Rational Design of Two-Dimensional Bimetallic Wave Structures from Zigzag Chains via Site-Specific Coordination around the 2,6-Naphthalenediphosphonic Acid Motif

Aysun Bulut, Yunus Zorlu, Michael Wörle, Salih Paşa, Hüseyin Kurt, Jon A Zubieta, Jens Beckmann, Gündoğ Yücesan

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

We report the synthesis of a novel aromatic 2,6-naphthalenediphosphonic acid (2,6-NDPA-H4) and the rational design of molecular, one-, two-, and three-dimensional structures of the resulting copper organophosphonate materials: [{Cu(terpy)}(2,6-NDPA-H3)][{Cu(terpy)}(2,6-NDPA-H3)(2,6-NDPA-H2)]·3H2O (2), [{Cu(terpy)}VO2(2,6-NDPA-H)]·H2O (4), [{Cu(terpy)}VO2(2,6-NDPA-H)] (3) and [{Cu(H2O)}(NDPA)0.5] (1). Engineering the copper coordination sphere and pH-controlled phosphonate protonation enabled the site specific dimensional evolution of CuII-organophosphonate frameworks exploiting the deprotonated phosphonate oxygen arms.

Original languageEnglish (US)
Pages (from-to)3506-3512
Number of pages7
JournalEuropean Journal of Inorganic Chemistry
Volume2016
Issue number21
DOIs
StatePublished - 2016

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Organophosphonates
Acids
Copper
Protonation
Oxygen

Keywords

  • Coordination modes
  • Copper
  • Ligand design
  • Magnetic properties
  • Metal-organic frameworks
  • Metal–organic solids
  • Organophosphonates

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

Rational Design of Two-Dimensional Bimetallic Wave Structures from Zigzag Chains via Site-Specific Coordination around the 2,6-Naphthalenediphosphonic Acid Motif. / Bulut, Aysun; Zorlu, Yunus; Wörle, Michael; Paşa, Salih; Kurt, Hüseyin; Zubieta, Jon A; Beckmann, Jens; Yücesan, Gündoğ.

In: European Journal of Inorganic Chemistry, Vol. 2016, No. 21, 2016, p. 3506-3512.

Research output: Contribution to journalArticle

Bulut, Aysun ; Zorlu, Yunus ; Wörle, Michael ; Paşa, Salih ; Kurt, Hüseyin ; Zubieta, Jon A ; Beckmann, Jens ; Yücesan, Gündoğ. / Rational Design of Two-Dimensional Bimetallic Wave Structures from Zigzag Chains via Site-Specific Coordination around the 2,6-Naphthalenediphosphonic Acid Motif. In: European Journal of Inorganic Chemistry. 2016 ; Vol. 2016, No. 21. pp. 3506-3512.
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abstract = "We report the synthesis of a novel aromatic 2,6-naphthalenediphosphonic acid (2,6-NDPA-H4) and the rational design of molecular, one-, two-, and three-dimensional structures of the resulting copper organophosphonate materials: [{Cu(terpy)}(2,6-NDPA-H3)][{Cu(terpy)}(2,6-NDPA-H3)(2,6-NDPA-H2)]·3H2O (2), [{Cu(terpy)}VO2(2,6-NDPA-H)]·H2O (4), [{Cu(terpy)}VO2(2,6-NDPA-H)] (3) and [{Cu(H2O)}(NDPA)0.5] (1). Engineering the copper coordination sphere and pH-controlled phosphonate protonation enabled the site specific dimensional evolution of CuII-organophosphonate frameworks exploiting the deprotonated phosphonate oxygen arms.",
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AU - Paşa, Salih

AU - Kurt, Hüseyin

AU - Zubieta, Jon A

AU - Beckmann, Jens

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AB - We report the synthesis of a novel aromatic 2,6-naphthalenediphosphonic acid (2,6-NDPA-H4) and the rational design of molecular, one-, two-, and three-dimensional structures of the resulting copper organophosphonate materials: [{Cu(terpy)}(2,6-NDPA-H3)][{Cu(terpy)}(2,6-NDPA-H3)(2,6-NDPA-H2)]·3H2O (2), [{Cu(terpy)}VO2(2,6-NDPA-H)]·H2O (4), [{Cu(terpy)}VO2(2,6-NDPA-H)] (3) and [{Cu(H2O)}(NDPA)0.5] (1). Engineering the copper coordination sphere and pH-controlled phosphonate protonation enabled the site specific dimensional evolution of CuII-organophosphonate frameworks exploiting the deprotonated phosphonate oxygen arms.

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