506-3512.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Rational Design of Two-Dimensional Bimetallic Wave Structures from Zigzag Chains via Site-Specific Coordination around the 2,6-Naphthalenediphosphonic Acid Motif
AU - Bulut, Aysun
AU - Zorlu, Yunus
AU - Wörle, Michael
AU - Paşa, Salih
AU - Kurt, Hüseyin
AU - Zubieta, Jon A
AU - Beckmann, Jens
AU - Yücesan, Gündoğ
PY - 2016
Y1 - 2016
N2 - We report the synthesis of a novel aromatic 2,6-naphthalenediphosphonic acid (2,6-NDPA-H4) and the rational design of molecular, one-, two-, and three-dimensional structures of the resulting copper organophosphonate materials: [{Cu(terpy)}(2,6-NDPA-H3)][{Cu(terpy)}(2,6-NDPA-H3)(2,6-NDPA-H2)]·3H2O (2), [{Cu(terpy)}VO2(2,6-NDPA-H)]·H2O (4), [{Cu(terpy)}VO2(2,6-NDPA-H)] (3) and [{Cu(H2O)}(NDPA)0.5] (1). Engineering the copper coordination sphere and pH-controlled phosphonate protonation enabled the site specific dimensional evolution of CuII-organophosphonate frameworks exploiting the deprotonated phosphonate oxygen arms.
AB - We report the synthesis of a novel aromatic 2,6-naphthalenediphosphonic acid (2,6-NDPA-H4) and the rational design of molecular, one-, two-, and three-dimensional structures of the resulting copper organophosphonate materials: [{Cu(terpy)}(2,6-NDPA-H3)][{Cu(terpy)}(2,6-NDPA-H3)(2,6-NDPA-H2)]·3H2O (2), [{Cu(terpy)}VO2(2,6-NDPA-H)]·H2O (4), [{Cu(terpy)}VO2(2,6-NDPA-H)] (3) and [{Cu(H2O)}(NDPA)0.5] (1). Engineering the copper coordination sphere and pH-controlled phosphonate protonation enabled the site specific dimensional evolution of CuII-organophosphonate frameworks exploiting the deprotonated phosphonate oxygen arms.
KW - Coordination modes
KW - Copper
KW - Ligand design
KW - Magnetic properties
KW - Metal-organic frameworks
KW - Metal–organic solids
KW - Organophosphonates
UR - http://www.scopus.com/inward/record.url?scp=84977485969&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84977485969&partnerID=8YFLogxK
U2 - 10.1002/ejic.201600309
DO - 10.1002/ejic.201600309
M3 - Article
VL - 2016
SP - 3506
EP - 3512
JO - Chemische Berichte
JF - Chemische Berichte
SN - 0009-2940
IS - 21
ER -